One-pot synthesis of imidazo[1,2-a]pyridines from benzyl halides or benzyl tosylates, 2-aminopyridines and isocyanides

A one-pot synthesis of imidazo[1,2-a]pyridines is described. Benzyl halides or benzyl tosylates are oxidized to aldehydes under mild Kornblum conditions which then undergo a three-component reaction with various 2-aminopyridines and isocyanides to afford the imidazo[1,2-a]pyridines in excellent yields.     

An accurate empirical correlation for predicting natural gas viscosity

Natural gas viscosity is an important parameter in many gas and petroleum engineering calculations.This study presents a new empirical model for quickly calculating the natural gas viscosity.The model was derived from 4089 experimental viscosity data with varieties ranging from 0.01 to 21,and 1 to 3 of pseudo reduced pressure and temperature,respectively.The accuracy of this new empirical correlation has been compared with commonly used empirical models,including Lee et al.,Heidaryan et al.,Carr et al.,and Adel Elsharkawy correlations.The comparison indicates that this new empirical model can predict viscosity of natural gas with average absolute relative deviation percentage AARD (%) of 2.173.     

Silicon carbide nanotubes (SiCNTs) serving for catalytic decomposition of toxic diazomethane (DAZM) gas: a DFT study

In the present study, the adsorption and decomposition of diazomethane (DAZM) on the surface of (6,0) zigzag silicon carbide nanotube (SiCNT) are investigated using density functional theory calculations. The geometry structures of the three stable configurations, adsorption energies and electronic properties of DAZM adsorption on the surface of SiCNT are investigated. It was found that the DAZM molecule is decomposed over the surface of (6,0) SiCNT with activation energy (E_act) of 0.523 eV. The curvature effect on the adsorption energies of the DAZM molecule is also considered by studying (5,0) and (7,0) SiCNTs. The results display that DAZM adsorption over smaller diameter of SiCNT is thermodynamically more favourable than larger one.     

Information Architecture for Data Disclosure

Preserving confidentiality of individuals in data disclosure is a prime concern for public and private organizations. The main challenge in the data disclosure problem is to release data such that misuse by intruders is avoided while providing useful information to legitimate users for analysis. We propose an information theoretic architecture for the data disclosure problem. The proposed framework consists of developing a maximum entropy (ME) model based on statistical information of the actual data, testing the adequacy of the ME model, producing disclosure data from the ME model and quantifying the discrepancy between the actual and the disclosure data. The architecture can be used both for univariate and multivariate data disclosure. We illustrate the implementation of our approach using financial data.     

Challenges and Strategies for Optimizing Corrosion and Biodegradation Stability of Biomedical Micro- and Nanoswimmers: A Review

The last two decades have witnessed the emergence of micro- and nanoswimmers (MNSs). Researchers have invested significant efforts in engineering motile micro- and nanodevices to address current limitations in minimally invasive medicine. MNSs can move through complex fluid media by using chemical fuels or external energy sources such as magnetic fields, ultrasound, or light. Despite significant advancements in their locomotion and functionalities, the gradual deterioration of MNSs in human physiological media is often overlooked. Corrosion and biodegradation caused by chemical reactions with surrounding medium and the activity of biological agents can significantly affect their chemical stability and functional properties during their lifetime performance. It is therefore essential to understand the degradation mechanisms and factors that influence them to design ideal biomedical MNSs that are affordable, highly efficient, and sufficiently resistant to degradation (at least during their service time). This review summarizes recent studies that delve into the physicochemical characteristics and complex environmental factors affecting the corrosion and biodegradation of MNSs, with a focus on metal-based devices. Additionally, different strategies are discussed to enhance and/or optimize their stability. Conversely, controlled degradation of non-toxic MNSs can be highly advantageous for numerous biomedical applications, allowing for less invasive, safer, and more efficient treatments.