楔形盒染料掺杂胆甾相液晶激光器研究

设计制作了楔形盒掺杂激光染料PM580的胆甾相液晶器件, 研究了激光辐射行为. 在楔形液晶盒中出现了一系列与楔棱平行的向错线和不同规则形状的晶畴, 胆甾相液晶形成了平面态排列. 采用固体Nd:YAG倍频532 nm 波长激光作为抽运光, 获得调谐精度约1 nm, 调谐范围约17 nm的一维波长可调谐激光器. 楔形盒中, 液晶扭曲力与取向膜表面锚定力相互平衡的过程中胆甾相液晶螺距伸张, 光子禁带位置移动, 从而调谐光子禁带边沿出射激光波长. 关键词： 胆甾相液晶 楔形盒 激光辐射     

色散补偿光子晶体光纤结构参数对其色散的影响

光子晶体光纤由于其灵活可调的色散特性用作色散补偿具有极大的应用潜力. 设计了一种色散补偿光子晶体光纤, 并运用频域有限差分法模拟了其色散特性,从理论上分析了其结构参数孔间距Λ和空气占空比d/Λ对该光子晶体光纤的色散系数的影响, 并且实际制备出了3种不同结构参数的光子晶体光纤. 通过对其色散曲线对比分析表明: 当光子晶体光纤孔间距在1 μm附近时, 其色散系数随着孔间距Λ和占空比d/Λ的增大而增加, 但对于孔间距Λ的变化比占空比d/Λ更为敏感, 并且随着孔间距Λ的增加,其对色散系数的影响能力逐渐减小. 设计并制备的光子晶体光纤在1550 nm处的色散系数为-241.5 ps·nm^-1·km^-1, 相对色散斜率为0.0018, 具有较好的色散补偿能力. 关键词： 色散 色散补偿 光子晶体光纤 结构参数     

Semi-Synthesis and In Vitro Anti-Cancer Evaluation of Magnolol Derivatives

Magnolol (MAG), a biphenolic neolignan, has various biological activities including antitumor effects. In this study, 15 MAG derivatives were semi-synthesized and evaluated for their in vitro anticancer activities. From these derivatives, compound 6a exhibited the best cytotoxic activity against four human cancer cell lines, with IC₅₀ values ranging from 20.43 to 28.27 μM. Wound-healing and transwell assays showed that compound 6a significantly inhibited the migration and invasion of MDA-MB-231 cells. In addition, Western blotting experiments, performed using various concentrations of 6a, demonstrated that it downregulates the expression of HIF-1α, MMP-2, and MMP-9 in a concentration-dependent manner. Overall, these results suggest that substituting a benzyl group having F atoms substituted at the C2 position on MAG is a viable strategy for the structural optimization of MAG derivatives as anticancer agents.     

Random pseudofractal scale-free networks with small-world effect

A random pseudofractal network (RPN) is generated by a recursive growing rule. The RPN is of the scale-free feature and small-world effect. We obtain the theoretical results of power-law exponent γ=3, clustering coefficient C=3π²-19≈ 0.74, and a proof that the mean distance increases no faster than ln N, where N is the network size. These results agree with the numerical simulation very well. In particular, we explain the property of growth and preferential attachment in RPNs. And the properties of a class of general RPNs are discussed in the end.     

智能交通系统的元胞自动机交通流模型

在Nagel-Schreckenberg(NS)模型的基础上，提出一种可应用智能交通系统（ITS）信息的新的交通流元胞自动机模型. 其中考虑了有效间距及刹车灯的作用，并引入了可变安全间距的新概念. 数值模拟表明：对于这种改进的ITS元胞自动机模型，道路交通量有了显著提高，体现了智能交通的优越性——有效地扩大交通流量，减少阻塞生成. 当考虑快车和慢车的混合交通流时，发现即使少量的慢车也会导致交通流量大幅度下降，说明了严格实施快慢道行驶的必要性. 关键词： 交通流 智能交通系统（ITS） 元胞自动机模型 刹车灯 可变安全间距     

Two new epimeric pairs of iridoid from mangrove plant Scyphiphora hydrophyllacea

Two new epimeric pairs of iridoid scyphiphin A_1(1a),A_2(1b) and scyphiphin B_1(2a),B_2(2b) were isolated from Scyphiphora hydrophyllacea Gaertn.F.Their structures were elucidated by spectroscopic methods.The mixture of scyphiphin B_1 and scyphiphin B_2 showed moderate cytotoxicity against human hepatoma SMMC-7721 cell line in vitro by MTT method.     

GaAs原子层外延技术的现状及发展

综述了原子层外延(ALE)技术的现状及其发展趋势。研究了晶体生长的程序设计和实验装置、生长的动力学模型及反应机制。对ALE薄膜的组成和结构进行了Raman和质谱分析。采用SPA原位诊断技术控制ALE的晶体生长,可有效地实现选择外延和图形化的晶体生长。大量实验表明:ALE技术可以实现原子级尺寸的超薄层晶体外延生长。用此技术已成功地研制出GaAs/GaAlAs量子阱器件。     

McKean-Vlasov limit for interacting random processes in random media

We apply large-deviation theory to particle systems with a random mean-field interaction in the McKean-Vlasov limit. In particular, we describe large deviations and normal fluctuations around the McKean-Vlasov equation. Due to the randomness in the interaction, the McKean-Vlasov equation is a collection of coupled PDEs indexed by the state space of the single components in the medium. As a result, the study of its solution and of the finite-size fluctuation around this solution requires some new ingredient as compared to existing techniques for nonrandom interaction.     

氮杂多环芳烃~（13）C－NMR化学位移的理论探讨

本文主要是对氮原子以ｓｐ~２杂化，孤氮电子占据ｓｐ~２杂化轨道，以这种形式成键的氮杂交变多环芳烃中的１１个化合物的~（１３）Ｃ－ＮＭＲ的化学位移进行了计算。该计算依据ＣＮＤＯ方法一个联系分子电荷密度，键级和键长等参数的半经验公式。同时利用环电流、空间效应以及针对氮原子的屏蔽效应和去屏蔽效应的影响，通过分子动力学的考虑，得到理论上计算的化学位移，该计算结果与实验值吻合得很好，通过时~（１３）Ｃ－ＮＭＲ化学位移的回归分析表明，回归系数达到０．９９，非常好地反映了氮杂多环芳烃~（１３）Ｃ－ＮＭＲ化学位移与分子微观结构之间的关系，同时表明我们在处理诸多化学位移时考虑到的因素是合理可行的。     

Navier－Stokes方程的变网格非协调有限元法

本文通过所谓的速度－压力型公式讨论了Ｎａｖｉｅｒ－Ｓｔｏｋｅｓ方程的变网格非协调有限元逼近，得到了在确定模意义下的速度、压力误差估计，且在一定条件下，某些误差估计能达到最优。