全文获取类型
收费全文 | 1275篇 |
免费 | 71篇 |
专业分类
化学 | 950篇 |
晶体学 | 8篇 |
力学 | 25篇 |
数学 | 141篇 |
物理学 | 157篇 |
无线电 | 65篇 |
出版年
2024年 | 3篇 |
2023年 | 19篇 |
2022年 | 60篇 |
2021年 | 62篇 |
2020年 | 45篇 |
2019年 | 44篇 |
2018年 | 24篇 |
2017年 | 40篇 |
2016年 | 68篇 |
2015年 | 50篇 |
2014年 | 53篇 |
2013年 | 97篇 |
2012年 | 104篇 |
2011年 | 103篇 |
2010年 | 50篇 |
2009年 | 50篇 |
2008年 | 67篇 |
2007年 | 66篇 |
2006年 | 44篇 |
2005年 | 46篇 |
2004年 | 32篇 |
2003年 | 30篇 |
2002年 | 32篇 |
2001年 | 12篇 |
2000年 | 12篇 |
1999年 | 7篇 |
1998年 | 10篇 |
1997年 | 4篇 |
1996年 | 17篇 |
1995年 | 7篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 7篇 |
1988年 | 6篇 |
1986年 | 2篇 |
1984年 | 2篇 |
1983年 | 4篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 4篇 |
1977年 | 4篇 |
1976年 | 7篇 |
1975年 | 3篇 |
1973年 | 2篇 |
1972年 | 3篇 |
1971年 | 2篇 |
1967年 | 3篇 |
排序方式: 共有1346条查询结果,搜索用时 15 毫秒
71.
Ana Margarida Silva Diana Pinto Iva Fernandes Victor de Freitas María de la Luz Cdiz-Gurrea Paulo Costa Cristina Delerue-Matos Francisca Rodrigues 《Molecules (Basel, Switzerland)》2021,26(8)
During kiwiberry production, different by-products are generated, including leaves that are removed to increase the fruit’s solar exposure. The aim of this work was to extract bioactive compounds from kiwiberry leaf by employing microwave-assisted extraction (MAE). Compatible food solvents (water and ethanol) were employed. The alcoholic extract contained the highest phenolic and flavonoid contents (629.48 mg of gallic acid equivalents (GAE) per gram of plant material on dry weight (dw) (GAE/g dw) and 136.81 mg of catechin equivalents per gram of plant material on dw (CAE/g dw), respectively). Oppositely, the hydroalcoholic extract achieved the highest antioxidant activity and scavenging activity against reactive oxygen and nitrogen species (IC50 = 29.10 μg/mL for O2•−, IC50 = 1.87 μg/mL for HOCl and IC50 = 1.18 μg/mL for •NO). The phenolic profile showed the presence of caffeoylquinic acids, proanthocyanidin, and quercetin in all samples. However, caffeoylquinic acids and quercetin were detected in higher amounts in the alcoholic extract, while proanthocyanidins were prevalent in the hydroalcoholic extract. No adverse effects were observed on Caco-2 viability, while the highest concentration (1000 µg/mL) of hydroalcoholic and alcoholic extracts conducted to a decrease of HT29-MTX viability. These results highlight the MAE potentialities to extract bioactive compounds from kiwiberry leaf. 相似文献
72.
73.
Kettle SF Boccaleri E Diana E Rossetti R Stanghellini PL Iapalucci MC Longoni G 《Inorganic chemistry》2003,42(20):6314-6322
The nu(CO) vibrational spectra of planar transition cluster carbonyls containing M(CO)(4) groups are studied. It is possible to anticipate qualitatively, both for the infrared and Raman, the band intensity changes associated with increasing metallic nature of the cluster. These enable a unification of the band patterns shown by the species reported. As for (idealized) spherical clusters, the spherical harmonic model (SHM), suitably modified, becomes of more general applicability as cluster size increases, although for smaller species the tensor harmonic model (THM) makes a contribution. 相似文献
74.
The linear stability analysis of the natural convection in a rectangular tilted infinite cavity filled with a Boussinesq fluid subject to Coriolis force is presented. The bottom and top surfaces have fixed temperatures. Both unstable and stable thermal conditions are studied (heated from below and heated from above respectively). The rotation axis passes through the center and it is orthogonal to the hot and cold surfaces. The stability equations were solved using the Tau–Chebyshev spectral method. The critical Rayleigh number and critical wave number were obtained for several rotation rates and different orientation of convective oblique rolls in a range of inclination of the cavity from 0 to 120 degrees. The stability analysis show that rotation rate affects the basic velocity profile, onset of convection, wave number and critical orientation of convective rolls. 相似文献
75.
Asymptotic conditional distribution of exceedance counts: fragility index with different margins 总被引:1,自引:0,他引:1
We consider a random vector X, whose components are neither necessarily independent nor identically distributed. The fragility index (FI), if it exists, is defined as the limit of the expected number of exceedances among the components of X above a high threshold, given that there is at least one exceedance. It measures the asymptotic stability of the system of components. The system is called stable if the FI is one and fragile otherwise. In this paper, we show that the asymptotic conditional distribution of exceedance counts exists, if the copula of X is in the domain of attraction of a multivariate extreme value distribution, and if the marginal distribution functions satisfy an appropriate tail condition. This enables the computation of the FI corresponding to X and of the extended FI as well as of the asymptotic distribution of the exceedance cluster length also in that case, where the components of X are not identically distributed. 相似文献
76.
Jorge Ivn Castro Diana Paola Navia-Porras Jaime Andrs Arbelez Corts Jos Herminsul Mina Hernndez Carlos David Grande-Tovar 《Molecules (Basel, Switzerland)》2022,27(7)
The indiscriminate use of plastic in food packaging contributes significantly to environmental pollution, promoting the search for more eco-friendly alternatives for the food industry. This work studied five formulations (T1–T5) of biodegradable cassava starch/gelatin films. The results showed the presence of the starch/gelatin functional groups by FT-IR spectroscopy. Differential scanning calorimetry (DSC) showed a thermal reinforcement after increasing the amount of gelatin in the formulations, which increased the crystallization temperature (Tc) from 190 °C for the starch-only film (T1) to 206 °C for the film with 50/50 starch/gelatin (T3). It also exhibited a homogeneous surface morphology, as evidenced by scanning electron microscopy (SEM). However, an excess of gelatin showed low compatibility with starch in the 25/75 starch/gelatin film (T4), evidenced by the low Tc definition and very rough and fractured surface morphology. Increasing gelatin ratio also significantly increased the strain (from 2.9 ± 0.5% for T1 to 285.1 ± 10.0% for T5) while decreasing the tensile strength (from 14.6 ± 0.5 MPa for T1 to 1.5 ± 0.3 MPa for T5). Water vapor permeability (WVP) increased, and water solubility (WS) also decreased with gelatin mass rising in the composites. On the other hand, opacity did not vary significantly due to the films’ cassava starch and gelatin ratio. Finally, optimizing the mechanical and water barrier properties resulted in a mass ratio of 53/47 cassava starch/gelatin as the most appropriate for their application in food packaging, indicating their usefulness in the food-packaging industry. 相似文献
77.
Tantalum Sulfide Nanosheets as a Theranostic Nanoplatform for Computed Tomography Imaging‐Guided Combinatorial Chemo‐Photothermal Therapy 下载免费PDF全文
Yanlan Liu Xiaoyuan Ji Jianhua Liu Winnie W. L. Tong Diana Askhatova Jinjun Shi 《Advanced functional materials》2017,27(39)
Near‐infrared (NIR)‐absorbing metal‐based nanomaterials have shown tremendous potential for cancer therapy, given their facile and controllable synthesis, efficient photothermal conversion, capability of spatiotemporal‐controlled drug delivery, and intrinsic imaging function. Tantalum (Ta) is among the most biocompatible metals and arouses negligible adverse biological responses in either oxidized or reduced forms, and thus Ta‐derived nanomaterials represent promising candidates for biomedical applications. However, Ta‐based nanomaterials by themselves have not been explored for NIR‐mediated photothermal ablation therapy. In this work, an innovative Ta‐based multifunctional nanoplatform composed of biocompatible tantalum sulfide (TaS2) nanosheets (NSs) is reported for simultaneous NIR hyperthermia, drug delivery, and computed tomography (CT) imaging. The TaS2 NSs exhibit multiple unique features including (i) efficient NIR light‐to‐heat conversion with a high photothermal conversion efficiency of 39%, (ii) high drug loading (177% by weight), (iii) controlled drug release triggered by NIR light and moderate acidic pH, (iv) high tumor accumulation via heat‐enhanced tumor vascular permeability, (v) complete tumor ablation and negligible side effects, and (vi) comparable CT imaging contrast efficiency to the widely clinically used agent iobitridol. It is expected that this multifunctional NS platform can serve as a promising candidate for imaging‐guided cancer therapy and selection of cancer patients with high tumor accumulation. 相似文献
78.
It is reported the production and characterization of silica nano-particles by Californian-red worms through a bio-digestion process of rice husk; the rice husk contains, naturally, high concentrations of silica (22%). The worms were fed gradually with rice husk and water during 5 months to clean the worm’s digestive system from other types of food. The humus was collected, dried at room temperature, pH neutralized and calcined at different temperatures (500, 600 and 700 °C) to remove the organic matter. The calcined humus was digested to remove traces of inorganic compounds. The size of the silica particles was in the range from 55 to 250 nm depending on calcination temperatures. The efficiency in the production of the particles was 88%. These results were compared with those obtained using other agro-industrial wastes that contain silica: coffee (12%) and cane (8%) husk. The samples were characterized by XRD, FTIR, EDS, DLS, SEM and TEM. 相似文献
79.
80.
Sather-Wagstaff Sean; Sharif Tirdad; White Diana 《Journal London Mathematical Society》2008,77(2):481-502
We show that an iteration of the procedure used to define theGorenstein projective modules over a commutative ring R yieldsexactly the Gorenstein projective modules. Specifically, givenan exact sequence of Gorenstein projective R-modules
such that the complexes HomR(G, H) and HomR(H,G) are exact for each Gorenstein projective R-module H, themodule Coker() is Gorensteinprojective. The proof of this result hinges upon our analysisof Gorenstein subcategories of abelian categories. 相似文献