Über die Bedeutung von Diffusionsgrenzschichten bei Ionenaustauschvorgängen

Based on NMR imaging results of the spatial and temporal development of ion exchange processes in alginate gels, the question of appropriate modelling of these processes is discussed. For rare earth and actinoid ions, the behaviour is found to correspond qualitatively to the expectations of Stefan’s model (shrinking core model, SCM). However, quantitative correspondence of the experimental data with the model can only be achieved when an additional diffusive layer at the surface of the ion exchange material is assumed. An extension of the SCM with respect to this problem is derived.     

Cylindrical spike model for the formation of diamondlike thin films by ion deposition

T /n_S of n_T rearrangements and n_S atoms in the spike volume as the crucial parameter characterizing the ability of a given ion–target combination to achieve complete rearrangement of the spike volume. n_T/n_S>1 is the optimum condition for diamondlike film growth. For aC films the ion energy dependence of n_T/n_S agrees well with the measured sp³ bond fraction. For Ar⁺-ion-assisted deposition of aC we find n_T/n_S>1 above 50 eV with no pronounced ion energy dependence. Furthermore, our model predicts optimum conditions for the formation of cubic boron nitride between 50 eV and 3 keV. Accepted: 14 October 1997     

Problem of the Sand Production in a Producing Well

The problem of sand production (dilatant-plastic reservoir fragmentation) in the process of pumping-out fluid through an uncased borehole is considered. Taking the dilatant change in reservoir porosity into account makes it possible to find a relation between the fluid and solid mass flow rates. There is no steady-state solution if the elasto-plastic boundary does not coincide with the supply contour. In this case a self-similar problem of well start-up with a constant production rate is considered.     

Research in the field of functionally substituted azines. Syntheses of imidazolidinyl-sym-triazines

New approaches have been developed for the application of cyanamino-sym-triazines in the synthesis of imidazolidinyl-sym-triazines.     

Rechargeable batteries for mobile communications

A critical component of mobile phones and other portable equipment is the battery. This paper reviews the characteristics of the nickel cadmium, nickel metal hydride and lithium ion cells, the three types of cells currently available for use in the mobile communications market. The future possibilities within the rechargeable battery market are also discussed     

Slow crack growth in blends of HDPE and model copolymers

The resistance to slow crack growth (SCG) was measured in binary blends of high density polyethylene (HDPE) and 5–10% concentrations of model ethylene-butene random copolymers by measuring the time to failure (t_f) under a constant stress intensity. An increase of t_f with the addition of the copolymer if the copolymer could crystallize and the increase was greater the higher branch density. The copolymer with 117 branches/1000C could not crystallize and therefore its blend had a t_f that was less than that of the HDPE. The fracture energies of the blends as determined by their resistance to SCG were compared with the energy by rapid fracture, J_c, as previously measured by Rhee and Crist. It is concluded that SCG is more sensitive to variations in the microstructure than is rapid fracture and that the differences in SCG behavior can be qualitatively explained in terms of the differences in microstructure of the blends. ©1995 John Wiley & Sons, Inc.     

Recurrent solar wind streams

A new approach to investigating the statistical relationship between certain solar features and recurrent wind streams is presented. This approach is based, on a comparative analysis of the distributions of lifetimes of a set of solar features, recurrent geomagnetic disturbances, and geomagnetic “calms.” Correlation coefficients of 0.81, 0.85, 0.79, and 0.77 are found for the distributions of several solar features—filaments, large-scale magnetic fields, coronal features, and coronal holes, respectively—and recurrent geomagnetic disturbances. A correlation factor of 0.97 between the distributions of geomagnetic “calms” and active regions is found. The combined evidence indicates that no specific type of solar feature is responsible for the recurrent stream activity. Rather, the configuration of the large-scale magnetic field of the Sun appears to control the permanently existing corpuscular activity. Since prominences trace polarity division lines of the large-scale magnetic field structure of the Sun, they have been checked as a possible general predictor of recurrent corpuscular activity; their parameters could present the most reliable indices that relate closely with trends in geomagnetic disturbances. A comparative analysis of cyclic variations of sunspot numbers, the total number of prominences, the relative number of low-height (<-20″) prominences, and recurrent geomagnetic storms is made for solar cycle N16. The relative number of low-height prominences is found to correlate broadly (0.83) with recurrent wind streams. P. K. Shternberg State Astronomical Institute, Moscow, Russia; National Solar Observatory, Sacramento Peak, U.S. Published in Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 41, No. 2, pp. 145–151, February, 1998.