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201.
Scott T. Knauert Jack F. Douglas Francis W. Starr 《Journal of Polymer Science.Polymer Physics》2007,45(14):1882-1897
Nanoparticles can influence the properties of polymer materials by a variety of mechanisms. With fullerene, carbon nanotube, and clay or graphene sheet nanocomposites in mind, we investigate how particle shape influences the melt shear viscosity η and the tensile strength τ, which we determine via molecular dynamics simulations. Our simulations of compact (icosahedral), tube or rod‐like, and sheet‐like model nanoparticles, all at a volume fraction ? ≈ 0.05, indicate an order of magnitude increase in the viscosity η relative to the pure melt. This finding evidently can not be explained by continuum hydrodynamics and we provide evidence that the η increase in our model nanocomposites has its origin in chain bridging between the nanoparticles. We find that this increase is the largest for the rod‐like nanoparticles and least for the sheet‐like nanoparticles. Curiously, the enhancements of η and τ exhibit opposite trends with increasing chain length N and with particle shape anisotropy. Evidently, the concept of bridging chains alone cannot account for the increase in τ and we suggest that the deformability or flexibility of the sheet nanoparticles contributes to nanocomposite strength and toughness by reducing the relative value of the Poisson ratio of the composite. The molecular dynamics simulations in the present work focus on the reference case where the modification of the melt structure associated with glass‐formation and entanglement interactions should not be an issue. Since many applications require good particle dispersion, we also focus on the case where the polymer‐particle interactions favor nanoparticle dispersion. Our simulations point to a substantial contribution of nanoparticle shape to both mechanical and processing properties of polymer nanocomposites. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1882–1897, 2007 相似文献
202.
203.
Existing NASA supported scientific databases are usually developed and managed by a team of database administrators whose main concern is the efficiency of the databases in terms of normalization and data search constructs. The populating of the database is usually done in a manual fashion by row and column as the data become available, and the data dictionary is usually defined by the same team (at times with little input from the end science user). This process is tedious, error prone and self-limiting in terms of what can be described in a relational Data Base Management System (DBMS). The next generation Earth remote sensing platforms [i.e., Earth Observing System (EOS)] will be capable of generating data at a rate of over 300 Megabits per second from a suite of instruments designed for different applications. What is needed is an innovative approach that creates object-oriented data-bases that segment, characterize, and catalog, and are manageable in a domain-specific context, and whose contents are available interactively and in near-real-time to the user community. This paper describes work in progress that utilizes an artificial neural net approach to characterize satellite imagery of undefined objects into high-level data objects. The characterized data is then dynamically allocated to an object-oriented database where it can be reviewed and accessed by a user. The definition, development, and evolution of the overall data system model are steps in the creation of an application-driven knowledge-based scientific information system. 相似文献
204.
In this paper, we discuss the local and global existence ofweak solutions for some hyperbolicparabolic systems modellingchemotaxis. 相似文献
205.
206.
Operation of a 16-tap fiber-optic delay line configured as a bandpass filter with a fundamental frequency of 2.0 GHz over the frequency range from 0 to 12.5 GHz is discussed. Equal tap weights and spacings were used to facilitate comparison of experimental and predicted results. More than 1011 analog multiplications per second are performed in this relatively simple signal processing system. Other processors for performing functions such as matched filtering and correlation can be implemented by appropriate choice of the mirror reflectances and fiber lengths 相似文献
207.
Hwang H.-K. Lee L.-S. Chen S.-H. 《Selected Areas in Communications, IEEE Journal on》1989,7(9):1450-1461
Multi-H phase-coded modulation (MHPM) is a bandwidth-efficient modulation scheme which offers substantial coding gain over conventional digital modulation schemes. MHPM with asymmetric modulation indices corresponding to the bipolar data +1 and -1 is considered, and numerical results for the minimum Euclidean distances are provided. It is shown that performance improvements on the error probability over conventional MHPM are gained with essentially the same bandwidth and a very slight modification in implementation. The upper bounds on the error probabilities as functions of observation intervals and received E b/N 0 are also investigated in detail. It is concluded that the concept of asymmetric modulation indices for MHPM is attractive for bandwidth and power-efficient modulation 相似文献
208.
K. Stein und F. Umland 《Fresenius' Journal of Analytical Chemistry》1986,323(2):176-177
Ohne Zusammenfassung
Wir danken dem Fonds der Chemischen Industrie für finanzielle Unterstützung. 相似文献
Trace analysis of lead, cadmium and manganese in honey and sugar
Wir danken dem Fonds der Chemischen Industrie für finanzielle Unterstützung. 相似文献
209.
A compact Ku -band phase-locked oscillator module has been developed in a full MMIC (monolithic microwave integrated circuit) configuration. The module includes an MMIC voltage-controlled oscillator, an analog frequency divider, and interstage amplifiers. The constituent monolithic chips are integrated in a very small single-package module and operate at the target frequencies without any external trimming or matching network. The oscillator is tuned more than 1 GHz with a constant output amplitude. The frequency-divided output is also obtained over the whole tuning range. Spurious output is not found at any frequency up to 22 GHz. In spite of the very low-Q factor of GaAs monolithic circuitry, the oscillator phase noise exhibited is less than -80 dBc/Hz, due to the high-gain, high-speed phase lock 相似文献
210.
R. Toledo-Marin F.A. Cruz-Perez L. Ortigoza-Guerrero 《Electronics letters》2007,43(7):399-401
A new mathematical method to analyse the performance of guard-channel-based strategies is proposed. The analysis is based on the iterative calculation of the average effective channel holding time. The method presented provides higher accuracy than alternative solutions previously reported in the literature 相似文献