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21.
Kyung Hwa Hong Jong Lyoul Park In Hwan Sul Ji Ho Youk Tae Jin Kang 《Journal of Polymer Science.Polymer Physics》2006,44(17):2468-2474
Polyvinyl alcohol (PVA) nanofibers containing Ag nanoparticles were prepared by electrospinning PVA/silver nitrate (AgNO3) aqueous solutions, followed by short heat treatment, and their antimicrobial activity was investigated for wound dressing applications. Since PVA is a water soluble and biocompatible polymer, it is one of the best materials for the preparation of wound dressing nanofibers. After heat treatment at 155 °C for 3 min, the PVA/AgNO3 nanofibers became insoluble, while the Ag+ ions therein were reduced so as to produce a large number of Ag nanoparticles situated preferentially on their surface. The residual Ag+ ions were reduced by subsequent UV irradiation for 3 h. The average diameter of the Ag nanoparticles after the heat treatment was 5.9 nm and this value increased slightly to 6.3 nm after UV irradiation. It was found that most of the Ag+ ions were reduced by the simple heat treatment. The PVA nanofibers containing Ag nanoparticles showed very strong antimicrobial activity. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2468–2474, 2006 相似文献
22.
本文在弱闪烁条件下,利用广泛适用于星际闪烁、行星际闪烁和电离层闪烁的薄相屏理论,以行星际闪烁为算例,对薄相屏闪烁进行了数值分析。结果表明:垂直于介质运动方向上的不规则结构的大小对闪烁有着重要的影响,直接表现在频谱的变化趋势和振荡幅度的不同。尤其是当小于Fresnel尺度时,数值计算表明此时没有闪烁发生。 相似文献
23.
讨论了热载流子注入对MOS结构C─V和I─V特性的影响。指出热载流子效应引起载流子陷落和界面态的产生,导致C─V特性曲线畸变、平带电压漂移和恒定电压下SiO2漏电流随时间漂移。本文论述了这些漂移的机理,提出了漂移的tn物理模型,从而很好地解释了实验所观察到的现象。 相似文献
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26.
Ping Liu Zheng-Fan Li Guo-Bing Han 《Electromagnetic Compatibility, IEEE Transactions on》2006,48(3):485-492
In this paper, the asymptotic waveform evaluation (AWE) technique is first applied to the conventional eigenmode expansion method for characterizing a power/ground (P/G) plane pair and analyzing the simultaneous switching noise on such plane pairs for printed circuit boards or multichip modules. The application of AWE avoids a large number of iterations in computing the impedance frequency response of a P/G plane pair structure and greatly reduces the computation time. Meanwhile, to obtain an accurate solution in an entire frequency range, we employ the complex frequency hopping technique which can help select multiple expansion points. In addition, the proposed approach can also be used to characterize the P/G plane pair structures with irregular shapes. Three examples demonstrate its high efficiency and good accuracy. 相似文献
27.
Chemisorption of polybenzimidazole on silver and copper etched with nitric acid has been observed by surface-enhanced Raman scattering (SERS). The polymer is found to react chemically with silver, forming a complexed film on the surface. The SERS spectra show that polybenzimidazole film inhibits oxidation of the metal at high temperature, unlike chemisorbed benzimidazole, benzotriazole, and poly(4-vinyl pyridine). © 1992 John Wiley & Sons, Inc. 相似文献
28.
Tian-lin Dong 《Journal of Infrared, Millimeter and Terahertz Waves》1992,13(8):1163-1174
Rigorous analysis of planar waveguides with two-dimensionally periodic (2DP) layer is presented. Characteristic solutions in periodic layer are exactly represented by a double Fourier series known as the Floquet solutions. The vector amplitudes of space harmonics are proved to be governed by five-term recurrence relation in the operator-vector form for sinusoidal modulation. A general transmission-line network representation of two-dimensionally periodic medium and multiport network representation of uniform-periodic-medium interface are introduced. Any layered structures cascading with periodic ones can be analyzed. Numerical results based on the established theory are also presented to illustrate characteristics of 2DP medium and structure. 相似文献
29.
In this article, the linear and nonlinear shear rheological behaviors of polylactide (PLA)/clay (organophilic‐montmorillonite) nanocomposites (PLACNs) were investigated by an Advanced Rheology Expanded System rheometer. The nanocomposites were prepared by master batch method using a twin‐screw extruder with poly(ε‐caprolactone) (PCL) as a compatibilizer. The presence of org‐MMT leads to obvious pseudo‐solid‐like behaviors of nanocomposite melts. The behaviors caused by the formation of a “percolating network” derived from the reciprocity among the strong related sheet particles. Therefore, the storage moduli, loss moduli, and dynamic viscosities of PLACNs show a monotonic increase with MMT content. Nonterminal behaviors exists in PLACNs nanocomposites. Besides the PLACNs melts show a greater shear thinning tendency than pure PLA melt because of the preferential orientation of the MMT layers. Therefore, PLACNs have higher moduli but better processibility compared with pure PLA. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 3189–3196, 2007 相似文献
30.
Qi Sheng Liu Lian Dong Liu Jing Min Shi 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(1):m58-m60
In the title centrosymmetric binuclear complex, [Cd2(C17H11N3O)4(H2O)2](ClO4)4, the CdII ion assumes a distorted octahedral geometry. There are π–π stacking interactions between the pyridine and 1,10‐phenanthroline ring systems of adjacent ligands at the same CdII centre. Intermolecular hydrogen bonds between the coordinated aqua ligand and the O atom of a keto group connect adjacent complex cations into extended chains. Hydrogen bonds also exist between the complex cations and the perchlorate anions. Compared with the fluorescence spectrum of the organic ligand, the complex displays strong fluorescent emission and an ipsochromic shift of the emission peaks, which may be attributed to the structural character. 相似文献