Cobalt‐based metal coordination polymers with 4,4′‐bipyridinyl groups: highly efficient catalysis for one‐pot synthesis of 3,4‐dihydropyrimidin‐2(1H)‐ones under solvent‐free conditions

Three new metal coordination complexes, namely [Co(BPY)₂(H₂O)₂](BPY)(BS)₂(H₂O)₄ ( 1 ), [Co(BPY)₂(H₂O)₄](ABS)₂(H₂O)₂ ( 2 ) and [Co(BPY)(H₂O)₄](MBS)₂ ( 3 ) (BPY = 4,4′‐bipyridine, BS = phenylsulfonic acid, ABS = p‐aminobenzenesulfonic acid, MBS = p‐methylbenzenesulfonic acid), were obtained under hydrothermal conditions. Complexes 1 , 2 , 3 were structurally characterized using single‐crystal X‐ray diffraction and infrared spectroscopy. All of them display low‐dimensional motifs: complex 1 displays a two‐dimensional structure; and complexes 2 and 3 exhibit a one‐dimensional tape structure. Through strong intermolecular hydrogen bonding interactions and weak packing interactions, all of them further stack to generate a three‐dimensional supramolecular architecture. Catalysts 1 , 2 , 3 were involved in the green synthesis of a variety of 3,4‐dihydropyrimidin‐2(1H)‐ones under solvent‐free conditions through Biginelli reactions. The corresponding catalytic product was obtained in quantitative yields (99%) under eco‐friendly synthesis conditions for the variety of reactions. Catalysts 1 , 2 , 3 exhibit excellent efficiency for the desired product, and their catalytic performance shows the following order: 2  >  1  ≈  3 , which can be ascribed to the hydrophobic interactions of different phenylsulfonate groups. The catalytic performance for the Biginelli reaction is not only dependent on the selected solvents, but also inversely proportional to the polarities of the solvents. Copyright © 2016 John Wiley & Sons, Ltd.     

Optical pulse shaper with integrated slab waveguide for arbitrary waveform generation using optical gradient force

Integrated optical pulse shaper opens up possibilities for realizing the ultra high-speed and ultra wide-band linear signal processing with compact size and low power consumption. We propose a silicon monolithic integrated optical pulse shaper using optical gradient force, which is based on the eight-path finite impulse response. A cantilever structure is fabricated in one arm of the Mach–Zehnder interferometer（MZI） to act as an amplitude modulator. The phase shift feature of waveguide is analyzed with the optical pump power, and five typical waveforms are demonstrated with the manipulation of optical force. Unlike other pulse shaper schemes based on thermo–optic effect or electro–optic effect, our scheme is based on a new degree of freedom manipulation, i.e., optical force, so no microelectrodes are required on the silicon chip,which can reduce the complexity of fabrication. Besides, the chip structure is suitable for commercial silicon on an insulator（SOI） wafer, which has a top silicon layer of about 220 nm in thickness.     

A generalized bi-criteria fuzzy integer flow sharing problem

The flow sharing problem is a class of techniques that can be used to find the optimal flow in a capacitated network, which realizes an equitable distribution of flows. This paper extends the integer flow sharing problem by considering fuzzy capacities and fuzzy weights such that the flux received at each sink node and the flow value through each arc are restricted to be multiples of some block unit. Fuzzy capacity describes the flexibility of the upper limit of flow value through each arc. Fuzzy weight represents the degree of satisfaction of the flux to a sink node. Our model has the two following criteria: to maximize the minimal degree of satisfaction among all of the fuzzy capacity constraints and to maximize the minimal degree of satisfaction among the fluxes to all of the sink nodes. Because an optimal flow pattern that simultaneously maximizes the two objectives is usually not feasible, we define non-domination in this setting and propose a pseudo-polynomial algorithm that finds some non-dominated flow patterns. Finally, a numerical example is presented to demonstrate how our algorithm works.     

An Information Hiding Algorithm Based on Bitmap Resource of Portable Executable File

An information hiding algorithm is proposed, which hides information by embedding secret data into the palette of bitmap resources of portable executable （PE） files. This algorithm has higher security than some traditional ones because of integrating secret data and bitmap resources together. Through analyzing the principle of bitmap resources parsing in an operating system and the layer of resource data in PE files, a safe and useful solution is presented to solve two problems that bitmap resources are incorrectly analyzed and other resources data are confused in the process of data embedding. The feasibility and effectiveness of the proposed algorithm are confirmed through computer experiments.     

转动中的材料形变检测方法探讨

扇叶因转动会产生形变,引起形变的参数主要由扇叶的形状以及旋转速度构成。本文主要介绍了寻找转动中材料形变的相应规律而设计的一系列实验及实验成果展示。不同于现有的观测方式,实验创新性地运用光学锁相成像技术获得的周期运动物体的准静态图像来定量测量形变程度,分析并找出相应规律,极大地降低了测试成本,在工程设计、产品检测等方面有着积极重要的意义。