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81.
The hyperbolic Eularian model is used as a mathematical framework for compressible multiphase flows. The formulation was obtained after an averaging process of the single phase Navier-Stokes equations. The closure of multi-component system leads to the volume fraction equation containing a non-conservative term and a pressure equilibrium condition. As a result the model equations cannot be written in a conservative form. To solve the equations a finite volume Godunov type computational approach is developed which uses an approximate Riemann solver combined with a numerical scheme to tackle the non-conservative terms. The approach accounts for pressure non-equilibrium. It enables resolving interfaces separating compressible fluids and captures the baroclinic source of vorticity generation. The computations are performed for various initial conditions and compared with theoretical and experimental data for a shock-bubble interaction problem. The investigated cases include acoustic wave transmission through isolated bubbles of helium and krypton. The numerical results illustrate the characteristic features of the evolving interfaces. The impulsively generated flow perturbations are dominated by the reflection and refraction of the shock and by the vorticity generation within the media. (© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
82.
83.
Candice Botuha Fabrice Chemla Franck Ferreira Julien Louvel Alejandro Pérez-Luna 《Tetrahedron: Asymmetry》2010,21(9-10):1147-1153
The stereoselective synthesis of alkynyl 1,2-amino alcohols by the addition of 3-chloro- and 3-methoxymethoxy- allenylzincs to chiral tert-butylsulfinylimines is described. The methodology is applicable to the preparation of alkynyl 2-amino-1,3-diols (O,N,O stereotriads) using α-alkoxy tert-butylsulfinylimines as chiral starting materials. The scope and limitations of the methodology along with recent applications to the efficient asymmetric syntheses of natural and/or bioactive alkaloids and polyhydroxylated alkaloids are presented. 相似文献
84.
In order to gain insight into the preactivation of merocyanine 540 (MC540) 1 for the photodynamic therapy (Gulliya et al., 1990a, Photochem. Photobiol. 52, 831-838) its photo-oxidation was investigated. After irradiation of MC540 1 on a preparative scale three main photodegradation products were isolated with 16-20% yields. They turned out to be derivatives of benzoxazole, thiouracil and thiohydantoin with the structures 4, 5 and 6, respectively. It may be possible that they contribute to the cytostatic and antiviral activity of preactivated MC540 1. 相似文献
85.
86.
Laurent Franck Grard Maral 《International Journal of Satellite Communications and Networking》2002,20(6):455-475
This paper presents and evaluates different routing schemes in a constellation of non‐geostationary satellites. Routing decisions may or may not take into account the state of the network. While taking into account the network state is likely to bring an improvement in both the network utilization and the quality of service, it also makes the routing architecture more complex. This paper proposes to evaluate the advantages and disadvantages of these different design approaches for routing. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
87.
Franck Pastor Malorie Trillat Joseph Pastor Etienne Loute 《Comptes Rendus Mecanique》2006,334(4):213-219
A nonlinear interior point method associated with the kinematic theorem of limit analysis is proposed. Associating these two tools enables one to determine an upper bound of the limit loading of a Gurson material structure from the knowledge of the sole yield criterion. We present the main features of the interior point algorithm and an original method providing a rigorous kinematic bound from a stress formulation of the problem. This method is tested by solving in plane strain the problem of a Gurson infinite bar compressed between rough rigid plates. To cite this article: F. Pastor et al., C. R. Mecanique 334 (2006). 相似文献
88.
Room‐Temperature Decarboxylative Alkynylation of Carboxylic Acids Using Photoredox Catalysis and EBX Reagents
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Franck Le Vaillant Dr. Thibaut Courant Prof. Dr. Jerome Waser 《Angewandte Chemie (International ed. in English)》2015,54(38):11200-11204
Alkynes are used as building blocks in synthetic and medicinal chemistry, chemical biology, and materials science. Therefore, efficient methods for their synthesis are the subject of intensive research. Herein, we report the direct synthesis of alkynes from readily available carboxylic acids at room temperature under visible‐light irradiation. The combination of an iridium photocatalyst with ethynylbenziodoxolone (EBX) reagents allowed the decarboxylative alkynylation of carboxylic acids in good yields under mild conditions. The method could be applied to silyl‐, aryl‐, and alkyl‐ substituted alkynes. It was particularly successful in the case of α‐amino and α‐oxo acids derived from biomass. 相似文献
89.
Franck Charmantray Nadia Touisni Laurence Hecquet Thierry Noguer Christine Mousty 《Electroanalysis》2015,27(6):1341-1344
This paper describes the development of an amperometric biosensor based on galactose oxidase (GAOx) immobilization within a laponite clay film deposited on Carbon Screen‐Printed Electrodes modified by electrodeposited Prussian Blue and coated with poly‐(O‐phenylenediamine) (PPD/PB/CSPEs). Amperometric performances of GAOx@laponite/PPD/PB/CSPEs bioelectrodes were determined using several GAOx substrates. Using these modified electrodes the reduction of enzymatically generated hydrogen peroxide was performed at ?0.2 V vs. Ag‐AgCl. In an initial attempt, E.Coli transketolase activity on its immobilized form was followed using a bienzymatic GAOx‐TK biosensor. 相似文献
90.
Dr. Damien Lhenry Dr. Manuel Larrouy Dr. Claire Bernhard Dr. Victor Goncalves Dr. Olivier Raguin Dr. Peggy Provent Dr. Mathieu Moreau Dr. Bertrand Collin Dr. Alexandra Oudot Dr. Jean‐Marc Vrigneaud Dr. François Brunotte Dr. Christine Goze Prof. Franck Denat 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(37):13091-13099
In molecular imaging, multimodal imaging agents can provide complementary information, for improving the accuracy of disease diagnosis or enhancing patient management. In particular, optical/nuclear imaging may find important preclinical and clinical applications. To simplify the preparation of dual‐labeled imaging agents, we prepared versatile monomolecular multimodal imaging probe (MOMIP) platforms containing both a fluorescent dye (BODIPY) and a metal chelator (polyazamacrocycle). One of the MOMIP was conjugated to a cyclopeptide (i.e., octreotide) and radiolabeled with 111In. In vitro and in vivo studies of the resulting bioconjugate were conducted, highlighting the potential of these BODIPY‐based bimodal probes. This work also confirmed that the biovector and/or the bimodal probes must be chosen carefully, due to the impact of the MOMIP on the overall properties of the resulting imaging agent. 相似文献