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81.
83.
星载扫描合成孔径雷达(ScanSAR)采取Burst工作模式,该模式在获得宽幅测绘能力的同时,也导致图像中产生了固有的扇贝效应,严重影响图像的视觉效果和定量应用。该文结合对ScanSAR图像方位向统计特性的分析,针对现有滤波模型稳定性差和时间复杂度高等缺点,提出了一种改进的Kalman滤波模型,对图像方位向标准差和均值进行滤波以校正扇贝条纹。在高分三号(GF-3)卫星获取的真实ScanSAR图像上的校正结果验证了改进算法的有效性和高效性,此外在建筑群和海陆交界等复杂场景图像上的实验结果表明,改进算法具有较强的鲁棒性。 相似文献
84.
海面高程3维成像是随着天宫二号发射而实现的技术,相位解缠是3维成像高度计高程反演的关键步骤.为改进Goldstein枝切法,缩短干涉相位图中枝切线的总长度,提升相位解缠的精确性,该文提出一种基于JVC全局最优线性分配算法生成枝切线的相位解缠方法.首先找出干涉相位图中的所有残差点并计算每一对异号残差点之间的距离;通过对比每对残差点之间的距离和各自与最近边界的距离和,确定采用JVC算法放置枝切线还是在残差点与边界之间直接放置枝切线,使得平衡枝切线的总长度最短.通过对3维成像高度计海面高程仿真干涉相位图和Etna火山地区干涉图像进行解缠实验并与其他3种算法进行对比,表明该算法的解缠结果与真实相位值误差相对较小,而且能够有效避免"孤岛现象"的产生. 相似文献
85.
86.
Hang GONG Nian Fa YANG? Wei Jun TANG Qing Hua FAN Li Wen YANG The College of Chemistry Xiangtan University Xiangtan Laboratory of Chemical Biology Center for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 《中国化学快报》2005,16(8)
Among the reactions in which C-C bonds are formed, the Baylis-Hillman coupling of aldehydes with α, β-unsaturated carbonylic compounds is currently attracting much interest due to the atom economy, the mild conditions and the generation of functional groups1,2. Furthermore, compared to the Heck, Suzuki and other palladium catalyzed C-C bond forming reaction3, the Baylis-Hillman reaction can be promoted by using organic bases in the complete absence of any metal4. However, almost all the … 相似文献
87.
A pyrryl substituted photocbromic fulgide, (1-p-methoxyphenyl-2-methyl-5-phenyl)-3-pyrryl-ethylidene (isopropylidene) succinic anhydride, was synthesized. Its chemical structure was identified by IR, 1H NMR MS and elemental analysis. The title compound was used to prepare the optical disks by the spin coating method and the vacuum evaporation method. The results of the static state examination show that the optical disks prepared with this kind of molecules possess excellent thermal stability and fatigue resistance, i.e. over 450 writing-erasing recycles, the relative contrast between writing state and erasing state remains at 40%. 相似文献
88.
Application of mono (6A-N-ethylenediamine-6A-deoxy) perphenylcarbamoylated β-cyclodextrin (β-CD) bonded stationary phase (CSP) in micro-high performance liquid chromatography (micro-HPLC) and pressurized capillary electrochromatography (p-CEC) was firstly presented. A series of racemic α-amidophosphonates were resolved in reversed- and normal-phase modes on this CSP. The investigated chromatographic parameters include retention factor (k′), separation factor (α) and resolution (Rs) of solutes. In addition, the structural variation of the solutes and the experimental factors affecting chiral separations have been examined, including the percentage of alcohol modifier, the linear velocity (u) of the mobile phase, electrical field strength, etc. Baseline separation was achieved for most of the entities. Hydrophobic interaction, steric effect and π-π interaction contribute to the possible mechanism. Comparative results indicate that higher Rs value up to 3.1 was found in micro-HPLC, higher efficiency up to 29,970 in p-CEC. 相似文献
89.
The glassy transition of the polyethylene terephthalate (PET) sampleswhich have been subjected to solvent induced crystallization (SINC) was investigated bymodulated differential scanning calorimetry (MDSC) and density measurement. The dif-ferential of heat capacity signal, d C_p/dT from MDSC, was used to monitor the SINCprocess. It reveals that the T_g temperature shifts to higher value with the advancement ofSINC. When the toluene-immersing time was longer (168h), the detection of T_g becomemore difficult, because some smaller peaks emerged at the lower temperatures and theseare explained as the movement of small segments in the amorphous region. These observedresults are due to the morphology and structure introduced by the SINC process. 相似文献
90.
Photochromism of two bispyrryl-substituted ethenes, 2, 3-bis-(1-p-methoxyphenyl-5-phenyl-2-methyl-3-pyrryl)-2-butene (BPE1) and 2,3-bis(1-p-bromophenyl-4-phenyl-2-methyl-3-pyrryl)-2-butene (BPE2), was studied by laser flash photolysis technique. The results indicate that photocyclization of these compounds proceeds mainly via the excited triplet state, and the cis-trans isomerization proceeds mainly via the excited singlet state. After UV laser pulse irradiation, both photocylization and cis-trans isomerization of BPEl occur, but photocydization is the main reaction. On the other hand, laser photolysis of BPE2 leads mainly to photocydization. The effects of the substituents on the photochromic mechanism are also discussed. 相似文献