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961.
Aleinikov N. N. Vasil'ev G. K. Kashtanov S. A. Makarov E. F. Chernyshev Yu. A. 《Kinetics and Catalysis》2001,42(2):233-237
The dependence of the rate of a photochemical reaction of XeO4with H2on the concentrations of H2and the diluent gases He and CO2is studied at room temperature. The results are compared with the data for the dark reaction. A mechanism with the elementary energetic branched-chain reaction OH
(v) + XeO4OH
+ O
+ XeO3is proposed to explain the results of the study. 相似文献
962.
A. N. Nesmeyanov I. B. Zlotina M. A. Khomutov I. F. Leshcheva N. E. Kolobova K. N. Anisimov 《Russian Chemical Bulletin》1977,26(3):642-643
Conclusions The cis-trans isomers of the vinylic fluorine substitution product were isolated and characterized when Na[5-C5H5Fe(CO)2] is reacted with ethyl perfluoromethacrylate.Deceased.The authors express their gratitude to E. M. Rokhlin and U. Utebaev for supplying the ethyl perfluoromethacrylate.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 705–706, March, 1977. 相似文献
963.
964.
T. Sato F. Ambe K. Endo M. Katada H. Sano 《Journal of Radioanalytical and Nuclear Chemistry》1995,190(2):257-261
The crystal structures of oxo-centered trineclear cobalt-iron chloroacetate complex [CoIIFe
2
III
O(CH2ClCO2)6(H2O)3]·3H2O (1) was compared with that of previously reported trinuclear iron complex [FeIIFe
2
III
O(CH2ClCO2)6(H2O)3]·3H2O (2) which has an isomorphous structure to 1. Compound 1 crystallizes in space group P21/n with Z=4 in a unit cell of a=14.826 (4) Å, b=4.536 (8) Å, c=14.000 (4) Å, =100.32 (2)0 and V=2968 (11) Å3. The structure was refined to R=0.75 and Rw=0.82. The coordination geometries of the three iron atoms are observed equivalent in 1 indicating a static disorder of the position among cobalt and iron atoms. Two distinct FeIII doublets observed in Mössbauer spectra of 1 become an indistinguishable broad doublet by dehydration of crystal water. On the other hand, no significant line-broadening is observed after the dehydration in complex 2. The results indicate that the dehydration in 2 induces a local environmental change reordering of an electronic configuration around iron atoms, whereas the remaining disordering is reflected in Mössbauer spectrum after the dehydration in 1. 相似文献
965.
966.
L. S. Andreeva A. A. Andrianov V. E. Bel'skii M. F. Vavilova É. A. Gurylev K. V. Nikonorov 《Russian Chemical Bulletin》1971,20(10):2219-2221
Conclusions The hydrolysis of chloroacetophos in water includes the parallel cleavage of acetic acid, hydrochloric acid and methanol. The ratio of the products, formed in the parallel steps, was determined, and we also determined the total rate constant for the hydrolysis of chloroacetophos.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2336–2338, October, 1971. 相似文献
967.
968.
The equilibrium volatilities at near infinite dilution of various solutes absorbed in molten polystyrene have been determined by a gas chromatographic technique. This method is much more rapid, although, with the present apparatus, probably less accurate than conventional static techniques. The primary parameters obtained from measurements of retention volumes are the Henry's law constants, from which are derived the weight and volume fraction activity coefficients, the Flory-Huggins interaction parameters, and the heats of dilution and solution. Of the solutes investigated, 2-butanone (MEK) was the least, and benzene the most compatible (highest and lowest volume fraction activity coefficients, respectively) with molten polystyrene. A small, but definite, variation of the activity coefficients with polystyrene molecular weight was observed. 相似文献
969.
970.
Sources of error in the fast neutron activation analysis determination of oxygen have been investigated and minimised. The oxygen contents of eighteen international rock standards and a sulphide ore standard have been determined, and compared with the values calculated by difference using the reported full analyses. Accuracies of 0.3% average deviation and reproducibilities of ±0.2% standard deviation have been obtained, where oxygen contents exceeded 1.0 g. 相似文献