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11.
James H. Looker Duane L. Shaneyfelt Wayne Halfar 《Journal of heterocyclic chemistry》1979,16(6):1281-1282
Condensation reactions of comenaldehyde methyl ether (I) with malonic acid, ethyl cyanoacetate, and cyanoacetamide to give β-(5-methoxy-4H-pyran-4-on-2-yl)acrylic acid (II), ethyl 2-cyano-3-(5-methoxy-4H-pyran-4-on-2-yl)propenoate (III), and 2-cyano-3-(5-methoxy-4H-pyran-4-on-2-yl)propenamide (IV), respectively, are described. Ultraviolet absorption spectra for 2-hydroxymethyl-5-methoxy-4H-pyran-4-one, I and II are presented. 相似文献
12.
B.Duane Dombek 《Journal of organometallic chemistry》1983,250(1):467-483
Carbon monoxide and hydrogen are converted into organic products, including methanol, ethylene glycol, and ethanol, by halide-promoted ruthenium catalysts in organic solvents. Iodide salts are exceptionally good promoters for this system. Spectroscopic and reaction studies have shown that two ruthenium complexes, HRu3(CO)11? and Ru(CO)3I3?, are present during catalysis and essential for optimum activity. Possible roles for the involvement of these complexes in catalysis are considered. 相似文献
13.
Rojas-González PX Castiñeiras A González-Pérez JM Choquesillo-Lazarte D Niclós-Gutiérrez J 《Inorganic chemistry》2002,41(24):6190-6192
The reaction in water of the N-benzyliminodiacetate-copper(II) chelate ([Cu(NBzIDA)]) and the adenine:thymine base pair complex (AdeH:ThyH) with a Cu/NBzIDA/AdeH/ThyH molar ratio of 2:2:1:1 yields [Cu(2)(NBzIDA)(2)(H(2)O)(2)(mu-N7,N9-Ade(N3)H)].3H(2)O and free ThyH. The compound has been studied by thermal, spectral, and X-ray diffraction methods. In the asymmetric dinuclear complex units both Cu(II) atoms exhibit a square pyramidal coordination, where the four closest donors are supplied by NBzIDA in a mer-tridentate conformation and the N7 or N9 donors of AdeH, which is protonated at N3. The mu-N7,N9 bridge represents a new coordination mode for nonsubstituted AdeH, except for some adeninate(1-)-[methylmercury(II)] derivatives studied earlier. The dinuclear complex is stabilized by the Cu-N7 and Cu-N9 bonds and N6-H(exocyclic)...O(carboxyl) and N3-H(heterocyclic)...O(carboxyl) interligand interactions, respectively. The structure of the new compound differs from that of the mononuclear compound [Cu(NBzIDA)(Ade(N9)H)(H(2)O)].H(2)O, in which the unusual Cu-N3(AdeH) bond is stabilized by a N9-H...O(carboxyl) interligand interaction and where alternating benzyl-AdeH intermolecular pi,pi-stacking interactions produce infinite stacked chains. The possibility for ThyH to be involved in the molecular recognition between [Cu(NBzIDA)] and the AdeH:ThyH base pair is proposed. 相似文献
14.
Duane C. Wallace 《International journal of quantum chemistry》1994,52(2):425-435
The multiparticle correlation expansion for the entropy of a classical monatomic liquid is presented. This entropy expresses the physical picture in which there is no free particle motion, but, rather, each atom moves within a cage formed by its neighbors. The liquid expansion, including only pair correlations, gives an excellent account of the experimental entropy of most liquid metals, of liquid argon, and of the hard-sphere liquid. The pair correlation entropy is well approximated by a universal function of temperature. Higher-order correlation entropy, due to n-particle irreducible correlations for n ≥ 3, is significant in only a few liquid metals, and its occurrence suggests the presence of n-body forces. When the liquid theory is applied to the study of melting, we discover the important classification of normal and anomalous melting, according to whether there is not or is a significant change in the electronic structure upon melting, and we discover the universal disordering entropy for melting of a monatomic crystal. Interesting directions for future research are extension to include orientational correlations of molecules, theoretical calculation of the entropy of water, application to the entropy of the amorphous state, and correlational entropy of compressed argon. We clarify the relation among different entropy expansions in the recent literature. © 1994 John Wiley & Sons, Inc. 相似文献
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Branching ratios, widths, and lepton energy spectra are derived for the leptonic decays of the into β0 and . The calculations are made by hypothesizing that higher-order multipoles in an expansion of the baryon current are zero. The axial vector coupling is determined using the bag model. 相似文献
18.
B. Pietrzyk R. Barate P. Bareyre P. Bonamy P. Borgeaud M. David F.X. Gentit G. Laurens Y. Lemoigne G. Villet S. Zaninotti P. Astbury A. Duane G.J. King B.C. Nandi R. Namjoshi D.M. Websdale J. Wiejak T. Marshall 《Physics letters. [Part B]》1982,113(1):105-112
A lepton-pair trigger was used to select a hadronic system in different flavour and colour states: properties of the transformation of this system into hadrons were measured in terms of charge flow, multiplicity distribution, and fragmentation function. It is observed that, while the effects of flavour are clearly seen, the colour degrees of freedom are not observed in the region of low pT. 相似文献
19.
Nair VA Mustafa SM Mohler ML Fisher SJ Dalton JT Miller DD 《Tetrahedron letters》2004,45(51):9475-9477
A series of optically active nonsteroidal selective androgen receptor modulators with structures analogous to bicalutamide was prepared by replacing the trifluoromethyl group with iodine and the sulfonyl linker by oxygen. 相似文献
20.
This paper proposes a new nonparametric reliability growth model for the analysis of the failure rate of a system that is undergoing development test. The only restrictions on the actual, unknown failure distribution for each stage of testing is that it be continuous, have only one unknown parameter ?, and have an associated unimodal likelihood function. No assumptions regarding the parametric form of the failure rate of the development process are made, only that there is no decay in the reliability of the system during the design changes. The parameters are assumed to be ordered from one test stage to the next such that ?1 ? ?2 ? ... ? ?m. The new model performs very well based on relative error and mean square error. The model is generally superior to the popular AMSAA model, regardless of the actual underlying failure process. In addition, the results indicate a notable bias in the AMSAA model, early in the development process, regardless of the actual underlying failure process. 相似文献