Unexpected reaction of melatonin derivatives with performic acid

A series of carbamate melatonin derivatives was treated with performic acid, providing tricyclic products with a 3-hydroxytetrahydropyrrolo[2,3-b]indole skeleton. An unusual migration of carbamate groups was observed in some cases, and the reaction appeared to be strongly dependent on the type of substituent in the phenyl ring of the phenylcarbamate group. Theoretical calculations suggest that the reaction is kinetically controlled.     

Inclusions of Waterman–Shiba spaces into generalized Wiener classes

The characterization of the inclusion of Waterman–Shiba spaces ΛBV^(p)$\Lambda {\mathit{BV}}^{(p)}$ into generalized Wiener classes of functions BV(q;δ)$\mathit{BV}(q;\delta )$ is given. It uses a new and shorter proof and extends an earlier result of U. Goginava.     

Determination of l-Ascorbic Acid after Chromatographic Separation

JPC – Journal of Planar Chromatography – Modern TLC - A simple and accurate analytical procedure is proposed for determination of L-ascorbic acid after chromatographic separation....     

Formation of crystalline inclusion compounds of poly (vinyl chloride) of different stereoregularity with γ-cyclodextrin

This work reports the formation and detailed characterization of the γ-cyclodextrin (γ-CD) inclusion compounds (ICs) formed with two poly (vinyl chloride) samples with different isotactic content. The ICs were characterized by X-ray diffraction, solid state ¹³C-NMR, solution ¹H-NMR, FT-infrared, differential scanning calorimetry, and thermogravimetric analysis. Experimental evidence of the inclusion of the guest polymer chains into the narrow channels created by the γ-CD crystalline host lattice has been obtained. Examination of coalesced poly (vinyl chlorides) (PVCs) obtained after the host γ-CD is removed reveals different characteristics specifically for the coalesced PVC sample with higher isotactic content. An increase in T_g was observed by DSC for this PVC. To the contrary, the T_g of the coalesced PVC sample with lower isotactic content is almost the same as that of the as-synthesized sample. Thermogravimetric analysis indicated that coalesced PVC with higher isotactic content acquires a degree of stabilization after modification by threading into and being extracted from its γ-CD IC. The results suggest that an irreversible conformational change takes place when PVC forms ICs with a solid host lattice like γ-CD. The PVC molecules extend and reorganize into a more stable conformation in the IC, consequently improving the properties of the coalesced sample. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2503–2513, 2007     

Difference between the 1/f noise spectral density before and after stress as a measure of the submicron MOS transistors degradation

The paper deals with the 1/f noise as a measure of the submicron MOS transistor degradation. As the reference point of the investigations has been assumed the plot of the 1/f noise drain voltage spectral density S_VD versus the channel length L of the long-channel device which in log-log scale is linear (1/L) at slope equals −1. A theoretical analysis and experimental investigations indicate that before stress decrease of the carrier effective mobility, when the MOS transistors channel becomes shorter, causes deviate down of the plot S_VD vs. L in comparison with the extrapolated linear plot of the long channel device. During stress the hot-electron effect leads to the out of controll generation of additional interface states near drain edge which influence on deviate up of the plot S_VD vs. L in comparison with the value before stress. The measure of the degradation due to the hot-electron effect is difference between S_VD after and before stress. It is showed that S_VD of the extrinsic transistors do not dependent on the parasitic resistances therefore the considerations concern both of the conventional and LDD-MOS devices. Moreover the fundamental conditions of the measurement have been determined     

Nonextensive model of self‐organizing systems

The article concerns the new nonextensive model of self‐organizing systems and consists of two interrelated parts. The first one presents a new nonextensive model of interaction between elements of systems. The second one concerns the relationship between microscopic and macroscopic processes in complex systems. It is shown that nonextensivity and self‐organization of systems is a result of mismatch between its elements. © 2013 Wiley Periodicals, Inc. Complexity 18: 28–36, 2013     

Stereoselectivity of the Hydrogen‐Atom Transfer in Benzophenone–Tyrosine Dyads: An Intramolecular Kinetic Solvent Effect

To be or not to be solvated is the decisive parameter that controls the photoinduced hydrogen‐atom transfer in diastereomeric ketone/phenol dyads. A kinetic solvent effect that refers to hydrogen bonding between the phenol and the solvent is suggested to be the main source of the stereoselective discrimination in the hydrogen transfer (see figure).