Acetic anhydride as a synthetic reagent

Acetic anhydride has been used widely in synthetic organic chemistry, especially in syntheses and transformations of heterocyclic compounds. These utilities are reviewed under the following classification.     

Fabrication of hollow palladium spheres and their successful application to the recyclable heterogeneous catalyst for suzuki coupling reactions

Novel palladium hollow spheres were synthesized using silica spheres as a template, and they were successfully applied as recyclable heterogeneous catalysts for Suzuki cross coupling reactions.     

Synthesis of pyrimido[4,5-e][1,4]oxazepin-5-ones

Eighteen novel pyrimido[4,5-e][1,4]oxazepin-5-ones were prepared directly via the reaction of either ethyl 4-chloro-2-phenyl-5-pyrimidinecarboxylate (Ia) or ethyl 4-chloro-2-m-chlorophenyl-5-pyrimidinecarboxylate (Ib) with a variety of substituted 2-(alkylamino)ethanols. A typical example was the preparation of 8,9-dihydro-9-methyl-2-phenylpyrimido[4,5-e][1,4]-oxazepin-5(7H)-one (IIa) from the reaction of Ia with 2-(methylamino)ethanol. Hydrolytic cleavage of the lactone ring in IIa with sodium hydroxide solution, followed by acidification with hydrochloric acid afforded 4-[(2-hydroxyethyl)methylamino]-2-phenyl-5-pyrimidinecarboxylic acid (IV). Reactions of IIa with concentrated ammonium hydroxide or hydrazine also caused cleavage of the lactone ring, giving the corresponding amide (V) or hydrazide (VI), respectively. Structural assignments were supported by infrared and nuclear magnetic resonance spectra.     

Synthesis of 5,6,8,9,14,14a-hexahydroisoquino[1,2-b][3]benzazepines

Syntheses of 5,6,8,9,14,14a-hexahydroisoquino[1,2-b][3]benzazepine-2,3,11,12-tetrol and related compounds are described. Key steps involve an initial construction of the isoquinoline ring under the Bischler-Napieralski conditions, which is followed by the building of the azepine ring via an intramolecular lactam formation on to the isoquinoline nucleus.     

Synthesis of 1,2,3,4,8,9,10,11-octahydro-[1,4] diazepino[6,5,4-jk ]earbazole and related compounds

1,2,3,4,8,9,10,11-Octahydro[1,4]diazepino[6,5,4-jk]earbazole (VIa) was synthesized from 2,3,4,5-tetrahydro-1H-benzodiazepine (la) via the route shown in Scheme 1. Other compounds which were prepared similarly are 3-acetyl-6-chloro-1,2,3,4,8,9,10,11-octahydro[1,4]diazepino-[6,5,4-jk]carbazole(Vb) and 3-methyl-1,2,3,4,8,9,10,11-octahydro[1,4]diazepino[6,5,4-jk]carb-azole (VIII). Chemical transformations which were carried out with VI and 3-acetyl-1,2,3,4,8,9, 10,11-octahydro[1,4]diazepino[6,5,4-jk]carbazole (Va) are also described.     

A modified low-pass filter with progressively diminishing ripples

A modified low-pass filter functions are proposed. A modified inverse Chebyshev function possesses progressively diminishing ripples in the stopband whereas the modified Chebyshev function exhibits ripples diminishing toward = 0 in the passband.Both are realizable in the doubly-terminated ladder structures for the ordern even or odd, thus lending themselves amenable to high-quality activeRC or switched capacitor filters through the simulation techniques.     

嵌入式电子助力转向系统研究

电子转向助力技术能够有效驱动汽车转向,为提高其转向控制的稳定性和准确性,本文设计了一种基于嵌入式的电子助力转向系统。首先针对传统的电子助力转向系统,利用牛顿第二定律建立其动力学模型,为控制器设计及构建硬件环境奠定基础。其次,针对典型电子转向助力系统的动力学模型,为降低其运动副间的摩擦对控制性能的影响,设计了自适应摩擦前馈补偿控制器,并根据Lyapunov稳定性原则确定了自适应控制率解析表达式。再次,本文以STM32F407嵌入式控制器为核心,搭建系统硬件平台并设计软件流程。最后,基于此平台展开试验验证,系统通过跟踪阶跃指令和正弦指令对比分析了传统PID算法和自适应摩擦前馈补偿算法,试验结果表明自适应前馈补偿算法可提高系统稳态精度和动态响应能力,并验证所设计的基于嵌入式的电子助力转向系统的正确性和完整性。     

The Chow rings for 3-dimensional toric varieties with one bad isolated singularity

The properties of a toric variety have strong connection with the combinatorial structure of the corresponding fan and the relations among the generators. Using this fact, we have described explicitly the Chow ring for aQ-factorial toric variety as the Stanley-Reisner ring for the corresponding fan modulo the linear equivalence relation. In this paper, we calculate the Chow ring for 3-dimensionalQ-factorial toric varieties having one bad isolated singularity.