Compositional Study and Antioxidant Potential of <em>Ipomoea hederacea</em> Jacq. and <em>Lepidium sativum</em> L. Seeds

The present investigation has been carried out to determine the proximate composition, amino acids, metal contents, oil composition as well as the antioxidant capacity of the seeds of Ipomoea hederacea Jacq. and Lepidium sativum L. Proximate composition indicated a great difference in oil (14.09 ± 0.66, 28.03 ± 1.05) and fibre (16.55 ± 0.31, 6.75 ± 1.20) contents for I. hederacea and L. sativum, respectively. Fatty acid profile indicated that oleic acid (19.50 ± 0.37, 30.50 ± 0.16) and linoleic acid (52.09 ± 0.48, 8.60 ± 0.38) are the major fatty acids. γ-Tocopherol and d-tocopherol (28.70 ± 0.14, 111.56 ± 0.37) were the most abundant in the seed oil of I. hederacea and L. sativum, respectively. Results of TEAC, FRAP and TRAP antioxidant assays indicated that L. sativum has much greater antioxidant potential than I. hederacea.     

Formation of Quaternary Stereogenic Centers by NHC–Cu‐Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Polyconjugated Cyclic Enones

The copper‐catalyzed conjugate addition of various Grignard reagents to polyconjugated enones (dienone and enynone derivatives) is reported. The catalyst system, composed of copper triflate and an NHC ligand, led to the unusual selective formation of the 1,4‐addition products. This reaction allows for the creation of all‐carbon chiral quaternary centers with enantiomeric excesses up to 99 %. The remaining unsaturation on the 1,4 adducts give access to valuable synthetic transformations.     

Manipulation of Förster energy transfer of coupled fluorophores through biotransformation by Pseudomonas resinovorans CA10

An alkyne‐terminated anthracene and azide‐terminated carbazole were joined through a copper‐catalyzed cycloaddition to form a joined donor/acceptor pair. The photonic pair exhibited energy transfer when excited at the peak absorbance of carbazole and fluoresced with an anthracene spectral response. The fluorescent behavior was confirmed as Förster energy transfer (FRET). The lysate of Pseudomonas resinovorans CA10, a member of a predominant group of soil microorganisms that can metabolize a host of substrates, was employed to degrade the pair and alter the luminance spectral characteristics. The FRET was diminished and the corresponding, individual fluorescence of carbazole and anthracene returned. This general approach may find applications in single‐cell metabolic studies and bioactivity assays.     

Some cyclization reactions of 1,3-diphenylbenzo[e][1,2,4]triazin-7(1H)-one: preparation and computational analysis of non symmetrical zwitterionic biscyanines

Regioselective nucleophilic addition of bisnucleophiles 1,2-benzenediamine, 2-amino-benzenethiol, and N-phenyl-1,2-benzenediamine to 1,3-diphenylbenzo[e][1,2,4]triazin-7(1H)-one (1) at C6 followed by intramolecular cyclocondensation at the C7 carbonyl afforded highly coloured tetracenes 1,3-diphenyl-1,6-dihydro-[1,2,4]triazino[5,6-b]phenazin-4-ium 4-methylbenzenesulfonate (12), 1,3-diphenyl-1H-[1,2,4]triazino[6,5-b]phenothiazine (14) and 1,3,11-triphenyl-1,6-dihydro-[1,2,4]triazino[5,6-b]phenazin-11-ium 4-methylbenzenesulfonate (15), respectively. Neutralization of the latter with alkali gave the free base 1,3,11-triphenyl-1H-[1,2,4]triazino[5,6-b]phenazin-11-ium-6-ide (16). Furthermore, the benzotriazinone 1 reacts with dimethyl malonate to give 6-(methoxycarbonyl)-7-oxo-1,3-diphenyl-7H-benzofuro[5,6-e][1,2,4]triazin-1-ium-4-ide (17) in 74% yield, while with S(4)N(4) [5,6-c]-thiadiazolo-7-oxo-1,3-diphenyl-1,2,4-benzotriazine (22) was formed in 15% yield. The free bases 16 and 17 display negative solvatochromism, which supports charge separated ground states similar to those of zwitterionic biscyanines, and DFT calculations at the UB3LYP/6-31G(d) level afford ΔE(ST) values of -13.6 and -18.7 kcal mol(-1), respectively that strongly favour the singlet ground state. All ring systems described are new and fully characterized.     

Reverse Khas’minskii condition

The aim of this paper is to present and discuss some equivalent characterizations of p-parabolicity for complete Riemannian manifolds in terms of existence of special exhaustion functions. In particular, Khas’minskii in Ergodic properties of recurrent diffusion prossesses and stabilization of solution to the Cauchy problem for parabolic equations (Theor Prob Appl 5(2), 1960) proved that if there exists a 2-superharmonic function ${\mathcal{K}}$ defined outside a compact set on a complete Riemannian manifold R such that ${\lim_{x\to \infty} \mathcal{K}(x)=\infty}$ , then R is 2-parabolic, and Sario and Nakai in Classification theory of Riemann surfaces (Springer, Berlin, 1970) were able to improve this result by showing that R is 2-parabolic if and only if there exists an Evans potential, i.e. a 2-harmonic function ${E:R{\setminus} K \to \mathbb{R}^+}$ with ${\lim_{x\to \infty}\mathcal{E}(x)=\infty}$ . In this paper, we will prove a reverse Khas’minskii condition valid for any p?>?1 and discuss the existence of Evans potentials in the nonlinear case.     

On the intercalation of the iodine-iodide couple on layered double hydroxides with different particle sizes

Molecular iodine was intercalated from nonaqueous solution into microsized ZnAl-layered double hydroxide (LDH) in the iodide form, generating the I(3)(-)/I(-) redox couple into the interlayer region. Chloroform, ethanol, acetonitrile, or diethyl ether were used as solvents to dissolve the molecular iodine. The intercalation compounds were characterized by thermogravimetric analysis, X-ray powder diffraction, UV-vis spectroscopy, and scanning and transmission electron microscopy. The stability of iodine-solvent adducts and the iodine concentration affected the LDH iodine loading, and samples with I(2)/I(-) molar ratio ranging from 0.14 to 0.82 were prepared. Nanosized, well dispersible LDH, synthesized by the urea method in water-ethylene glycol media, were also prepared and successfully functionalized with the I(3)(-)/I(-) redox couple applying the conditions optimized for the micrometric systems.     

<Emphasis Type="Italic">ABCD</Emphasis>-<Emphasis Type="Italic">Tool</Emphasis>, a software suite for the analysis of α/β spectra from liquid scintillation counting

This paper presents the alpha/beta complete deconvolution tool (ABCD-Tool), a C++ application for the analysis of spectra from liquid scintillation counting (LSC) measurements. In addition to the basic algorithms for standard gross alpha/beta analysis and the determination of the counting efficiency, the software implements a recent unfolding technique based on Fourier transforms, which gives precise and reliable results even in the case of complex, strongly overlapping spectra. The application is designed to be used with alpha/beta spectra generated from Perkin Elmer Wallac Quantulus 1220. However, future upgrades are scheduled in order to extend the compatibility to spectra from other LSC instruments in commerce.     

On the Poincaré inequality for vector fields

We prove the Poincaré inequality for vector fields on the balls of the control distance by integrating along subunit paths. Our method requires that the balls are representable by means of suitable “controllable almost exponential maps”. Both authors were partially supported by the University of Bologna, funds for selected research topics.     

On the problem of spurious eigenvalues in the approximation of linear elliptic problems in mixed form

In the approximation of linear elliptic operators in mixed form, it is well known that the so-called inf-sup and ellipticity in the kernel properties are sufficient (and, in a sense to be made precise, necessary) in order to have good approximation properties and optimal error bounds. One might think, in the spirit of Mercier-Osborn-Rappaz-Raviart and in consideration of the good behavior of commonly used mixed elements (like Raviart-Thomas or Brezzi-Douglas-Marini elements), that these conditions are also sufficient to ensure good convergence properties for eigenvalues. In this paper we show that this is not the case. In particular we present examples of mixed finite element approximations that satisfy the above properties but exhibit spurious eigenvalues. Such bad behavior is proved analytically and demonstrated in numerical experiments. We also present additional assumptions (fulfilled by the commonly used mixed methods already mentioned) which guarantee optimal error bounds for eigenvalue approximations as well.

     

Non–Isothermal Shear Band Localization in Crystal Plasticity

We analyze the formation of shear bands in plastically deforming single crystals under non-isothermal quasi-static loading conditions. A key feature of the present work is to motivate the constitutive coupled thermomechanical equations for the slip resistance and the slip evolution by micromechanical investigations of defects in crystals. Here, we put particular emphasis on comparative investigations of hardening–softening effects of crystals under non-isothermal conditions, including a quantification of the latent energy storage. Furthermore, we analyze a numerical solution algorithm for the coupled thermomechanical problem and we test the performance on a typical benchmark example of finite-strain single-crystal thermoplasticity: the localization of deformation into a shear band for the case of a rectangular strip. Experimental evidence for this problem is well documented. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)