Diaquabis(2,5‐dihydroxybenzoato‐κO)bis(1,10‐phenanthroline‐κ2N,N′)strontium(II) bis(1,10‐phenanthroline) tetrahydrate

The title compound, [Sr(C₇H₅O₄)₂(C₁₂H₈N₂)₂(H₂O)₂]·2C₁₂H₈N₂·4H₂O, consists of an Sr^II complex, uncoordinated phenanthroline (phen) molecules and solvent water molecules. The Sr^II ion is located on a twofold axis and is coordinated by two phen ligands, two dihydroxybenzoate anions and two water molecules in a distorted tetragonal antiprismatic geometry. Partially overlapped arrangements exist between parallel coordinated and parallel uncoordinated phen rings; the face‐to‐face separations between the former (coordinated) and the latter (uncoordinated) rings are 3.436 (13) and 3.550 (14) Å, respectively. This difference suggests the effect of metal coordination on π–π stacking between phen rings.     

Synthesis and magnetic properties of the one-dimensional linear chain structure cyano-bridged complex [Cu(teta)(H2O)2][Cu(teta) Fe(CN)6]ClO4·2H2O (teta=5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacylotetradecane)

Reaction of either K₃[Fe(CN)₆] or K₄[Fe(CN)₆] with a macrocyclic Cu^II complex, [Cu(teta)](ClO₄)₂ (teta = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacylotetradecane), in aqueous solution gave the same product as shown by spectroscopic and physicochemical characterisation. The crystal structure of the complex shows that it is a one-dimensional linear chain type heterobinuclear Fe^III–Cu^II polymer. The unit is composed of a [Cu(teta)(H₂O)₂]²⁺ cationic complex, a Fe^III–Cu^II alternate linear chain unit, a ClO ₄ ^– ion and four water molecules. The Cu atom is coordinated in a distorted octahedral arrangement by four nitrogen atoms from one teta ligand and two nitrogen atoms of the bridging cyanide groups. The Cu—N bond distances involving the cyanide bridges, 2.522(7) and 2.608(7)Å, respectively, indicate weak antiferromagnetic interactions between the Fe^III and Cu^II atoms.     

Donorstabilisierte Galliumdihalogenide Ga2X4·2D (X = Cl,Br; D = Donormolekül): Ein experimenteller Beitrag zu den Variationsmöglichkeiten der Ga‐Ga‐Einfachbindung

Donor‐stabilized Galliumdihalides Ga₂X₄·2D (X = Cl, Br; D = Donor): An Experimental Contribution on the Variation of the Gallium‐Gallium Single Bond During the disproportionation of metastable GaX‐solutions (X= Cl, Br) donor‐stabilized galliumdihalides are formed as oxidized products. According to X‐ray structure analyses they all exhibit dimeric entities DX₂Ga‐GAX₂D (D= THF, NHEt2, NEt3, 4‐^tButylpyridin or Br^‐), which means these compounds are isoelectronic with ethane and could schematically be regarded as representatives of catenulate or alkane‐like gallium subhalides: Ga_n(X, D)_2n+2. The gallium‐gallium bond in these compounds is shorter than in the organometallic compounds such as R₂Ga‐GaR₂. The comparison of the bonding situation in the galliumdihalides, particularly of the gallium‐gallium bond, shows clearly the influence by donor molecules as well as by halogen ligands.     

具有应变沟道及EOT 1.2nm高性能栅长22nm CMOS器件

深入研究了亚30nm CMOS关键工艺技术,特别是提出了一种新的低成本的提高空穴迁移率的技术--Ge预非晶化S/D延伸区诱生沟道应变技术,它使栅长90nm pMOS空穴有效迁移率在0.6MV/cm电场下提高32%.而且空穴有效迁移率的改善,随器件特征尺寸缩小而增强.利用零阶劳厄线衍射的大角度会聚束电子衍射分析表明,在沟道区相应的压应变为-3.6%.在集成技术优化的基础上,研制成功了高性能栅长22nm应变沟道CMOS器件及栅长27nm CMOS 32分频器电路(其中分别嵌入了57级/201级环形振荡器),EOT为1.2nm,具有Ni自对准硅化物.     

如何打造内容数据业务价值链

1概述 1．1传统计费模式与内容计费模式的比较 在传统的计费模式中，电信运营商仅能获得用户的行为数据，如通话时长、通话费用、通话时段等。而通过内容计费则能够获得更多的信息，及时掌握用户的实际需求。例如，通过内容计费可以发现：如果用户A从某网购买了很多婴幼儿产品，电信运营商就会判断该用户家中可能有个刚出生的宝贝；如果用户B经常从某网订购国内外足球联赛的有关新闻，电信运营商因此可以判断该用户可能是一个足球迷。     

双面阶梯埋氧型SOI结构的耐压分析段宝兴

在单面阶梯埋氧型SOI结构的基础上,提出了一种双面阶梯埋氧SOI新结构.双面阶梯的电荷积累作用使其纵向电场突破了传统上受界面电荷为零限制的3倍关系,埋氧层的电场可以高达200V/μm;而且双面阶梯对表面电场的调制作用使其表面电场达到近乎理想的均匀分布.借助二维MEDICI数值分析软件,验证了此结构具有同时优化横向SOI基高压器件横、纵向电场,提高击穿电压的优点.     

神经网络的函数逼近能力分析

本文综述了多层前传网络（ＭＬＰ）及径向基函数网络（ＲＢＦ）对函数任意精度逼近的能力，比较了两种网络的最佳逼近特性。对激活函数类的扩充作了介绍，并说明有限数值精度对函数逼近能力实现的影响。     

Notable shift of ultraviolet intensity on Sn-doped ZnO nanostructure fabricated by sol–gel method

Sn-doped ZnO (SZO) thin films are deposited by sol–gel dip-coating method with Sn content at 0 at.% and 1–15 at.% with an increment of 2 at.%. The structure and luminescence of the films are investigated. X-ray diffraction results indicate that all the SZO samples show preferential orientation along the (002) direction, and the scanning electron microscope exhibits that the surface morphology of the films change from nanoparticles to nanorods with increasing Sn concentration. X-ray photoelectron spectroscopy reveals that Sn exists as valence of +4 in the matrix. The photoluminescence peaks at 381 and 398 nm are observed in all the samples. The ratio of intensity of peak at 381 nm to that of peak at 398 nm differed markedly. The intensity of peak at 398 nm might be due to the response for the Sn atoms, while the intensity of peak at 381 nm is probably related to the quantum size effect.