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191.
The surface reaction pathways of isothiazole and thiazole on Si(100)?2?×?1 surface were theoretically investigated using multireference wavefunctions. In the case of isothiazole, the Si?CN dative adduct turned out to be the major surface product. In contrast, a direct reaction competition between a concerted [4?+?2]CC cycloaddition and Si?CN dative adduct was found in the adsorption of thiazole. Therefore, it is concluded that the particular geometric arrangements of heteroatoms exhibit distinctly different initial surface reaction mechanisms. 相似文献
192.
Rowdra Ghatak Dipak R. Poddar Rabindra K. Mishra 《AEUE-International Journal of Electronics and Communications》2009,63(4):279-286
This article compares input impedances and radiation characteristics of half wavelength Koch fractal V–electric dipoles having included angles 60°, 90° and 120°. The study considers three structures. In the 1st structure the Koch arms open into the V-region, in 2nd structure they open away from the V-region and in the third structure, one arm opens into and the other away from the V-region. A first iteration, structure 1 of V-Koch electric dipole antenna with included angle of 120° was fabricated and the experimental return loss was in good agreement with simulation. At their first resonances the antennas’ gain and input resistance decrease with decrease in included angles, an observation synonymous to Euclidian electric dipoles. In terms of gain, the first structure is found to give better performance than the other two. For this structure, the pattern distortion at the second resonance was also less compared to the other structures. 相似文献
193.
Subrata Saha Dr. I. Ravikumar Prof. Pradyut Ghosh 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(49):13626-13626
194.
Dipak Maity S.N. Kale Jun-Min Xue 《Journal of magnetism and magnetic materials》2009,321(19):3093-3098
In this paper, water-soluble magnetite nanoparticles have been directly synthesized by thermal decomposition of iron (III) acetylacetonate, Fe(acac)3 in tri(ethyleneglycol). Size and morphology of the nanoparticles are determined by transmission electron microscopy (TEM) and dynamic light scattering (DLS) measurements while the crystal structure is identified using X-ray diffraction (XRD). Surface charge and surface coating of the nanoparticles are recognized using Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectra (XPS) and zeta potential measurements. Magnetic properties are determined using vibrating sample magnetometer (VSM) and superconducting quantum interference device (SQUID) measurements. The results show that as-prepared magnetite nanoparticles are relatively monodisperse, single crystalline and superparamagnetic in nature with the blocking temperature at around 100 K. The magnetite nanoparticles are found to be highly soluble in water due to steric and electrostatic interactions between the particles arising by the surface adsorbed tri(ethyleneglycol) molecules and associated positive charges, respectively. Cytotoxicity studies on human cervical (SiHa), mouse melanoma (B16F10) and mouse primary fibroblast cells demonstrate that up to a dose of 80 μg/ml, the magnetic nanoparticles are nontoxic to the cells. Specific absorption rate (SAR) value has been calculated to be 885 and 539 W/gm for samples with the iron concentration of 1 and 0.5 mg/ml, respectively. The high SAR value upon exposure to 20 MHz radiofrequency signifies the applicability of as-prepared magnetite nanoparticles for a feasible magnetic hyperthermia treatment. 相似文献
195.
196.
197.
Subhasis Mallick Subala Mondal Arup Mandal Biplab K. Bera Parnajyoti Karmakar Alak K. Ghosh 《国际化学动力学杂志》2011,43(9):498-506
The kinetics of the interaction of three glycine‐containing dipeptides, namely, glycine‐L‐leucine (Gly‐Leu), glycine‐L‐isoleucine (Gly‐Ile), and glycine‐valine (Gly‐Val) with [Pt(en)(H2O)2](ClO4)2 has been studied spectrophotometrically as a function of [substrate complex], [dipeptides] and temperature at a particular pH(4.0), where the substrate complex exists predominantly as the diaqua species and the dipeptides as a zwitterion. The substitution reaction shows two consecutive steps; the first is the ligand‐assisted anation and the second is the chelation step. The activation parameters for both the steps were evaluated using Eyring's equation. The low ΔH1≠ and large negative value of ΔS1≠ as well as ΔH2≠ and ΔS2≠ indicate an associative mode of activation for both the aqua ligand substitution processes. © 2011 Wiley Periodicals, Inc. Int J Chem Kinet 43: 498–506, 2011 相似文献
198.
The reactions of p‐nitrophenyl acetate (PNPA) with a series of monopyridinium oximes, viz. 2‐PAM (2‐hydroxyiminomethyl‐1‐methylpyridinium iodide), 3‐PAM (3‐hydroxyiminomethyl‐1‐methylpyridinium iodide), and 4‐PAM (4‐hydroxyiminomethyl‐1‐methylpyridinium iodide) have been studied in the presence of cationic surfactants of same hydrophobic chain length (C16) within the concentration range of 0.5–6.0 mM at pH 8.0 under the pseudo‐first‐order condition. The observed rate constant (kobs) increases with increasing surfactant concentration culminating into a maximum, and this has been analyzed in detail following the concepts of micellar catalysis. The structure–activity relationship of the investigated oximes has been discussed, and 2‐PAM was found to be the most reactive among all the three investigated oximes for the cleavage of PNPA. Esterolytic decomposition of p‐nitrophenyldiphenyl phosphate with oximate ions (? CH?NO?) was followed in cetyltrimethylammonium bromide micelles at pH 9.0, and 4‐PAM was the most reactive oxime for the micellar hydrolysis of phosphate ester. The apparent acid dissociation constants (pKa) of the investigated oximes have been determined spectrophotometrically. © 2011 Wiley Periodicals, Inc. Int J Chem Kinet 43: 569–578, 2011 相似文献
199.
Sadhan Ghosh 《Journal of magnetism and magnetic materials》2011,323(5):552-556
This work reports isothermal reversible variation of magnetization in nanoporous Pd-Ni alloys subjected to continuous charging and discharging of the sample in aprotic electrolyte medium. Polarizing metal surface with excess charge also finds strain in the nanoporous structure using the sample as working electrode. Therefore, it is proposed that pressure induced by strain is the key parameter for the observed reversible magnetization in the transition metal alloys. 相似文献
200.
The preparation of capped metal oxide nanoparticles through the hydrolysis of metal salts is made arduous by the difficulty of dissolving long organic chain capping agents in water; by performing the reaction in propylene glycol under reflux, instead of water, we are able to hydrolyse FeCl3 in the presence of n-octylamine to obtain (repeatedly) soluble, monodisperse approximately 5 nm gamma-Fe2O3 particles that display a tendency to aggregate into superlattices. 相似文献