300mm全自动去胶清洗设备的研制

介绍了一种全自动去胶清洗设备的结构技术,主要从工艺槽体溶液均匀性实现等方面阐述槽体结构。经用户使用证明：该系统运行稳定可靠,工艺灵活,清洗工艺先进。适用150～300 mm晶圆片的去胶、腐蚀、清洗等工艺。     

工程流体力学关于沿程阻力的教学探讨

针对工程流体力学中沿程阻力知识点的教授,将与其相关的连续性方程、伯努利方程、动量方程、牛顿内摩擦定律、量纲分析、雷诺实验、尼古拉兹实验以及沿程阻力的应用等知识点有机地串联在一起,并传递了"理论推演-量纲分析-实验研究-实例应用"的工程流体力学经典研究方法,构建了以沿程阻力为核心的知识体系,以期为学生学习和教师讲授提供帮助.     

高熵合金强韧化理论建模与模拟研究进展

高熵合金因其优异的性能受到广泛关注,如高强度、高硬度、高韧性、高耐磨、高耐辐照、高耐腐蚀、高电阻、高耐热等,有望应用于核能、航天航空等重要领域和重大装备.高熵合金制备、组织结构以及性能表征等方面开展的实验研究表明其独特的性质依赖于高熵合金高熵效应、晶格畸变和扩散迟滞.在微观尺度以及宏观尺度,理论模型和数值模拟为研究高熵合金微观机理和力学特性提供了一种方法.建立从高熵合金的微观结构与变形机理到宏观独特力学性能的联系是一个多尺度的科学问题.最近,基于实验观察结果,采用多尺度的理论与模拟方法(第一性原理、分子动力学、离散位错动力学、晶体塑性有限元、微结构依赖的理论模型),研究了高熵合金层错能、弹性模量、扩散系数以及相稳定性,揭示了高熵合金变形与强韧化机制.论文综述多尺度计算在高熵合金力学性能和变形行为方面的研究进展,并对高熵合金在原位变形实验、高通量技术以及机器学习方面的研究进行简要展望.     

循环接触下安定状态问题的研究

基于线性随动强化理论,运用算子分离技术,研究将弹塑性问题转换为弹性问题和残余问题的分析方法,且针对循环载荷接触安定状态,建立了计算机分析程序.该研究能够分析计算弹塑性接触载荷在安定状态下的应力、残余累积应变及残余应力.分析计算了不同载荷的安定状态,并探讨其残余应力场的分析方法.     

新型Br(o)nsted-Lewis酸性离子液体的合成及其在松香二聚反应中的应用

合成、表征了新型Bronsted-Lewis酸性离子液体1-(3-磺酸)-丙基-3-甲基咪唑氯锌酸盐([HO3S-(CH2)3-mim]Cl-ZnCl2),并将其用于催化松香二聚反应.结果表明,[HO3S-(CH2)3-mim]Cl-ZnCl2(ZnCl2摩尔分数x＞0.5)为Bronsted和Lewis双酸性,且以[HO3S-(CH2)3-mim]Cl-ZnCl2 (x=0.64)的催化性能较佳.在松香5.0 g,甲苯15 g,离子液体质量分数5%,反应温度110℃和反应时间4 h的较佳实验条件下,所得产物聚合松香的软化点为118 ℃.此外,该催化剂的使用有利于产物的分离且分离的离子液体催化剂具有良好的重复使用性能.     

Silver-Alkylamine Complex Mediated Single Micelle toward Synthesis of Sub-8 nm Silver Nanocrystals

Small size and narrow distribution are the key factors to improve performances of metal nanocrystals due to nanosize effect. Here, a silver-alkylamine complex–mediated single micelle, a one-pot approach, for controlled synthesis of monodisperse silver nanocrystals, in which oleylamine molecules play key roles serving both as complex agent and as micellar coalescence blocker is reported. After the synthesis, monodisperse products can be directly collected through subsequent single-step separation as the particle size is finely adjusted during the synthesis. Dual-soluble silver oleylamine complex is prepared through liquid phase complexing and is used as oil-soluble precursor in single reverse micelle. The as-synthesized silver nanocrystals are very uniform with a controlled size of 6.00 ± 0.29 or 8.0 ± 0.40 nm and a narrow size distribution with a standard deviation (σ) of ≈5.0%. The protocol offers a general platform for fast synthesis of noble metal nanocrystals with rationally designed size and structure.     

Droplet‐Based Self‐Propelled Miniboat

Self‐propelled autonomous devices have huge application prospects in the field of environmental protection and energy. Nonetheless, the requirement of special chemicals or external electric and thermal energy limits their practical application. Here, a green self‐propelling method based on Laplace pressure originated from water droplets is reported. First, a triangle‐shaped miniboat composed of a superhydrophobic plate with an inclined superhydrophilic pore is fabricated. Water droplets put on superhydrophilic pore pass through the pore and form a jellyfish‐like jet, which further propels the miniboat to move spontaneously and directionally. The propelling distance, propelling time, and instantaneous propelling velocity of the miniboat is greatly affected by the pore size and the initial water droplet volume. Then, two types of devices are designed and installed on the miniboat to successively provide small water droplets from the reservoir or rain to realize the continuous and long‐distance self‐propelled motion. Moreover, a spindle‐shaped miniboat with two or four symmetrical and inclined pores is designed. Under propelling by the torque, the spontaneous and continuous rotation motion is also achieved. This finding will open a new avenue for a wide range of applications ranging from a detecting minirobot on the water surface to a power generation device from rain.     

TATB生成焓的量子力学计算

采用Hartree-Fock方法和密度泛函 BPW91方法,对TATB分子的几何结构进行了优化,计算了其电子能量和热运动的能量.计算并讨论了TATB的生成焓.结果表明,TATB分子中的苯环离域电子结构引起TATB生成焓计算的较大的系统偏差;利用具有相似离域电子结构的苯和NO的生成焓进行修正,计算得到的TATB生成热与实验结果符合较好.?     

Adsorption and biotransformation of 17β-estradiol in biological activated carbon adsorbers

As the first systematic study dealing with the adsorption of estrogens by granular activated carbon (GAC), the removal behavior of 17β-estradiol (E2) and its biotransformation product of estrone (E1) in fixed GAC columns was examined using four biological activated carbon (BAC) columns (BAC-1～BAC-4) generated by coating four GAC columns with detached microorganisms from the riverbed sediment of a representative drinking river water source containing lower content of natural organic matter (NOM). For comparison, parallel adsorption experiments were also performed using another four GAC columns (GAC-1～ GAC-4) packed by strictly following the configurations of four BAC columns. Adsorption experimental results obtained by intermittently spiking E2 over a total running period about 350 days into the river water mixed with or without a peaty water containing higher content of NOM showed that E2 was readily removed by adsorption and the combined adsorption/biodegradation. The vertical profiles of E2 and E1, which have great significance for better understanding and optimization of the adsorption process for removal of human estrogens, were also obtained.