Structure of absintholide a new guaianolide dimer of Artemisia absinthium L.

Absintholide $\text{1}$ is a new guaianolide dimer whose structure and stereochemistry has been elucidated on the basis of high resolution n.m.r.     

Programming problems in mathematical logic

In the early days of computing, special machines were built for solving logical (as opposed to numerical) problems. Experience in several significant problems of Mathematical logic has indicated that a general purpose machine can be used simply and effectively, provided a powerful programming language is available.     

Tensor spline approximation

The cyclic-shift tensor-factorization interpolation method recently described by de Boor can be used in particular for least-squares fitting of multivariate data on a rectangular grid and for evaluation of the resulting tensor-product splines, taking advantage of existing linear algebra and univariate spline software. We discuss the computational details of this method, pointing out variants and suggesting techniques for dealing with ill-conditioned least-squares problems.     

Accuracy of semiclassical dynamics in the presence of chaos

We review some of the issues facing semiclassical methods in classically chaotic systems, then demonstrate the long-time accuracy of semiclassical propagation of a nonstationary wave packet using the quantum baker's map of Balazs and Voros. We show why some of the standard arguments against the efficacy of semiclassical dynamics for long-time chaotic motion are incorrect.     

Dual mode model for mixed gas permeation of CO2, H2, and N2 through a dry chitosan membrane

Dry chitosan is an excellent candidate for facilitated transport membranes that can be utilized in industrial applications, such as fuel cell operations and other purification processes. This article is the first to report temperature effects on transport properties of CO₂, H₂, and N₂ in a gas mixture typical of such applications. At a feed pressure of 1.5 atm, CO₂ permeabilities increased (0.381–26.1 barrers) at temperatures of 20–150 °C with decreasing CO₂/N₂ (19.7–4.55) and CO₂/H₂ (3.14–1.71) separation factors. The pressure effect on solubilities and permeabilities were fitted to the extended dual mode model and its corresponding mixed gas permeation model. The dual mode and transport parameters, the sorption heats and the activation energies of Henry's and Langmuir's regimes and their pre‐exponential parameters were determined. The Langmuir's capacity constants were utilized to estimate chitosan's glass transition temperature (CO₂: 172 °C, N₂: 175 °C, and H₂: 171 °C). The activation energies of diffusion in the Henry's law and Langmuir regimes were dependent on the collision diameter of the gases. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2620–2631, 2007