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101.
102.
An 'objective' method for determining conformational equilibria in substituted ethanes, proposed by Abraham et al., has been evaluated by computational methods. Abraham's method involves measuring vicinal couplings, such as (3)J(H,H) and (3)J(H,F), between methine and methylene protons with methine, methylene protons and fluorine in a range of solvents, on the assumption that the underlying coupling constants of the individual conformers are constant, but the fractions of each conformer in each solvent are different and unknown. Abraham posited that this would produce an 'over-determined' data set with more equations than unknowns would. Abraham's procedure is re-evaluated, and it is demonstrated that the type of system being considered here, where there are more equations than unknowns, is not necessarily over-determined. A computer equation solver and Monte Carlo-type procedures were employed to demonstrate that multiple numerical solutions exist for a representative 'over-determined' data set provided by Abraham. A statistical method was also developed to determine precisely which parameter sets constitute plausible solutions. 相似文献
103.
Quantum theory as a universal physical theory 总被引:1,自引:0,他引:1
David Deutsch 《International Journal of Theoretical Physics》1985,24(1):1-41
The problem of setting up quantum theory as a universal physical theory is investigated. It is shown that the existing formalism, in either the conventional or the Everett interpretation, must be supplemented by an additional structure, the interpretation basis. This is a preferred ordered orthonormal basis in the space of states. Quantum measurement theory is developed as a tool for determining the interpretation basis. The augmented quantum theory is discussed. 相似文献
104.
Widmer A.X. Wrenner K. Ainspan H.A. Parker B. Austruy P. Brezzo B. Haen A.-M. Ewen J.F. Soyuer M. Blanc A. Abbiate J.-C. Deutsch A. Hyun J. Shin 《Solid-State Circuits, IEEE Journal of》1996,31(12):2004-2014
A CMOS chip containing four 500-MBd serializer/deserializer pairs has been designed to relieve interconnect congestion in an ATM switch system. The 9.7×9.7 mm2 chip fabricated in a 0.8-μm technology is packaged on a ceramic ball grid array and dissipates 3.5 W. It replaces a 72-wire parallel interface with an eight-line serial interface transparent to the user and supports transmission at 1.6 Gb/s per direction in full-duplex mode. Virtually error-free operation in a system environment over electrical serial links having up to 9 dB loss at 500 MHz has been realized using signal predistortion for the serial bit stream and PLL clock recovery for each of the four receivers. Interface timing and serial-link driver strength are programmable 相似文献
105.
For the isocratic ion chromatography (IC) separation of low-molecular-mass organic acids and inorganic anions three different anion-exchange columns were studied: IonPac AS14 (9 μm particle size), Allsep A-2 (7 μm particle size), and IC SI-50 4E (5 μm particle size). A complete baseline separation for all analyzed anions (i.e., F−, acetate, formate, Cl−, NO2−, Br−, NO3−, HPO42− and SO42−) in one analytical cycle of shorter than 17 min was achieved on the IC SI-50 4E column, using an eluent mixture of 3.2 mM Na2CO3 and 1.0 mM NaHCO3 with a flow rate of 1.0 mL min−1. On the IonPac AS14 column, it was possible to separate acetate from inorganic anions in one run (i.e., less than 9 min), but not formate, under the following conditions: 3.5 mM Na2CO3 plus 1.0 mM NaHCO3 with a flow rate of 1.2 mL min−1. Therefore, it was necessary to adapt a second run with a 2.0 mM Na2B4O7 solution as an eluent under a flow rate of 0.8 mL min−1 for the separation of organic ions, which considerably enlarged the analysis time. For the Allsep A-2 column, using an eluent mixture of 1.2 mM Na2CO3 plus 1.5 mM NaHCO3 with a flow rate of 1.6 mL min−1, it was possible to separate almost all anions in one run within 25 min, except the fluoride-acetate critical pair. A Certified Multianion Standard Solution PRIMUS for IC was used for the validation of the analytical methods. The lowest RSDs (less than 1%) and the best LODs (0.02, 0.2, 0.16, 0.11, 0.06, 0.05, 0.04, 0.14 and 0.09 mg L−1 for F−, Ac−, For−, Cl−, NO2−, Br−, NO3−, HPO42− and SO42−, respectively) were achieved using the IC SI-50 4E column. This column was applied for the separation of concerned ions in environmental precipitation samples such as snow, hail and rainwater. 相似文献
106.
Orit Ravid-Hermesh Naomi Zurgil Yana Shafran Maria Sobolev Moti Galmidi Yoav Badihi Liron Limor Israel Jean Paul Lellouche Emmanuel Lellouche Shulamit Michaeli Mordechai Deutsch 《Analytical and bioanalytical chemistry》2014,406(28):7085-7101
Cell populations represent intrinsically heterogeneous systems with a high level of spatiotemporal complexity. Monitoring and understanding cell-to-cell diversity is essential for the research and application of intra- and interpopulation variations. Optical analysis of live cells is challenging since both adherent and nonadherent cells change their spatial location. However, most currently available single-cell techniques do not facilitate treatment and monitoring of the same live cells over time throughout multistep experiments. An imaging-dish-based live cell array (ID-LCA) has been developed and produced for cell handling, culturing, and imaging of numerous live cells. The dish is composed of an array of pico scale cavities—pico wells (PWs) embossed on its glass bottom. Cells are seeded, cultured, treated, and spatiotemporally measured on the ID-LCA, while each cell or small group of cells are locally constrained in the PWs. Finally, predefined cells can be retrieved for further evaluation. Various types of ID-LCAs were used in this proof-of-principle work, to demonstrate on-ID-LCA transfection of fluorescently tagged chimeric proteins, as well as the detection and kinetic analysis of their induced translocation. High variability was evident within cell populations with regard to protein expression levels as well as the extent and dynamics of protein redistribution. The association of these parameters with cell morphology and functional parameters was examined. Both the new methodology and the device facilitate research of the translocation process at individual cell resolution within large populations and thus, can potentially be used in high-throughput fashion. Graphical Abstract
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107.
108.
Raja Mohamed Beema Shafreen Selvaraj Alagu Lakshmi Shunmugiah Karutha Pandian Young-Mo Kim Joseph Deutsch Elena Katrich Shela Gorinstein 《Molecules (Basel, Switzerland)》2021,26(21)
Previous reports have shown that consumption of wine has several health benefits; however, there are different types of wine. In the present study, red wines were investigated for their compositions of active ingredients. The interaction of each component in terms of its binding mode with different serum proteins was unraveled, and the components were implicated as drug candidates in clinical settings. Overall, the study indicates that red wines have a composition of flavonoids, non-flavonoids, and phenolic acids that can interact with the key regions of proteins to enhance their biological activity. Among them, rutin, resveratrol, and tannic acid have shown good binding affinity and possess beneficial properties that can enhance their role in clinical applications. 相似文献
109.
H. Kersten H. Deutsch E. Stoffels W.W. Stoffels G.M.W. Kroesen R. Hippler 《等离子体物理论文集》2001,41(6):598-609
The research effort in the area of dusty plasmas initially aimed at avoiding particle formation and controlling the contamination level in industrial reactors. Nowadays, dusty plasmas have grown into a vast field and new applications of plasma‐processed dust particles are emerging. There is demand for particles with special properties, and for particle‐seeded composite materials. Low‐pressure plasmas offer a unique possibility of confinement, control and fine tailoring of particle properties. The role of plasma technology in treatment and surface modification of powder grains is reviewed and illustrated with examples. The interaction between plasma and injected micro‐disperse powder particles can also be used as a diagnostic tool for the study of plasma surface processes. 相似文献
110.
Luigi Genovese Brice Videau Matthieu Ospici Thierry Deutsch Stefan Goedecker Jean-François Méhaut 《Comptes Rendus Mecanique》2011,339(2-3):149-164
In this contribution we will describe in detail a Density Functional Theory method based on a Daubechies wavelets basis set, named BigDFT. We will see that, thanks to wavelet properties, this code shows high systematic convergence properties, very good performances and an excellent efficiency for parallel calculations. BigDFT code operation are also well-suited for GPU acceleration. We will discuss how the problematic of fruitfully benefit of this new technology can be match with the needs of robustness and flexibility of a complex code like BigDFT. This work may be of interest not only for expert in electronic structure calculations, but may also provide feedback to the wider community of high performance scientific computing. 相似文献