Preparation and Eh--pH diagrams of Fe(II)--Fe(III) green rust compounds; hyperfine interaction characteristics and stoichiometry of hydroxy-chloride, -sulphate and -carbonate

Fe(II)--Fe(III) hydroxy-chloride, -sulphate and -carbonate were prepared by oxidation of a ferrous hydroxide precipitate in anion-containing aqueous solutions. The compounds are characterized by monitoring the redox potential E_h and the pH of stochiometric suspension vs time with the appropriate concentration ratios. X-ray diffraction allows us to characterize the crystal structure by distinguishing “green rust one” (GR1) from “green rust two” (GR2). Since green rusts (GRs) are of a pyroaurite-sjögrenite-like structure, i.e., consisting of intercalated foreign anions and water molecules in the interlayers between the brucite-like layers of Fe(OH)₂, their chemical formulae can be determined from the Mössbauer spectra. Three quadrupole doublets are observed: D₁ and D₂ correspond to a ferrous state with isomershift IS of about 1.27 mm s^-1 and quadrupole splittings QS of about 2.85 and 2.60 mm s^-1, respectively, whereas D₃ corresponds to a ferric state with IS and QS of about 0.4 mm s^-1. The hyperfine parameters of these doublets are similar from one green rust to another but their intensity ratios vary considerably. Finally, E_h and pH equilibrium diagrams of the Fe species in the presence of chloride, sulphate and carbonate anions contained within the water solution are drawn and the thermodynamic conditions of existence and degrees of oxidation of green rusts are discussed.     

Effect of annealing in an atomic-hydrogen atmosphere on the properties of amorphous hydrated silicon films and the parameters of p-i-n structures based on them

The decrease in the density of dangling silicon-silicon bonds in a-Si:H films as a result of annealing in an atomic-hydrogen atmosphere is determined by their density in the initial (nonannealed) film. The change in the total hydrogen density in a-Si:H films, annealed in an atomic-hydrogen atmosphere, is determined by the type of silicon-hydrogen bonds and the impurity content: The hydrogen content can decrease to 1 at. % in the presence of monohydride bonds (2020 cm⁻¹) and no change is observed in the hydrogen content in the presence of oxygen (≲0.1 at. %). A decrease in the defect density as a result of annealing in an atomic-hydrogen atmosphere is observed for all films. The Staebler-Wronski effect — AM-1 irradiation for 10 h — is observed for all films irrespective of the total hydrogen density, the type of silicon-hydrogen bonds, and the presence of oxygen. Fiz. Tekh. Poluprovodn. 32, 620–626 (May 1998)     

Diffraction of millimeter waves by projecting a shadow pattern onto a semiconductor

The transmission of millimeter waves through a semiconductor changes according to the amount of light falling on it. In the experiments reported here, a pattern of light and shadow is projected onto a sheet of semiconductor and the regions of greater and lesser transmission serve as a diffracting object for a millimeter-wave beam. The light source is a quartz tungsten halogen lamp. A lock-in amplifier is employed to overcome difficulties due to the differences in transmitted power being small.     

The error probability of M-ary PSK block coded modulation schemes

A tight upper bound on the decoding error probability is derived for block-coded modulation structures where an M-ary phase shift keying (M-PSK) signal constellation is employed. This bound, called a tangential sphere bound, is tight for very low (as well as for high) signal-to-noise ratios (SNRs). Berlekamp's tangential union bound, previously derived for binary codes, can be derived for an M-PSK block coded modulation structure as well. However, it is proven that our tangential sphere bound is tighter than Berlekamp's (1980) tangential bound. For particular schemes, it is shown that for low SNRs our bound is considerably tighter than the tangential bound. As one of the examples, a multistage decoder is considered     

Experimental modelling of high frequency circuits at low audio frequencies part I

At microwave frequencies, frequent use is made in circuit design of the electrical properties of short lengths of resistively terminated transmission line. It will be shown in the following contribution that circuits based on high frequency distributed lines can usefully be modelled at low audio frequencies using lumped element lines.     

Variable-bit-rate speech transmission using punctured convolutionalcodes

Rate (n-1)/n punctured convolutional codes are very effective in conjunction with embedded differential pulse code modulation (EDPCM) in variable-bit-rate speech transmission. The authors investigate the performance of this variable-bit-rate EDPCM system in terms of probability of bit error and audio signal-to-noise ratio (SNR) versus channel SNR in an additive white Gaussian noise and Rayleigh fading channel using soft-decision decoding for specific sets of code generators of punctured convolutional codes. The results show that different sets of code generators affect the performance in terms of both the probability of bit error and the audio SNR. Improvements were obtained in the cases of Gaussian nonfading and Rayleigh fading channels using soft-decision decoding     

Excited-state-absorption cross sections and amplifier modeling inthe 1300-nm region for Nd-doped glasses

The performance of Nd³⁺-doped fibre amplifiers is limited by strong excited-state absorption (ESA) of the signal, and, even for fluorozirconate glasses, ESA prevents the important region below 1320 nm from being used. To quantify this limitation and explore alternative host materials, ESA and stimulated-emission cross sections have been measured for a representative group of glass compositions. These parameters have been used in an accurate fiber-amplifier model to provide the first quantitative comparisons of performance for Nd³⁺ -doped glasses in the 1300-nm band as a function of host