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排序方式: 共有645条查询结果,搜索用时 734 毫秒
111.
电沉积法制备铂纳米粒子过程中卤素阴离子对粒子形貌及电催化性质的影响 总被引:2,自引:0,他引:2
在电化学沉积铂纳米粒子的过程中, 通过添加卤素阴离子, 可以显著地改变纳米粒子的形貌. 通过添加氯离子、溴离子和碘离子, 可以在导电基底上分别获得球形、片状及立方结构的铂纳米粒子. 对卤素阴离子影响电沉积铂纳米粒子形貌的原因进行了探讨. 研究了铂纳米粒子的电催化活性, 发现通过添加卤素阴离子制备得到的铂纳米粒子对于甲醇的电化学催化氧化表现出较低的电化学催化活性. 通过电化学氧化法全部或部分除去铂表面吸附的卤素阴离子后, 纳米粒子对甲醇的电化学催化氧化活性显著提高. 相似文献
112.
Naibo Lin Xiang Yang Liu Ying Ying Diao Hongyao Xu Chunyan Chen Xinhua Ouyang Hongzhi Yang Wei Ji 《Advanced functional materials》2012,22(2):361-368
A generic and effective approach to “switch on” and enhance the two‐photon fluorescence (TPF) emission of quenched TPF molecules, i.e., fluorene derivatives, is reported in terms of molecular recognition with a decoupling medium. Such a medium, in this case Bombyx mori silk, can recognize TPF molecules and inhibit the aggregation of the TPF molecules. The designed TPF molecules are 2,7‐bis[2‐(4‐nitrophenyl)ethenyl]‐9,9‐dibutylfluorene ( 4NF ) and 2,7‐bis[2‐(4‐nitrophenyl)ethenyl]‐9,9‐dioctylfluorene ( 8NF ), which exhibit suppressed TPF emission owing to molecular‐stacking‐led aggregation in the solid form. Due to the specific recognition between –NO2 in the quenched fluorescent molecules and –NH groups in silk fibroin molecules, the aggregated molecules of 4NF / 8NF molecules are decoupled. This decoupling gives rise to a significant increase in TPF quantum yields. The mechanism is further confirmed by replacing the terminal group –NO2 in 8NF with –CH3 (in 2,7‐bis[2‐(4‐methylphenyl)ethenyl]‐9,9‐dioctylfluorene; 8MF ) to eliminate the possibility of molecular recognition. As predicted, in the case of 8MF the switching‐on effect is eliminated. Completely new TPF silk fibers can additionally be applied in real‐time 3D high‐resolution TPF scaffold bioimaging. 相似文献
113.
Long Li Kaisheng Diao Yuqiu Ding Xianhong Yin 《Molecular Crystals and Liquid Crystals》2014,588(1):63-73
Three new metal–organic complexes, [CoL2(H2O)4] 1, [CdL2(H2O)2] 2, and [CuL2(H2O)2] 3 [HL = 4-chlorophenyloxyacetic acid], have been synthesized and characterized by IR spectra, elemental analysis, fluorescence spectra, and single-crystal X-ray diffraction. Compounds 1, 2, and 3 are all zero-dimensional dimers. The carboxylate ligand exhibits different coordination modes in all compounds. These compounds exhibit interesting supramolecular architecture according to O–H···O and C–H···Cl interactions. Compounds 1, 2, and 3 develop to different framework though they all are from same ligands, which will be helpful to design of different materials.
[Supplemental materials are available for this article. Go to the publisher's online edition of Molecular Crystals and Liquid Crystals to view the free supplemental file: CCDC 902676, 902674, 902675 contains the supplementary crystallographic data for this article. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB2 1EZ, UK; Fax: C44 1223 336033; e-mail: deposit@ccdc.cam.ac.uk).] 相似文献
114.
硅烯是由单层硅原子形成的二维蜂窝状晶格结构,具有石墨烯类似的电学性质,由于硅烯中存在比较强的自旋轨道耦合而备受关注.本文利用非平衡格林函数方法研究了门电压控制的硅烯量子线中电子输运性质和能带结构.研究发现,只有在较强的门电压下,而且硅烯量子线具有较好的锯齿形或扶手椅形边界而不存在额外硅原子时,硅烯量子线中才存在无能隙的自旋极化边缘态.另外,计算结果表明这种门电压控制的硅烯量子线中边缘态在每个能谷处自旋是极化的.这些计算结果将为实验上利用电场制作硅烯纳米结构提供理论支持. 相似文献
115.
H Zhou GW Diao SY Qian XZ Yang AH Yuan Y Song YZ Li 《Dalton transactions (Cambridge, England : 2003)》2012,41(35):10690-10697
The reaction of [W(CN)(8)](3-) with Ln(3+) and pyrazine in acetonitrile yielded a series of isostructural compounds formulated as Ln(H(2)O)(4)(pyrazine)(0.5)W(CN)(8) (Ln = La(1), Ce(2), Pr(3), Nd(4), Sm(5), Eu(6), Gd(7)). The Ln(iii) and W(v) centers in the structure are linked through cyanide groups to form two-dimensional (2D) layers, which are further pillared by pyrazine, generating 3D frameworks. The magnetic behavior for compounds 1-7 were driven by the lanthanide ions involved. The Ln(iii) and W(v) ions in compounds 2 and 5 are ferromagnetically coupled with magnetic ordering occurring at 2.8 K, comparable with magnetic ordering with the critical temperature of 1.9 K for compound 4. In addition, the antiferromagnetic interactions were observed in compounds 3 and 7, while no significant magnetic couplings were found in compounds 1 and 6. 相似文献
116.
Counting is one of the most basic procedures in mathematics and statistics. In statistics literature it is usually done via
the proportion estimation method. In this article we manifest a radically different counting procedure first proposed in the
late 1990’s based on the techniques of quantum computation. It combines two major tools in quantum computation, quantum Fourier
transform and quantum amplitude amplification, and shares similar structure to the quantum part of the celebrated Shor’s factoring
algorithm. We present complete details of this quantum counting algorithm and the analysis of its error distribution. Comparing
it with the conventional proportion estimation method, we demonstrate that this quantum approach achieves much faster convergence
rate than the classical approach. 相似文献
117.
相对于单层电极结构,优化的前表面双层电极能够明显减小功率损失,改善晶体硅太阳电池的电学特性.本文对晶体硅太阳电池的双层电极进行了优化分析和实验研究.通过扫描电子显微镜观测将双层电极的截面抽象为更接近于实际的半椭圆型,建立了太阳电池前表面的双层电极模型,理论分析了双层电极的电学损失和光学损失.结合丝网印刷后光诱导电镀太阳电池的实验,得到了理论和实验上的最优化光诱导电镀增厚电极厚度与丝网印刷电极宽度的关系.所得到的理论和实验结果符合良好.由于并不涉及电极制备的具体技术,双层电极理论模型普遍适用于多种类型的双层电极结构. 相似文献
118.
A 1 064-nm pulsed coherent Doppler lidar (CDL) prototype is developed to measure short range wind speed in the lower altitude troposphere layer. The CDL system adopts an injection-seeded Nd:YAG laser with the pulse duration of 80 ns, single pulse energy of 0.5 mJ, and pulse repetition rate of 200 Hz. Speed calibration experiments are implemented to obtain a speed accuracy of 0.3 m/s using a hard target. Data analysis results show that the CDL system can obtain a line-of-sight wind velocity at a range of 30 to 500 m with the range resolution of 40 m and 38 pulses accumulation. 相似文献
119.
We consider a class of cure rate frailty models for multivariate failure time data with a survival fraction. This class is formulated through a transformation on the unknown population survival function. It incorporates random effects to account for the underlying correlation, and includes the mixture cure model and the proportional hazards cure model as two special cases. We develop efficient likelihood-based estimation and inference procedures. We show that the nonparametric maximum likelihood estimators for the parameters of these models are consistent and asymptotically normal, and that the limiting variances achieve the semiparametric efficiency bounds. Simulation studies demonstrate that the proposed methods perform well in finite samples. We provide an application of the proposed methods to the data of the age at onset of alcohol dependence, from the Collaborative Study on the Genetics of Alcoholism. 相似文献
120.
Networks of topologically linked minicircle polymers are found in diverse natural systems and are a subject of intense research
in nanotechonology. In a recent report the authors introduced a new theoretical model to study the effects of polymer density
on the formation and on the topological properties of minicircle networks. Three key topological characteristics were identified
in the formation and characterization of a network: the critical percolation density, the average saturation density and the
mean valence of the network. In this work we report how these characteristics change when an orientation bias is imposed on
the minicircles forming the network. We observe that such restrictions have significant effects on the key topological characteristics
of the network. In particular while the effects of restriction of the tilting angle can be predicted we find that those of
the azimuthal angle can have somewhat unexpected results. 相似文献