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71.
Kan‐Yi Pu Yi Chen Xiao‐Ying Qi Chun‐Yang Qin Qing‐Quan Chen Hong‐Yu Wang Yun Deng Qu‐Li Fan Yan‐Qin Huang Shu‐Juan Liu Wei Wei Bo Peng Wei Huang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3776-3787
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007 相似文献
72.
73.
Kikue S. Burnham Robert Roth Faith Zhou Wenya Fan Emma Brouk Mehari Stifanos 《Journal of polymer science. Part A, Polymer chemistry》2006,44(24):6909-6925
In an attempt to develop a low‐k interlayer dielectric, adamantane‐diphenyldiethynyl moiety containing oligomer is prepared. Oligomerization of 1,3,5,7‐tetrakis[3/4‐ethynylphenyl]adamantane ( 4 ) is accomplished by a Glaser–Hay oxidative coupling with 1,3,5‐triethynylbenzene and phenylacetylene end‐capping agent. The CHCl3 soluble oligomer is then thermally treated by step‐curing at 200, 300, 380, and 450 °C for 30 min at each temperature under nitrogen flow to render a shiny void‐free black polymer. TGA analysis indicates that the polymer is stable under nitrogen up to 500 °C with a marginal decomposition up to 800 °C. Solid‐state 13C NMR, Raman scattering, and FTIR are used to characterize the structure of the polymer. The polymer consists of amorphous carbon networks with the adamantane moieties and nanosized graphitic regions (clusters), which are generated from the thermal crosslinking of the diphenyldiethynyl units. It shows a remarkably low linear coefficient of thermal expansion (~25 ppm/°C), presumably due to the presence of the disordered graphitic structure. Its high density (~1.21 g/cm3), refractive index (~1.80 at 632 nm), and Young's modulus (~17.0 GPa) are also consistent with the interpretation. This study reveals important details about the effect of microscopic structure on the macroscopic properties of the highly crosslinked polymer. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6909–6925, 2006 相似文献
74.
75.
A self-aligned diffusion process has been demonstrated in the fabrication of n-InP JFETs on semi-insulating InP. This process utilises the anisotropic and selective etching properties of InP/GaInAs materials. Using this technique, sub-micrometre gate lengths can be achieved even with conventional photolithography. Devices with trans-conductance of >35mS/mm, leakage current of < 10nA/mm and gate capacitance of <0.7pF/mm have been fabricated with a cutoff frequency of 7 GHz. 相似文献
76.
The binding of lomefloxacin to bovine lactoferrin (BLf) in a dilute aqueous solution was studied using fluorescence spectra. The binding constant (K) and the number of binding sites (n) were obtained by a fluorescence quenching method. The binding distance (r) and energy-transfer efficiency (E) between lomefloxacin and bovine lactoferrin were also obtained according to the mechanism of Fo?rster-type dipole-dipole nonradiative energy-transfer. The effect of lomefloxacin on the conformation of bovine lactoferrin was also analyzed by synchronous fluorescence spectroscopy. The interaction between lomefloxacin and bovine lactoferrin is strong. Lomefloxacin can affect the conformation of bovine lactoferrin to some degree. 相似文献
77.
Jian Song Chongcheng Fan 《Lightwave Technology, Journal of》1995,13(3):546-550
A simplified formula for the dispersion limit of single-mode-fiber intensity modulation/direct detection (IM/DD) systems is derived for arbitrary given normalized pulse width U, eye opening penalty X and source linewidth enhancement factor α. From the comparison with published theoretical analyses, computer simulation and experimental data, its validity and the limits of existing formulae are shown. Using this simple and general formula, one can easily obtain the dispersion limit of various fiber types under different working conditions in IM/DD systems 相似文献
78.
The analysis of an arbitrarily inclined slot on the ground plane of a microstrip line is presented using the spectral domain approach and reciprocity theorem. Comparison of numerical results for the special case of a perpendicular slot with other available computed and measured data shows a good agreement. It is found that the impedance level can be controlled over a wide range by varying inclination angle. Results should be useful in antenna and multilayer circuit integration applications 相似文献
79.
主要作为电子高科技的重点领域,专用实时设备无论类别和型号,抑或数量和质量,均与日俱增,令人目不暇接。它们的高效管理与灵活加接,是任何计算机专用实时系统不可或缺的基本功能,其驱动模块随之成为任何专用实时系统无法回避的设计难点。本文介绍我们自行研制的专用实时设备驱动程序交互式生成器RTDG的设计与实现。 相似文献
80.
对于集成电路设计、生产过程中的多目标、多约束统计优化问题,本文提出了“合格率足够高”的优化宗旨,并从概率论的基本原理出发,结合集成电路的特点,导出了一种合格率的近似表述方法,提出的变权重Monte Carlo法编程简便,效率高。采用这些优化策略设计的集成电路合格率优化系统取得了比较好的结果。 相似文献