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91.
When the matrix of distances between cities is symmetric and circulant, the traveling salesman problem (TSP) reduces to the so-called symmetric circulant traveling salesman problem (SCTSP), that has applications in the design of reconfigurable networks, and in minimizing wallpaper waste. The complexity of the SCTSP is open, but conjectured to be NP-hard, and we compare different lower bounds on the optimal value that may be computed in polynomial time. We derive a new linear programming (LP) relaxation of the SCTSP from the semidefinite programming (SDP) relaxation in [E. de Klerk, D.V. Pasechnik, R. Sotirov, On semidefinite programming relaxation of the traveling salesman problem, SIAM Journal of Optimization 19 (4) (2008) 1559-1573]. Further, we discuss theoretical and empirical comparisons between this new bound and three well-known bounds from the literature, namely the Held-Karp bound [M. Held, R.M. Karp, The traveling salesman problem and minimum spanning trees, Operations Research 18 (1970) 1138-1162], the 1-tree bound, and the closed-form bound for SCTSP proposed in [J.A.A. van der Veen, Solvable cases of TSP with various objective functions, Ph.D. Thesis, Groningen University, The Netherlands, 1992]. 相似文献
92.
The present work reports on the synthesis and evaluation of a crosslinkable thiolated gelatin derivative. The effect of varying two parameters including the pH of the reaction buffer and the thiolating agent applied (i.e. N-acetylhomocysteine thiolactone versus Traut’s reagent) on the obtained modification degree was studied in a first part. The gelatin derivatives synthesized starting from N-acetylhomocysteine thiolactone and Traut’s reagent were characterized in depth using size exclusion chromatography and UV–VIS spectrophotometry. In a subsequent part of the present work, hydrogel films were prepared starting from the thiolated gelatin derivative developed using N-acetylhomocysteine thiolactone. The contributions of both the chemical and the physical crosslinking of the hydrogels developed were studied in depth using rheology, swelling experiments and texturometry. The results indicate that the physical structuring, inherent to gelatin, contributes to a large extent to the mechanical properties. However, the chemical crosslinking mostly determines the final hydrogel properties and can be controlled to a large extent. The gelatin-based gels are flexible, strong and transparent. A major advantage of disulfide-crosslinked hydrogels is the fact that the crosslinking is reversible. The latter could be interesting in view of future applications as cell carriers for tissue engineering. 相似文献
93.
Louguet S Kumar AC Sigaud G Duguet E Lecommandoux S Schatz C 《Journal of colloid and interface science》2011,359(2):413-422
The adsorption behavior of poly(ethylene oxide)-b-poly(L-lysine) (PEO(113)-b-PLL(10)) copolymer onto silica nanoparticles was investigated in phosphate buffer at pH 7.4 by means of dynamic light scattering, zeta potential, adsorption isotherms and microcalorimetry measurements. Both blocks have an affinity for the silica surface through hydrogen bonding (PEO and PLL) or electrostatic interactions (PLL). Competitive adsorption experiments from a mixture of PEO and PLL homopolymers evidenced greater interactions of PLL with silica while displacement experiments even revealed that free PLL chains could desorb PEO chains from the particle surface. This allowed us to better understand the adsorption mechanism of PEO-b-PLL copolymer at the silica surface. At low surface coverage, both blocks adsorbed in flat conformation leading to the flocculation of the particles as neither steric nor electrostatic forces could take place at the silica surface. The addition of a large excess of copolymer favoured the dispersion of flocs according to a presumed mechanism where PLL blocks of incoming copolymer chains preferentially adsorbed to the surface by displacing already adsorbed PEO blocks. The gradual addition of silica particles to an excess of PEO-b-PLL copolymer solution was the preferred method for particle coating as it favoured equilibrium conditions where the copolymer formed an anchor-buoy (PLL-PEO) structure with stabilizing properties at the silica-water interface. 相似文献
94.
T. Mlin F. Lelarge B. Etienne F. Laruelle 《Physica E: Low-dimensional Systems and Nanostructures》1998,2(1-4)
We report on new features in the photoluminescence excitation (PLE) spectra and PLE linear polarization spectra of GaAs/AlAs lateral superlattices grown by molecular beam epitaxy (MBE). These lines appear systematically as the tilt angle of the lateral superlattice is varied. They are identified as zone–edge excitonic transitions by comparison between experimental data and detailed numerical calculations of optical transitions including valence-band mixing and tilt effects. 相似文献
95.
Quantum wires superlattices have been grown on GaAs vicinal surfaces. Their electrical resistance anisotropy, their low-field magnetoresistance (for current flow perpendicular to the wires) and, in the magnetic quantum limit, the van Hove singularities of the Landau bands, and the very sudden enhancement of the spin splitting above a critical field, all demonstrate unambiguously that a strong low-disordered periodic lateral potential modulation can be achieved as a result of significant atomic ordering by the steps. 相似文献
96.
97.
One can expect to get the electron-hole (EHD) binding energy φ either from spectroscopic or from threshold measurements. While the value obtained by the former is in excellent agreement with theory, the results given by the latter did not seem to lead to φ in a simple way. We present here new optical threshold studies in which we think that the right conditions to obtain a direct thermodynamic measurement of φ have been mastered. Besides, our results present novel features like a sharp jump of the EHD luminescence at threshold above 2.4 K and observation of hysteresis in the whole temperature range of our work. 相似文献
98.
In this paper, we report results dealing with the effects of stoichiometry on surface properties of GaAs(001) layers grown by MBE. Three aspects of surface properties were investigated: crystallography, electronic properties and chemical reactivity. Surface crystallography was studied mainly by LEED. The reconstruction of the surface was found to be drastically dependent on the composition of the uppermost atomic layer, i.e. the surface stoichiometry. According to the arsenic surface coverage, many structures from the c(8 × 2) Ga rich to the (1 × 1) arsenic saturated surface have been observed. The influence of stoichiometry on surface electronic properties has been studied by electron loss spectroscopy (ELS) and contact potential difference (CPD) measurements. In the electron loss spectra, two peaks, at about 10.3 and 20.2 eV are very sensitive to the surface composition: they gradually disappear when the arsenic coverage increases, and consequently are associated with surface states on gallium atoms. On the other hand, the CPD measurements have shown that the variation of the work function with the arsenic surface coverage is not monotonic: in particular, an abrupt change of work function of about 300 meV occurs between the (1 × 6) and c(2 × 8) structures which are very similar as far as the arsenic surface coverage (about 0,5 and 0,6 respectively) is concerned. Therefore, it seems that the work function is strongly dependent on the atomic reconstruction occurring at the surface, and not only on its stoichiometry. The connection between stoichiometry and chemical reactivity of the surface is illustrated by the study of H2S adsorption: a large difference (factor of 103) in sticking coefficient has been found between surfaces with different arsenic coverages. 相似文献
99.
The theoretical considerations and the experimental data to calculate the activation energy of the ethylene oligomerization using a microreactor in a differential thermal analyzer are presented. 相似文献
100.
P. Etienne T. Woignier A. Alaoui J. Phalippou 《Journal of Sol-Gel Science and Technology》1997,8(1-3):801-806
The mechanical behaviour of silica aerogels in alcoholic environment has been interpreted in terms of stress corrosion in
analogy with silica glass. The chemical susceptibility factor has been determined by the dynamical method and we also measured
the Weibull’s modulus which characterizes the strength distribution. These data show a stress corrosion effect which is significant
in alcoholic atmosphere. The results could explain a possible fracture of gels during the supercritical drying treatment as
already observed. 相似文献