Self－assembly of Novel Hetero[3]rotaxane, [2]Rotaxanes and [2]Catenane

One linear template 13 and one cyclophane template 15, both incorporating two electron rich 1,4‐dialkoxybenzene units and one diamide unit, have been synthesized. By utilizing donor‐acceptor interaction and/or intermolecular hydrogen bonding assembling principles, one novel hetero[3]rotazane 22·4Cl, possessing one neutral and one tetracationic ring components, has been synthesized from 13, through neutral [2]rotaxane 21 as intermediate. With 15 as template, tetracationic [2]catenane 23·4PF₆ was assembled by using donor‐acceptor interaction, but no neutral [2]rotaxane could be obtained under the typical conditions of hydrogen bonding assembling principle. The interlocked supramolecular compounds have been characterized and their spectral properties are investigated.     

强流电子束泵浦XeCl准分子激光动力学模型

强流电子束泵浦XeCl准分子激光动力学模型由三部分组成,即电子束能量沉积的计算;电子温度、电子反应速率的计算和化学/激光动力学。这个模型可以准确地预报小信号增益、吸收等激光特征量的时间变化规律。 该模型是在文献[1]、[2]、[3]报导的动力学模型的基础上提出的。采用四阶龙格_库塔法在VAX—11/780机器上进行数值求解。 计算给出XeCl准分子激光反应过程中各种粒子浓度、小信号增益、吸收、输出光强、激发速率以及平均电子能量随时间的变化规律。计算结果表明本征效率是激发速率,电流密度和工作气体(Ne/Xe/HCl)的各分压比的函数。 该模型可为高功率准分子激光器的研制提供设计参数和最佳实验条件。     

On the permutability of Bäcklund transformations: 1 infinitesimal Bäcklund transformations of the sine-Gordon equation

Letu′=B _a u be the Bäcklund transformation of the sine-Gordon equation, we prove that $$B_{a + \varepsilon } B_a^{ - 1} u = u + \varepsilon \sum\limits_{n = 0}^\infty {2D^{ - 1} } \frac{{\delta G_{n + 1} }}{{\delta u}}a^{2n} ,$$ where {G _n} is an infinite set of conserved densities of the sine-Gordon equation and η ⁿ ≡D ^?1δG _n /δu are just the symmetries obtained by Olver [17]. Basing upon this expansion, we prove the equivalence between the permutability of the infinitesimal Bäcklund transformations and the involution of the conserved densities of the sine-Gordon equation.     

Derivatives of 2H-pyrazolo[4,5-b]-1,4-thiazine

Derivatives of 2H-pyrazolo[4,5-b]-1,4-thiazine, which tend to undergo dimerization at the 2-methylene group were synthesized by reaction of 5-amino-3-methyl-4-thio-1-phenylpyrazole with -bromoacetophenones.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 265–268, February, 1989.     

A differential pulsewidth control loop for high-speed VLSI systems

For those adopting double data rate technology systems, the precise system timing plays a crucial role since both rising and falling edges of the system clock signal are used to sample the input data. Due to this requirement, it is necessary to accurately maintain the duty cycle of the clock signal at 50%. For a multistage clock buffer, a pulsewidth control loop (PWCL) circuit was therefore proposed to adjust the duty cycle of its output signal. This paper is aimed at introducing a new proposed differential PWCL (DPWCL) together with investigating its mechanism through a comprehensive theoretical analysis. By taking advantage of a differential topology, the dc offset in generating the control voltage can be removed thereby improving the duty cycle control accuracy. Moreover, the proposed DPWCL employs a low-pass filter to generate the reference voltage so that the DPWCL does not necessitate a 50% duty cycle reference clock.     

A Comprehensive Review of Rosmarinic Acid: From Phytochemistry to Pharmacology and Its New Insight

Polyphenolic acids are the widely occurring natural products in almost each herbal plant, among which rosmarinic acid (RA, C₁₈H₁₆O₈) is well-known, and is present in over 160 species belonging to many families, especially the Lamiaceae. Aside from this herbal ingredient, dozens of its natural derivatives have also been isolated and characterized from many natural plants. In recent years, with the increasing focus on the natural products as alternative treatments, a large number of pharmacological studies have been carried out to demonstrate the various biological activities of RA such as anti-inflammation, anti-oxidation, anti-diabetes, anti-virus, anti-tumor, neuroprotection, hepatoprotection, etc. In addition, investigations concerning its biosynthesis, extraction, analysis, clinical applications, and pharmacokinetics have also been performed. Although many achievements have been made in various research aspects, there still exist some problems or issues to be answered, especially its toxicity and bioavailability. Thus, we hope that in the case of natural products, the present review can not only provide a comprehensive understanding on RA covering its miscellaneous research fields, but also highlight some of the present issues and future perspectives worth investigating later, in order to help us utilize this polyphenolic acid more efficiently, widely, and safely.     

Cu(ii)/SPDO complex catalyzed asymmetric Baeyer–Villiger oxidation of 2-arylcyclobutanones and its application for the total synthesis of eupomatilones 5 and 6

A novel classical kinetic resolution of 2-aryl-substituted or 2,3-disubstituted cyclobutanones of Baeyer–Villiger oxidation catalyzed by a Cu(ii)/SPDO complex is reported for the first time, producing normal lactones in excellent enantioselectivities (up to 96% ee) and regioselectivities (up to >20/1), along with unreacted ketones in excellent enantioselectivities (up to 99% ee). The current transformation features a wide substrate scope. Moreover, catalytic asymmetric total syntheses of natural eupomatilones 5 and 6 are achieved in nine steps from commercially available 3-methylcyclobutan-1-one.

A novel classical kinetic resolution of Baeyer–Villiger oxidation catalyzed by a Cu(ii)/SPDO complex with excellent enantioselectivity, regioselectivity and wide substrate scope is reported for the first time and explore the synthetic application.     

基于S3F9488与CP2512的电子产品应用设计

运用电容触摸检测芯片CP2512与单片机S3F9488进行电路设计.触摸检测芯片CP2512通过检测电容的变化量来感知外界数据的变化,通过I2C协议把CP2512采集的数据送到S3F9488,S3F9488根据采集到的数据进行相应的功率控制.本文给出了CP2512与S3F9488的硬件设计图.该方案的设计可以使家电产品更加耐用、美观;能有效地提高产品的抗干扰能力,提升产品的品质.该电路的设计为家电产品提够了一种低成本解决方案,最终在电磁炉中得到了实现.     

激光干扰下红外成像系统性能预测研究

激光干扰是抑制红外成像系统现场性能的有效手段,为实现对激光干扰下红外成像系统性能预测,文中以激光干扰红外成像探测器的作用机理为基础,通过对红外成像系统吸收的激光能量与对比度增强之间的关系进行分析,得到干扰激光的能量与对比度增强之间的关系,进而修正红外成像系统的对比度阈值函数;并结合NVThermIP性能模型实现激光干扰对系统性能的预测,给出了仿真结果,为红外成像系统的性能预测评估和理论模型的继续完善提供依据。