宽带卫星Mesh网多址接入信道预测分配方案研究

该文针对具有网状(Mesh)拓扑结构的宽带卫星通信网,研究了分布式控制多址接入信道分配策略。提出了一种基于自相似业务流量混沌预测的混合动态分配方案。利用OPNET软件建立了仿真系统,研究比较了信道分配周期、信道负载以及业务流自相似程度对几种方案性能的影响。仿真结果表明,对于采用地球同步轨道(GEO)卫星、低轨(LEO)和中轨(MEO)卫星星座的宽带卫星Mesh网,所提出方案在高信道负载条件下都具有明显的优势。     

Photo-induced doping effect and dynamic process in monolayer MoSe2

Dynamic processes of electron transfer by optical doping in monolayer MoSe₂ at 6 K are investigated via measuring time resolved photoluminescence (PL) traces under different excitation powers. Time-dependent electron transfer process can be analyzed by a power-law distribution of t^−α with α = 0.1–0.24, depending on the laser excitation power. The average electron transfer time of approximately 27.65 s is obtained in the excitation power range of 0.5 to 100 μW. As the temperature increases from 20 to 44 K, the energy difference between the neutral and charged excitons is observed to decrease.     

Bioavailability Enhancement of Cepharanthine via Pulmonary Administration in Rats and Its Therapeutic Potential for Pulmonary Fibrosis Associated with COVID-19 Infection

Cepharanthine (CEP) has excellent anti-SARS-CoV-2 properties, indicating its favorable potential for COVID-19 treatment. However, its application is challenged by its poor dissolubility and oral bioavailability. The present study aimed to improve the bioavailability of CEP by optimizing its solubility and through a pulmonary delivery method, which improved its bioavailability by five times when compared to that through the oral delivery method (68.07% vs. 13.15%). An ultra-performance liquid chromatography tandem-mass spectrometry (UPLC-MS/MS) method for quantification of CEP in rat plasma was developed and validated to support the bioavailability and pharmacokinetic studies. In addition, pulmonary fibrosis was recognized as a sequela of COVID-19 infection, warranting further evaluation of the therapeutic potential of CEP on a rat lung fibrosis model. The antifibrotic effect was assessed by analysis of lung index and histopathological examination, detection of transforming growth factor (TGF)-β1, interleukin-6 (IL-6), α-smooth muscle actin (α-SMA), and hydroxyproline level in serum or lung tissues. Our data demonstrated that CEP could significantly alleviate bleomycin (BLM)-induced collagen accumulation and inflammation, thereby exerting protective effects against pulmonary fibrosis. Our results provide evidence supporting the hypothesis that pulmonary delivery CEP may be a promising therapy for pulmonary fibrosis associated with COVID-19 infection.     

一类求解鞍点问题的广义不精确Uzawa方法

本文提出了一类求解大型稀疏鞍点问题的新的广义不精确Uzawa算法.该方法不仅可以包含 前人的方法, 而且可以拓展出很多新方法. 理论分析给出该方法收敛的条件, 并详细的分析了其收敛性质和参数矩阵的选取方法. 通过对有限元离散的Stokes问题的数值实验表明, 新方法是行之有效的, 其收敛速度明显优于原来的算法.     

1-3型压电复合材料的机电响应特性和温度稳定性

1-3型压电复合材料具备优异的机电耦合性能,这对于高性能压电换能器的开发具有重要意义。该文采用低成本的切割填充法制备了不同结构参数的1-3型PZT/环氧树脂复合材料,并结合有限元模拟法对其压电性能、机电响应特性和温度稳定性进行了系统地研究。1-3阵列结构对平面方向应变产生了很大的衰减,使能量更集中于厚度共振模式。复合材料的高径比是影响机电耦合性能的主要因素,更精细的阵列结构有利于高性能压电换能器的制造。在-20～60℃内,1-3型压电复合材料的厚度机电耦合系数约为0.61,变化率小于1%,表现出良好的温度稳定性。     

A 9,9′-bianthracene-cored molecule enjoying twisted intramolecular charge transfer to enhance radiative-excitons generation for highly efficient deep-blue OLEDs

The efficiency of fluorescent organic light emitting diodes (FOLEDs) is strongly affected by the fraction of singlet excitons formed. However, the standard statistical value of the single to triplet ratio is 1:3, which implies most of the excitons are invalid in fluorescent emitting devices. Here, we demonstrate the ability of twisted intramolecular charge transfer state (TICT-state) to enhance the occurrence of singlet excitons in a fluorescent emitter that is based on the 9,9′-bianthracene (BA) moiety. The anthracene–anthracene (A–A) linked by a single bond and having perpendicular electronic structure is a charge transfer intersystem crossing π system in excited state. The BA-cored fluorescence emitter (CzBACz) with particular TICT characteristics realizes the electron–hole (e–h) recombination via intramolecular conversion from charge-transfer excitons (immediate precursor) to radiative singlet exciton (final state). For CzBACz-based electroluminescent (EL) device, the singlet generation fraction is more than 25%.     

Relative and Absolute Configuration of Vatiparol (1 mg): A Novel Anti‐inflammatory Polyphenol

Bioactive natural products offer multiple opportunities for the discovery of novel chemical entities with potential pharmaceutical, nutraceutical and agrochemical applications. Many new organic compounds with novel scaffolds are isolated in small quantities and established methods often fail to determine the structure and bioactivity of such novel natural products. To meet this challenge, we present here a new methodology combining RDC (residual dipolar coupling)‐based NMR spectroscopy in microtubes, with a motif‐inspired biological assessment strategy. Using only one milligram (ca. 1.5 μmol) of sample, the new protocol established the bioactivity as well as the relative and absolute configuration of vatiparol obtained from Vatica parvifolia. Vatiparol is unique in its unprecedented carbon skeleton and selective inhibitory effect on the expression of monocyte chemo‐attractant protein‐1 (MCP‐1, also known as CCL2). The plausible biosynthetic pathway of vatiparol is briefly discussed. The approach introduced here promises to be widely applicable to the determination of the structure and bioactivity of structurally unknown organic samples available in very limited amounts.     

基于稀疏重构的全极化SAR联合多维重建

各极化通道独立处理和三维分步成像会忽视数据之间的关联性,造成散射中心的失配以及极化散射矩阵获取的不准确。鉴于此,该文提出一种基于稀疏重构的全极化联合多维重建方法。该方法通过设置联合稀疏约束对所有极化通道及所有维度进行联合,将全极化多维重建建模为多通道联合稀疏重构问题。通过数据插值对模型简化后,结合三维快速傅里叶变换、共轭梯度法和牛顿迭代法给出一种高效的模型求解方法,可以同时得到极化散射矩阵和目标三维信息。该文方法保证了不同极化通道、不同维度的稀疏支撑集一致,且充分利用了数据之间的关联性带来的额外信息。基于仿真数据和电磁计算数据的实验结果表明,该方法的性能不受目标类型影响,具有一定的抗噪性,能有效地获取目标的多维重建结果,得到的三维成像结果分辨率高且极化散射矩阵估计精度高。      

Surface-enhanced resonant Raman spectroscopy (SERRS) of single-walled carbon nanotubes absorbed on the Ag-coated anodic aluminum oxide (AAO) surface

In this paper, we developed a new kind of substrate, the silver-coated anodic aluminum oxide (AAO), to investigate the characters of surface-enhanced resonant Raman scattering (SERRS) of the dilute single-walled carbon nanotubes. Homogeneous Ag-coated AAO substrate was obtained by decomposing the AgNO₃ on the surface of AAO. single-walled carbon nanotubes (SWNTs) were directly grown onto this substrate through floating catalyst chemical vapor deposition method (CVD). SERRS of SWNTs was carried out using several different wavelength lasers. The bands coming from metallic SWNTs were significantly enhanced. The two SERRS mechanisms, the “electromagnetic” and “chemical” mechanism, were mainly responsible for the experiment results.