全文获取类型
收费全文 | 893篇 |
免费 | 18篇 |
国内免费 | 1篇 |
专业分类
化学 | 429篇 |
晶体学 | 3篇 |
力学 | 24篇 |
数学 | 113篇 |
物理学 | 214篇 |
无线电 | 129篇 |
出版年
2020年 | 17篇 |
2019年 | 10篇 |
2018年 | 7篇 |
2017年 | 7篇 |
2016年 | 8篇 |
2015年 | 13篇 |
2014年 | 12篇 |
2013年 | 38篇 |
2012年 | 35篇 |
2011年 | 62篇 |
2010年 | 25篇 |
2009年 | 23篇 |
2008年 | 39篇 |
2007年 | 38篇 |
2006年 | 34篇 |
2005年 | 35篇 |
2004年 | 33篇 |
2003年 | 27篇 |
2002年 | 38篇 |
2001年 | 24篇 |
2000年 | 29篇 |
1999年 | 21篇 |
1998年 | 15篇 |
1997年 | 12篇 |
1996年 | 27篇 |
1995年 | 21篇 |
1994年 | 18篇 |
1993年 | 13篇 |
1992年 | 18篇 |
1991年 | 20篇 |
1990年 | 12篇 |
1989年 | 11篇 |
1988年 | 16篇 |
1987年 | 7篇 |
1986年 | 9篇 |
1985年 | 10篇 |
1984年 | 12篇 |
1983年 | 6篇 |
1982年 | 7篇 |
1981年 | 9篇 |
1980年 | 4篇 |
1979年 | 8篇 |
1978年 | 4篇 |
1976年 | 8篇 |
1975年 | 10篇 |
1974年 | 13篇 |
1973年 | 4篇 |
1972年 | 8篇 |
1971年 | 5篇 |
1948年 | 3篇 |
排序方式: 共有912条查询结果,搜索用时 8 毫秒
11.
Xianwen Lou Hans-Gerd Janssen Henri Snijders Carel A. Cramers 《Journal of separation science》1996,19(8):449-456
The influence of pressure drop on retention, selectivity, plate height and resolution was investigated systematically in packed supercritical fluid chromatography (SFC) using pure carbon dioxide as the mobile phase. Numerical methods developed previously which enabled the prediction of pressure gradients, diffusivities, capacity factors, plate heights and resolutions along the length of the column were used for the model calculations. The effects of inlet pressure and supercritical fluid flow rate on selectivity and resolution are studied. In packed column SFC with pure carbon dioxide as the mobile phase, the pressure drop can have a significant effect on resolution. The flow rate is shown to have a larger effect than generally realized. The calculated data are shown to be in good agreement with the experimental results. Finally, the variation of the chromatographic parameters along a 5.5 meter long model SFC column is illustrated. The possibilities and limitations of using long packed columns in SFC are discussed. It is demonstrated that long columns with large plate numbers do not necessarily yield better separations. 相似文献
12.
13.
Kastelein RA Janssen M Verboom WC de Haan D 《The Journal of the Acoustical Society of America》2005,118(2):1172-1179
Receiving beam patterns of a harbor porpoise were measured in the horizontal plane, using narrow-band frequency modulated signals with center frequencies of 16, 64, and 100 kHz. Total signal duration was 1000 ms, including a 200 ms rise time and 300 ms fall time. The harbor porpoise was trained to participate in a psychophysical test and stationed itself horizontally in a specific direction in the center of a 16-m-diameter circle consisting of 16 equally-spaced underwater transducers. The animal's head and the transducers were in the same horizontal plane, 1.5 m below the water surface. The go/no-go response paradigm was used; the animal left the listening station when it heard a sound signal. The method of constants was applied. For each transducer the 50% detection threshold amplitude was determined in 16 trials per amplitude, for each of the three frequencies. The beam patterns were not symmetrical with respect to the midline of the animal's body, but had a deflection of 3-7 degrees to the right. The receiving beam pattern narrowed with increasing frequency. Assuming that the pattern is rotation-symmetrical according to an average of the horizontal beam pattern halves, the receiving directivity indices are 4.3 at 16 kHz, 6.0 at 64 kHz, and 11.7 dB at 100 kHz. The receiving directivity indices of the porpoise were lower than those measured for bottlenose dolphins. This means that harbor porpoises have wider receiving beam patterns than bottlenose dolphins for the same frequencies. Directivity of hearing improves the signal-to-noise ratio and thus is a tool for a better detection of certain signals in a given ambient noise condition. 相似文献
14.
Znabet A Blanken S Janssen E de Kanter FJ Helliwell M Turner NJ Ruijter E Orru RV 《Organic & biomolecular chemistry》2012,10(5):941-944
An efficient combination of MAO-N-catalyzed desymmetrization of cyclic meso-amines with Ugi-Smiles multicomponent chemistry produced optically pure N-aryl proline amides. This method represents the first report of a fully asymmetric Ugi-Smiles process. 相似文献
15.
16.
17.
A state-space model is described for continuous titrations based on first-order dynamics. The Kalman filter allows on-line monitoring of an empirically established setpoint in the titration curve. The algorithm advocated is examined for potentiometric titrations of ca. 10?3 M solutins of acids, silver(I) and copper(II). Only gross indications of the essential parameters such as the time constant and noise covariances are required. The computer-controlled titration system is compared with a conventional setpoint titrator. Especially in cases of slow response times and steep inflections, there are advantages in both accuracy and speed when the Kalman filter is applied. 相似文献
18.
Alex B. Scholten Jan W. de Haan Hans-Gerd Janssen Leo J. M. van de Ven Carel A. Cramers 《Journal of separation science》1997,20(1):17-23
Retention gape deactivated with Silicone OV-1701-OH show good chromatographic performance and remarkable stability against water induced stationary phase degradrdation. In an attempt to better understand the findamentals off the deactivation process using silanol terminated polysiloxanes, a fumed silica was deactivated with Silicon OV-1701-OH. In contrast to fused silic capillaries, fumed silica (Aerosil A-200) can be studied by 29Si cross-polarization magic-angle-spinning (CPMAS) NMR, thus serving as a model substrate for fused silica. Retention data from inverse gas chromatography at infinite dilurion and 29Si CP MAS NMR data of five Aerosil phases, differing in residual silanol surface concentration, are correlated with the aim of validating this approach for stationary phase characterization. A comparatively detailed model of the deactivating polymer layer that explains the observed absorption activities is deduced. Surface silanols are shown to play a key role in the polymer layer, the structure of which is of primary importance for the absorption behavior after deactivation. Contrary to common belief, the absolute silanol surface concentration after deativation is only of secondary importance for the overall absorption activity. High silanol surface concentrations enhance degradation of the polysiloxane chains into small cyclic fragments as well as subsequent absorption and immobolization to the silica substrate surface. The mobility of linear polysiloxane chains in the kHz regime (as determined bby NMR cross-polarization dynamics) appears to determine the extent which the residual silanols are accessible for analytes. It is therefore anticipated that there is an optimum silanol surface concentration of fused silica surfaces to be deactivated with silanol terminated polysiloxanes; it should be lazrge enough to adsord polymer fragments, but not large to avoid excessive residual silanol activity. 相似文献
19.
J. K. Klahn J. J. M. Janssen G. E. J. Vaessen R. de Swart W. G. M. Agterof 《Colloids and surfaces. A, Physicochemical and engineering aspects》2002,210(2-3):167-181
This paper deals with a phenomenon which plays an important role in the phase inversion process of emulsions. This process is governed by the interplay of coalescence of droplets, often leading to double emulsions, and the escape of those internal droplets. The latter process retards the inversion process. Coalescence has been the subject of many studies, contrary to the escape event. This paper addresses the escape process both theoretically and experimentally. The model developed analyses the rate of the escape of internal droplets from the mother droplet via a coalescence process, where the internal flow, as generated by the external flow, generates the viscous force for coalescence. Incomplete mixing in the droplet has been assumed. Experimental data on the escape rate of oil droplets from O/W/O emulsions have been analysed using a Computational Fluid Dynamics approach, where the model as indicated above has been incorporated. Experimental data and simulations compare very well. Data have been compared on varying the size of the inner droplets and the rotational speed of the vessel where the double emulsion has been formed and where the escape took place. 相似文献