Optimization of stir bar sorptive extraction applied to the determination of pesticides in vinegars

Stir bar sorptive extraction (SBSE) has been evaluated for analysing pesticides in vinegar. The extraction analytical conditions have been optimised using a two-level factorial design expanded further to a central composite design. After optimization, the proposed analytical conditions are: sample volume 40 mL, sampling time 150 min, and stirring speed 1000 rpm. On the basis of the results, it was decided not to add NaCl. The SBSE procedure developed shows detection limits and linear ranges adequate for analysing this type of compound, giving recoveries close to 100%. The repeatability and reproducibility values obtained were lower than 18 and 23%, respectively. The method was applied to a variety of commercial vinegars. SBSE is a very simple, solvent-free, and fast technique with high sensitivities.     

Selective mode suppression in microstrip differential lines by means of electric-LC (ELC) and magnetic-LC (MLC) resonators

In this paper, it is demonstrated that the so-called electric-LC (ELC) resonators, and their dual counterparts, the magnetic-LC (MLC) resonators, are useful for the selective suppression of either the differential or the common mode in microstrip differential lines. The key point to mode suppression is the alignment of the resonator with the electric (differential mode) or magnetic (common mode) wall of the line. It is shown that by simply rotating the resonators 90^° we can selectively choose the suppressed mode in the vicinity of the resonator’s fundamental resonance frequency. The theory is validated through full-wave electromagnetic simulation, the lumped element equivalent circuit models of the proposed structures and experimental data.     

Suspending the Cartan Embedding of {{\mathbb H}P^n} Through Spindles and Generators of Homotopy Groups

We provide an equivariant suspension of the Cartan embedding of the symmetric space ${S^{4n+3} \to \mathbb {H}P^n \hookrightarrow Sp(n+1)}$ ; this construction furnishes geometric generators of the homotopy group of ?? _4n+6 Sp(n?+?1). We study the topology and geometry of the image of this generator; in particular we show that it is a spindle, minimal with respect to the biinvariant metric from Sp(n?+?1). This spindle also admits a different metric of positive curvature away from the cone singular point.     

Stability and magnetorheological behaviour of magnetic fluids based on ionic liquids

This paper reports the preparation of magnetic fluids consisting of magnetite nanoparticles dispersed in an ionic liquid. Different additives were used in order to stabilize the fluids. Colloidal stability was checked by magnetic sedimentation, centrifugation and direct observation. The results of these tests showed that a true ferrofluid was only obtained when the nanoparticles were coated with a layer of surfactant compatible with the ionic liquid. These experiments also showed that stability could not be reached just by electrostatic repulsion. The conclusions of the stability tests were confirmed by calculations of the interparticle energies of interaction. The rheological behaviour of the magnetic fluids upon magnetic field application was also investigated. The experimental magnetoviscous response was fitted by a microstructural model. The model considered that the fluids consisted of two populations of particles, one with a magnetic core diameter of 9?nm, and another with a larger diameter. Upon field application chain-like structures are supposed to be induced. According to estimations particles of 9?nm are too small to aggregate upon field application. The results of the calculations showed that the intensity of the magnetoviscous response depends on the concentration and size of the large particles, and on the thickness of the surfactant layers.     

Blue‐to‐Orange Color‐Tunable Laser Emission from Tailored Boron‐Dipyrromethene Dyes

A series of meso‐substituted boron‐bipyrromethene (BODIPY) dyes are synthesized and their laser and photophysical properties systematically studied. Laser emission covering a wide visible spectral region (from blue to orange) is obtained by just changing the electron donor character of the heteroatom at position 8. The additional presence of methyl groups at positions 3 and 5 results in dyes with a photostability similar to that of the unsubstituted dye but with much improved efficiency. Correlation of the lasing properties of the different dyes to their photophysical properties provides inklings to define synthetic strategies of new BODIPY dyes with enhanced efficiency and modulated wavelength emission over the visible spectral region.     

Controlled aggregation in conjugated polymer nanoparticles via organic acid treatments

Understanding and controlling aggregation structures of conjugated polymers (CPs) in aqueous solutions is critical to improving the physical and photophysical properties of CPs for biological applications. Here, we present spectroscopic evidence, including nuclear magnetic resonance (NMR) spectroscopic results, that different organic acid treatment induces different aggregation structures and photophysical properties of CPs in water. Conjugated polymer nanoparticles (CPNs) were fabricated by treating a non-aqueous soluble, primary amine-containing poly(phenylene ethynylene) (PPE-NH(2)) with organic acids followed by dialysis. CPNs formed by acetic acid (AA) treatment (CPN-AAs) exhibit characteristics of loose aggregation with minimal π-π stacking, while CPNs formed by tartaric acid (TA) treatment (CPN-TAs) exhibit a high degree of π-π stacking among PPE-NH(2) chains. The controlled aggregation for a specific application was demonstrated by comparing the fluorescence quenching abilities of the CPN-AAs and the CPN-TAs. A doubled Stern-Volmer constant was obtained from the densely packed CPN-TAs compared to that of the loosely aggregated CPN-AAs.     

Ueber fortgesetztes Tangentenziehen an Curven dritter Ordnung mit einem Doppel- oder Rückkehrpunkte

Ohne Zusammenfassung     

Weighted fractional Sobolev spaces as interpolation spaces in bounded domains

We characterize the real interpolation space between a weighted $L^p$ space and a weighted Sobolev space in arbitrary bounded domains in ${\mathbb{R}}^n$, with weights that are positive powers of the distance to the boundary.