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Elaheh Rohani Rad Henri Vahabi Krzysztof Formela Mohammad Reza Saeb Sabu Thomas 《先进技术聚合物》2019,30(9):2250-2260
Although significant progress has been made in the design and application of injectable hydrogels for biomedical applications, concurrent control of rheological and mechanical properties of injectable hydrogels has remained as an open challenge to the researchers. In this work, we introduce and put into practice a photo‐curable poloxamer (also known as Pluronic)/graphene oxide (Plu/GO) injectable hydrogel with well‐controlled rheological and mechanical properties. Acrylate group was anchored to hydrogel structure to endow photo‐crosslinking ability through decelerating degradation rate of poloxamer hydrogels after injection. It was found that the modified Plu remains stable in biological media for a long‐term period without significant weight loss. Rheological properties of hydrogels were also carried out as essential prerequisite for an ideal injectability via frequency sweep, flow curve, recovery, and yield stress before and after modification, signifying shear‐thinning behavior of Plu/GO hydrogels with high recoverability. The viscosity of shear‐thinning‐like hydrogels dropped at higher shear stress, which facilitated injection process. Moreover, mechanical behavior of Plu was optimized by manipulating the content of Plu, degree of modification with reactive precursor, curing, and particularly incorporation of GO without deteriorating effects on rheological behavior of Plu. 相似文献
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Kowsari Elaheh Morad Fariba Seifvand Naemeh Bazri Behrouz Karimi Maryam 《Research on Chemical Intermediates》2020,46(2):1217-1234
Research on Chemical Intermediates - A nanostructured composite material was produced through sol–gel-assisted ionic liquid (IL) synthesized TiO2, WO3 and functionalized reduced graphene... 相似文献
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Namvar-Mahboub Mahdieh Khodeir Elaheh Karimian Azam 《Research on Chemical Intermediates》2018,44(11):6877-6893
Research on Chemical Intermediates - Magnetic graphene oxide (GO)/amino-functionalized Fe3O4 nanocomposite was prepared using tannic acid as binder. For this purpose, Fe3O4 nanoparticles were... 相似文献
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Abolghasem Jouyban Masoumeh Abbasi Elaheh Rahimpour Mohammad Barzegar-Jalali Jalil Vaez-Gharamaleki 《Physics and Chemistry of Liquids》2018,56(5):619-626
The solubility of deferiprone (DFP) in five organic solvents including ethyl acetate, chloroform, acetonitrile, 1,4-dioxane and dichloromethane was investigated by the flask-shake method under atmospheric pressure at temperatures ranging from 293.15 to 313.15 K. In general, the solubility (mol L–1) obeyed the following order from high to low in different mono-solvents: dichloromethane > chloroform > acetonitrile > 1,4-dioxane > ethyl acetate. The solubility of DFP in the mono-solvents increased with a rise of temperature. The solubility data were successfully correlated with the van’t Hoff equation. The generated data in this work and the previously published data were used to calculate the thermodynamic parameters of the system using the modified van’t Hoff equation, and the derived thermodynamic properties were correlated using Abraham solvation parameters. 相似文献
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The role of molecularly imprinted polymers (MIPs) is changing from academic to applied researches. Challenging problems about MIP will be more highlighted in applicable uses and solving these problems is vital. The controlled/“living” radical polymerization (CLRP) techniques are applicable to solve the challenging problems in MIPs. The “living” nature of CLRP helps to improve the heterogeneity of binding sites in MIPs as a main challenge where precise control over sizes, compositions, and surface functionalities is achieved. Among different techniques of CLRP, reversible addition-fragmentation chain transfer (RAFT) technique presents distinguished benefits such as compatibility and tolerance to a wide range of functional monomers and mild reaction conditions rather than other CLRP techniques. In this review, in order to obtain more insights into the potential benefits of RAFT polymerization in fabrication of nano and micro MIP networks, recent research in advanced MIP materials for different templates with improved morphology, efficiency, and binding capacities with respect to traditional free radical polymerization (FRP) will be discussed. MIPs prepared via RAFT method have advantages of MIPs as high performance molecular recognition devices and CLRP as controllable polymerization mechanism, simultaneously. 相似文献
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Maryam Abareshi Elaheh K. Goharshadi S. Mojtaba Zebarjad 《Journal of Molecular Liquids》2009,149(3):66-73
In the present work, we have used a simple equation of state called the GMA EoS to calculate the density of three ionic liquid mixtures including 1-butyl-3-methylimidazolum hexafluorophosphate, [BMIM] [PF6] + methanol, 1-butyl-3-methylimidazolum tetrafluoroborate, [BMIM] [BF4] + methanol, and [BMIM] [BF4] + ethanol at different temperatures, pressures, and compositions. The isothermal compressibility, excess molar volumes, and excess Gibbs molar energy of these mixtures have been computed using this equation of state. The values of statistical parameters show that the GMA EoS can predict these thermodynamic properties very well within the experimental errors. The results show that isothermal compressibility of ionic liquids is lower than alcohols and the effect of temperature and pressure on the isothermal compressibility of ionic liquids is lower than alcohols. The excess molar volumes and excess molar Gibbs energy for these ionic liquid mixtures with alcohols are all negative at various temperatures and pressures over the whole composition range. The results have been interpreted in terms of intermolecular interactions and structural factors of the ionic liquids and alcohols. 相似文献
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For the first time, zinc oxide nanoparticles have been synthesized by the sonochemical method in an ionic liquid, 1-hexyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide, liquid [hmim][NTf(2)] as a solvent. The morphology and structure of ZnO nanoparticles have been characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). A possible mechanism is proposed to explain the formation of ZnO nanostructures. 相似文献
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Synthesis of tetrasubstituted pyrroles by the three-component condensation reaction of acid chlorides, dialkyl acetylenedicarboxylates,
and amino acids in the presence of various room-temperature ionic liquids (RTILs) as catalysts in water is reported. Among
the ionic liquids used, the basic functionalized ionic liquid, butyl methyl imidazolium hydroxide [bmim]OH, was the most effective
catalyst. The influence of reaction temperature, reaction time, and amount of ionic liquid on the reaction was investigated.
The [bmim]OH/H2O catalyst system could be reused for at least five recycles without appreciable loss of efficiency. 相似文献