Time dependence of the luminescence excited by rectangular pulses

The theory of the time dependence of luminescence, during and after excitation by rectangular pulse, is discussed. Some phenomena, which cannot be described as direct excited luminescence, will be mentioned. In order to explain these phenomena, the model for energy transfer between two monomolecular centres has been used. On the basis of this model, the theoretical time dependence of the luminescence is obtained. The theoretical formula describe qualitatively very well the experimental observations in ZnSMn and other compounds.     

Off-shell behaviour of theN-N interaction in a six-quark resonating group model of the deuteron

Two different 6-quark resonating group models of the deuteron are investigated to study the off-shell property of theN-N interaction. In the first model the quarks interact by a central one-gluon-exchange potential plus confinement potential. The meson-exchange contribution to then-p potential is simulated by a central GaussianN-N potential. In the second model the quarks interact by one-gluon-and one-pion-exchange potentials (central and noncentral) plus confinement potential. A small additional -exchange potential between neutron and proton binds the deuteron at the correct energy.Several off-shell variants of the two resonating group models are compared with each other by analyzing their elastic electron scattering cross sections. It is found that the standard renormalized version of the resonating group model yields potentials and wave functions that may be considered physical within the limitations of the model. Unitary off-shell transformations, which modify potentials and wave functions in any sizeable way, lead to a disagreement between the charge distribution predicted by the model via analysis of electron scattering and the charge distribution following from the microscopic quark distribution.Both of the 6-quark models support a soft repulsive core of the tripletn-p potential with a core height of around 900 MeV.     

Laser spectroscopy of desorbing molecules

In this article the application of tunable dye lasers to desorption phenomena is illuminated. These lasers provide radiation continuously tunable from 105 nm in the vacuum ultraviolet to about 10 m in the mid-IR. By employing either laser induced fluorescence (LIF) or resonance enhanced multiphoton ionization (REMPI) spectroscopy almost all diatomic and many polyatomic molecules can be probed with the sensitivity required to detect desorbing molecules under UHV conditions. The spectral resolution of the lasers is sufficiently high that rotational state selectivity is achieved. Recent developments permit in addition the velocity distributions of molecules to be determined with internal quantum state resolution. Therefore very detailed information about the molecular dynamics has been obtained. In most experiments so far reactive recombinations off surfaces have been investigated. In this paper special emphasis will be given to the recombination of hydrogen on copper and palladium surfaces. For these systems very detailed data about the internal state populations at various surface temperatures have been obtained. The rotational cooling previously observed in molecular beam scattering has also been established for desorption. Strong vibrational excitation has been observed, which in the case of desorption from copper may be associated with the recombination dynamics, whereas for desorption of D₂ from Pd(100) a molecular precursor state might be responsible. By measuring the velocity distribution in each quantum state, the complete energetics of the desorbing molecules has been determined. Some first experiments on laser induced desorption with state selective detection of the desorbing molecules will also be discussed. Finally, making use of the polarization analysis of the signal, alignment effects in the desorption can be observed, permitting observation of molecular dynamics with a magnifying glass.Heisenberg fellow of the Deutsche Forschungsgemeinschaft     

Base-atom recognition in protein adsorption to alkyl agaroses.

The three proteins phosphorylase b, calmodulin and fibrinogen are adsorbed onto thioalkyl derivatives of Sepharose much more strongly than onto gels carrying the same alkyl residue coupled via a carbamate linkage. This enhancement of binding onto alkyl-S-Sepharoses compared with alkyl-N-agaroses is not primarily due to an increase in the extent of conformational changes of the proteins occurring on the gel surface. This can be shown in experiments with the tripeptide Trp-Trp-Trp. The Trp tripeptide is also adsorbed with a much higher affinity to butyl-S-Sepharose than to butyl-N-Sepharose, showing that the primary interaction between the immobilized alkyl residue and the amino acids of the protein is decisive for adsorption. A model stressing the strong influence of an atom or a group of atoms at the base of an immobilized alkyl residue is described as "base-atom recognition".     

Dispersive anisotropic ballistic phonon propagation in [100] GaAs

We report experimental observations of the phonon focusing pattern in [100] GaAs using low temperature electron beam scanning for phonon generation. The typical dispersive effects for high-frequency phonons expected from the calculations by Tamura have clearly been observed using PbIn tunnel junctions for phonon detection. The quantitative comparison of our experimental results with the frequency dependent calculations by Tamura allowed to determine the dominant phonon frequencies contributing to the detector signal in our different experiments. Above the temperature of the -point the dominant phonon frequencies appear to be shifted considerably to lower values, which could be explained by a heating effect in the liquid-He layer adjacent to the tunnel junction detector. By comparing the observed magnitude of the detector signal with different theoretical treatments of the detector response, we have found satisfactory agreement for a model where the perturbation due to the high-frequency phonons is restricted to the base electrode of the detector reached first by the phonons following their passage through the crystal.     

The absorption of pulsed CO2-laser radiation by ethylene at total pressures from 25 to 3000 Torr

The absorption of pulsed CO₂-laser radiation by ethylene has been measured at total pressures from 25 to 3000 Torr, using the P(12) and P(14) lines in the 10.6 m band, with incident fluences from 0.1 to 0.7 J/cm². Marked deviations from the Beer-Lambert absorption law were observed, with the effective absorption coefficient varying with pressure, fluence, absorption path-length and the addition of non-absorbing gas. Pressure broadening of the rotational lines of the ethylene absorption spectrum was shown to be the major cause of these deviations, together with lesser effects which can be attributed to the rise in temperature of the absorbing gas during the laser pulse.     

Complementary influence of electric and magnetic fields on the sample voltage oscillations ofP-type ultrapure germanium

We report on a previously not observed behaviour of oscillations of the voltage over a hyperpure germanium sample, when increasing the sample current from 0.05 to 13 A, for a number of transverse magnetic fields ranging from 697 to 1746 gauss. The sample temperature was 7.54 K±0.02 K. For each magnetic field the first observed peaks in the frequency spectrum of the sample voltage go to chaos by the period-doubling route and simultaneously shift to lower frequencies (first scenario). Superimposed upon this chaotic spectrum a new peak emerges, which again shifts to lower frequencies with increasing sample current (second scenario). A complementary effect of the sample current and the magnetic field is detected for four properties: firstly, the sudden onset of high resistance in the current versus voltage diagram, secondly, the transition between the two frequency scenarios described above, thirdly the presence of certain frequencies in the sample voltage spectra and fourthly the occurrence of an amplitude maximum for the principal frequency of the first scenario. It is shown that the first two transitions are interrelated.     

Landau levels and electron radiation in planar channeling in monocrystals

The influence of a magnetic field on the motion and radiation of an electron is considered for planar channeling in a monocrystal. It is shown that discrete levels analogous to Landau levels appear in the super-barrier domain of transverse energies instead of a continuous spectrum. The spectral composition and intensity of anomalous and normal waves are computed. The possibilities are discussed of the observation of electron radiation with Landau levels.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 88–93, August, 1989.     

Magnetooptical effects in bismuth-containing ferrite-garnet films

We present results of magnetooptical investigations of bismuth-containing ferrite-garnet films with the easy axis of magnetization parallel to the specimen surface. Measurements were conducted for incident light with energies in the range 1.5–3.2 eV for transverse [equatorial Kerr effect (EKE)] and for longitudinal [meridional intensity effect (MIE)] magnetizations of thin-layer specimens. It is shown that the EKE differs from zero when the films are opaque, and it is established that the EKE peak in the region 2.8 eV increases with increasing bismuth concentration. For longitudinal magnetization, conditions for observing magnetooptical interference were realized. The experimental curves agree well with the theoretical ones.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 10–14, November, 1989.     

The sensitivity to technological innovations of the doses delivered by optimized mammography systems

Multiparameter optimizations have been carried out to study the effects of hypothetical technological advances on the patient doses required to maintain a given image quality in mammography. The assumed advances include: improvement in the power loading limits of the tube focal spot, increased absorption efficiency for a given detector resolution, increases in detector system gain, and changes in the exposure time limitations that result from patient motion. The optimization permits system geometry, kVp of the examination, filtration, detector resolution, focal spot size, and grid characteristics to vary simultaneously and self-consistently subject to image quality as well as technological constraints. The effects of technological innovations were measured by systematically varying the technological constraints to reflect hypothetical improvements and comparing the resulting minimized doses, required to maintain constant image quality, to a baseline optimized system derived from a set of baseline technological capabilities.