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991.
E. Tamez M. T. Olguín N. Segovia S. Bulbulian F. Abascal 《Journal of Radioanalytical and Nuclear Chemistry》1986,103(4):231-240
Experiments were designed to measure trace uranium concentration and the rate of radon exhalation from masonry structural materials, both bare and surface finished and coated. LR115 cellulose nitrate track detectors were used to record the alpha emission from structural material surface. Fission track, neutron activation and fluorometric analysis methods were used to determine the uranium content. Most types of paints studied will reduce alpha contribution and radon emanation from building materials. 相似文献
992.
trans-1,2,3,4,4a,5,6,10b-Octahydrophenanthridine, the 9-methoxy analog, and 5-methyl derivatives ( 6a,6b ) of each have been synthesized from trans-phenylcyclohexylamines ( 2a,2b ) and ethyl chloroformate followed by cyclization and reduction or by cyclization, N-methylation and reduction. The oximes ( la,1b ) of 2-phenylcyclohexanone and the m-methoxy relative, a mixture of the syn and anti isomers, were reduced to 2a and 2b with sodium and ethanol. Hydrogenation (platinum oxide-acetic acid) of 1a gave in addition to 2a , a small yield of 2-cyclohexylcyclohexyl-amine. Similar hydrogenation of 1b gave only this fully reduced compound. 相似文献
993.
It is demonstrated that a previously developed topological expression for the total π-electron energy of aromatic molecules provides a good qualitative account of localization energies. The logarithm of the ratio of the algebraic structure counts for the ground state and the localized reaction intermediate is the principle energy determining factor. This expression fails for hydrocarbons with unusually small HOMO-LUMO separations. An alternative topological expression that includes a correction for this situation provides an excellent non-empirical explanation for the successful empirical use of Dewar reactivity numbers in correlating exact localization energies. The present analysis provides an explanation for the success of the traditional resonance structure counting technique in predicting relative rates of aromatic substitution. The analysis develop applied only to alternant hydrocarbons. 相似文献
994.
All the amines studied are absorbed in excess of the exchange capacity bysulfonated polystyrene resins from aqueous solutions; the absorption is greatest with benzylamine, whose molecular structure is the closest to that of the monomer of the resin. The absorption is greater, then less the crosslinking of the resin, and it is influenced by the electrostatic field of the resin cations. There is no excess absorption from solvents such as alcohols, acetic acid or dioxane. The absorption characteristics of amines are sufficiently different that separations by elution chromatography on cation exchange resins are possible. Two such separations have been demonstrated. For quantitative analytical use, however, it would be wise to use very fine mesh resins on account of the slowness of diffusion of large amine molecules within the resins. 相似文献
995.
Zusammenfassung 4-O-Methyl-7,8-dehydro-metathebainon-methin (1) geht in alkalischer Lösung in das Naphthalin-Derivat3 über, das unter Abspaltung von Formiat7 liefert. Das Auftreten von3 kann durch Isolierung von13a nach Reduktion mit NaBH4 nachgewiesen werden. Die aus3 und7 durch Reduktion erhaltenen Alkohole8a und13a werden in saurer Lösung unter Methanol-Abspaltung zu den 2,3-Dihydro-naphtho[1,8-bc]pyranen9 und14 cyclisiert.
Mit 2 Abbildungen 相似文献
A new rearrangement of a metathebainone derivative with a cyclohexa-2,5-dienone groupment
4-O-Methyl-7.8-dehydrometathebainonemethine (1) in alkaline solution rearranges to the naphthalene derivative3, which eliminates formiate to give7. The occurrence of3 was confirmed by isolation of13a after reduction with NaBH4. The hydroxy compounds8a and13a, obtained by reduction, eliminate methanol and cyclize to the 2.3-dihydronaphtho[1.8-bc]pyrans9 and14.
Mit 2 Abbildungen 相似文献
996.
J L Straughan W F Cathcart-Rake D W Shoeman D L Azarnoff 《Journal of chromatography. A》1978,146(3):473-480
Chlordiazepoxide and its 4 major metabolites were assayed after separation by thin-layer chromatography following extraction from biological fluids. The compounds become intensely fluorescent in the presence of red, fuming nitric acid. The resulting compounds are quantitated with a spectrodensitometer with a fluorescent attachment. The sensitivity varies between 0.05 and 0.1 microgram. The coefficient of variation is 1.4% for assays in urine and 6.4% in serum. 相似文献
997.
F. Sanem Koçak 《Journal of organometallic chemistry》2006,691(23):5030-5037
Thermal substitution reaction of Cr(CO)4(η2:2-1,5-cyclooctadiene), Mo(CO)4(η2:2-norbornadiene), and W(CO)5(η2-bis(trimethylsilyl)ethyne) with N,N′-bis(ferrocenylmethylene)ethylenediamine (bfeda) yields M(CO)4(bfeda) complexes which could be isolated from the reaction solution and characterized by elemental analysis, MS, IR, and NMR spectroscopy. In the case of tungsten, W(CO)5(bfeda) is formed as intermediate and then undergoes the ring closure reaction yielding the ultimate product W(CO)4(bfeda). The electrochemical behavior of the M(CO)4(bfeda) complexes was studied by using cyclic voltammetry (CV) and differential pulse voltammetry (DPV) in dichloromethane with tetrabutylammonium tetrafluoroborate as electrolyte. Constant potential electrolysis of the complexes was performed successively at their peak potentials at 0 °C in their CH2Cl2 solution and the electrolysis was followed by in situ recording the electronic absorption spectra in every 5 mC. In the electrolysis of Cr(CO)4(bfeda), the central Cr(0) is oxidized first and electrolysis continues with oxidations of two ferrocenyl groups until the end of totally three moles of electron passage per mole of complex. In the electrolysis of Mo(CO)4(bfeda) and W(CO)4(bfeda) the first oxidation occurs on the central atom forming a short-lived species which undergoes an intramolecular one-electron transfer and is reduced back to M(0) while one of the ferrocene units is oxidized to the ferrocenium cation at the same time. This indicates that the electron is transferred from iron to the central metal atom. 相似文献
998.
Alan S.F. BoydGraeme Cooke Florence M.A. DuclairoirVincent M. Rotello 《Tetrahedron letters》2003,44(2):303-306
We have investigated the electrochemically controlled hydrogen bonding interactions between tetrathiafulvalene host 3 and guests 4 or 5. Stabilisation of the 3+ state is dependent upon the nature of the guest species, whereas both guests prevent precipitation of the electrochemically generated 32+ species at the working electrode via hydrogen bonded molecular recognition processes. 相似文献
999.
The porcine neurotubule and its basic subunit were found to be modified in vitro by iodination of amino acids (principally tyrosine) using lactoperoxidase. Iodide ion, H2O2, or lactoperoxidase singly or in any pairwise combination had virtually no effect on neurotubules. However, when all three reagents were present, permitting covalent iodination, it was found that at 0.1 iodotyrosines per tubulin dimer the microtubules unravel to form structures which morphologically resemble strands of protofilaments twisted or wound around each other. These abnormal tubules are stable at room temperature and 4 degrees C. Both monomers of tubulin are labeled to approximately the same extent. Iodinated tubulin (0.1 iodotyrosines/dimer) is unable to assemble in vitro under normal assembly conditions. Heavily iodinated microtubules (8 iodines per tubulin dimer) are similar in morphology to the slightly iodinated structures. 相似文献
1000.
I. F. Abdullin E. N. Turova G. K. Ziyatdinova G. K. Budnikov 《Journal of Analytical Chemistry》2002,57(4):353-355
It was found that an iodine-modified platinum electrode gives a linear potentiometric response to 1.0 × 10–5 to 1.0 × 10–3 M ascorbic acid in model solutions. Ascorbic acid in some preparations was determined by potentiometry. The contribution of ascorbic acid to the total antioxidant capacity of aqueous extracts of hips, hop cones, and lemon juice was estimated. 相似文献