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981.
Dempere-Marco L Hu XP Ellis SM Hansell DM Yang GZ 《IEEE transactions on medical imaging》2006,25(8):1011-1021
Eye movements provide important insight into the cognitive processes underlying the visual search tasks. For image understanding, although the visual search patterns of different observers while studying the same scene bear some common characteristics, the idiosyncrasy associated with individual observers provides both research opportunities and challenges. The aim of this paper is to study the spatial characteristics of visual search, together with the intrinsic visual features of the fixation points for comparing different visual search strategies. An analysis framework based on earth mover's distance (EMD) in normalized anatomical space is proposed, and the results are demonstrated with high resolution computed tomography (HRCT) images of the lungs. The study shows that through the effective use of both spatial and feature space representation, it is possible to untangle what appear to be uncorrelated fixation distribution patterns to reveal common visual search behaviors. 相似文献
982.
Friesen DM Bowles OJ McDonald R Rosenberg L 《Dalton transactions (Cambridge, England : 2003)》2006,(22):2671-2682
The synthesis and structural characterization of a series of tripodal tris(phosphine) ligands, containing SiMe2 elbow groups, is described. The significant steric congestion in these ligands, due to the silylmethyl substituents, is manifest both in the solid-state structures and in the solution NMR spectra of the free ligands. Variable temperature 1H{31P} NMR studies of one of the ligands, CH3C(SiMe2PEt2)3 (4b) gave an estimated barrier to rotation around the Si-Capical bonds of approximately 10.4 kcal mol(-1). Octahedral kappa2- and kappa3-molybdenum complexes of these ligands also demonstrate the impact of the additional bulk imparted by the SiMe2 substituents, and the high Lewis basicity of these phosphines, with subtle changes at the apical and phosphine substituents changing the overall coordination chemistry observed. 相似文献
983.
Tonei DM Ware DC Brothers PJ Plieger PG Clark GR 《Dalton transactions (Cambridge, England : 2003)》2006,(1):152-158
Zinc metal reduction of the cobalt(III) complex [Co(1,4-bcc)](+) (1,4-bcc = 1,4-bis-carboxymethylcyclam) produces the corresponding cobalt(II) complex which crystallises as the coordination polymer {[Co(1,4-bcc)]ZnCl(2)}(n). A method has been developed for removal of the cobalt(III) ion from [Co(1,4-bcc)](+) and isolation of the free ligand as its hydrochloride salt, H(2)(1,4-bcc).4HCl. This has been used for the preparation of new metal complexes, and the syntheses and characterisation of the copper(ii), nickel(ii), zinc(ii) and chromium(iii) complexes containing the 1,4-bcc ligand are described. X-Ray crystal structures of {[Co(1,4-bcc)]ZnCl(2)}(n).2.5H(2)O, {[Cu(1,4-bcc)]CuCl(2)}(n).0.25MeOH.H(2)O and [Cu(1,4-bcc)H]ClO(4) show the complexes to have the trans(O) geometry of the 1,4-bcc ligand, while the structure of [Cr(1,4-bcc)H(0.5)](ClO(4))(1.5).EtOH exhibits the cis(O) configuration. 相似文献
984.
Baker RJ Jones C Mills DP Murphy DM Hey-Hawkins E Wolf R 《Dalton transactions (Cambridge, England : 2003)》2006,(1):64-72
The reactivity of a series of Ga(I), Ga(II) and Ga(III) heterocyclic compounds towards a number of Group 15 substrates has been investigated with a view to prepare examples of gallium-terminal pnictinidene complexes. Although no examples of such complexes were isolated, a number of novel complexes have been prepared. The reactions of the gallium(I) N-heterocyclic carbene analogue, [K(tmeda)][:Ga{[N(Ar)C(H)](2)}] (Ar = 2,6-diisopropylphenyl) with cyclo-(PPh)(5) and PhN[double bond, length as m-dash]NPh led to the unusual anionic spirocyclic complexes, [{kappa(2)P,P'-(PhP)(4)}Ga{[N(Ar)C(H)](2)}](-) and [{kappa(2)N,C-PhNN(H)(C(6)H(4))}Ga{[N(Ar)C(H)](2)}](-), via formal reductions of the Group 15 substrate. The reaction of the digallane(4), [Ga{[N(Ar)C(H)](2)}](2), with (Me(3)Si)N(3) afforded the paramagnetic, dimeric imido-gallane complex, [{[N(Ar)C(H) ](2)}Ga{mu-N(SiMe(3))}](2), via a Ga-Ga bond insertion process. In addition, the new gallium(III) phosphide, [GaI{P(H)Mes*}{[N(Ar)C(H)](2) }], Mes* = C(6)H(2)Bu(t)(3)-2,4,6; was prepared and treated with diazabicycloundecane (DBU) to give [Ga(DBU){P(H)Mes*}{[N(Ar)C(H)](2)}], presumably via a gallium-terminal phosphinidene intermediate, [Ga{[double bond, length as m-dash]PMes*}{[N(Ar)C(H)](2) }]. The possible mechanisms of all reactions are discussed, all new complexes have been crystallographically characterised and all paramagnetic complexes have been studied by ENDOR and/or EPR spectroscopy. 相似文献
985.
Sharma U Srivastava S Prakesch M Sharma M Leek DM Arya P 《Journal of combinatorial chemistry》2006,8(5):735-761
The solution- and solid-phase synthesis to obtain several natural-product-like, tetrahydroquinoline-based, polycyclic derivatives were developed. In one approach, two derivatives (38 and 41) having an eight-membered unsaturated lactam were successfully obtained both in solution and on solid support. 相似文献
986.
The wetting property and evaporation behavior of ethanol-water mixtures of various concentrations on gold surfaces modified with 1-decanethiolate self-assembled monolayers (SAMs) were studied by digital contact angle analysis. It has been shown that the initial contact angle decreases monotonically with increased concentration of ethanol in the mixture. Evaporation studies revealed a general trend with a preliminary increase in contact angle accompanied with a decrease in contact area, then a constant contact angle accompanied with a slower, linear decrease in contact area. At the very beginning of the evaporation process, the contact angles showed a rapid decrease for the microdroplets of a binary mixture with equal volume fractions (i.e., 50% ethanol). Three distinct stages of the evaporation profile for the ethanol-water mixtures were observed, which differ from the inclusive "pinning" and "shrinking" behavior observed for the pure liquid case. Ultimately, the study makes possible the use of an evaporation profile to monitor the change in concentration of a binary system and allows a better understanding of the interactions between liquid microdroplets with solid substrates. 相似文献
987.
Matsuzaki S Hayes JM Benbrook DM Jankowiak R 《The journal of physical chemistry. B》2006,110(32):16124-16130
Results are presented of nonphotochemical hole-burning (HB) experiments on cancerous ovarian and analogous normal peritoneal in vitro tissues stained with the mitochondrial-selective dye rhodamine 800. A comparison of fluorescence excitation spectra, hole-growth kinetics data, and external electric field (Stark) effects on the shape of spectral holes burned in cancerous and normal tissues stained with rhodamine 800 revealed significant differences only in the dipole moment change (fDeltamu) measured by a combination of HB and Stark spectroscopies. It is shown that the permanent dipole moment change for the S0--> S1 transition of the rhodamine 800 molecules in cancerous tissue is higher than that of normal tissue by a factor of about 1.4. The finding is similar to the HB results obtained earlier for human ovarian surface epithelial cell lines, i.e., OV167 carcinoma and OSE(tsT)-14 normal cells stained with the same mitochondria-specific dye (Walsh et al. Biophys. J. 2003, 84, 1299). We propose that the observed difference in the permanent dipole moment change in cancerous ovarian tissue is related to a modification in mitochondrial membrane potential. 相似文献
988.
Rampulla DM Francis AJ Knight KS Gellman AJ 《The journal of physical chemistry. B》2006,110(21):10411-10420
The enantioselective surface chemistry of chiral R-2-bromobutane was studied on the naturally chiral Cu(643)R&S and Cu(531)R&S surfaces by comparing relative product yields during temperature-programmed reaction spectroscopy. Molecularly adsorbed R-2-bromobutane can desorb molecularly or debrominate to form R-2-butyl groups on the surfaces. The R-2-butyl groups react further by beta-hydride elimination to form 1- or 2-butene or by hydrogenation to form butane. Temperature-programmed reaction spectroscopy was used to quantify the relative yields of the various reaction products. At low coverages of R-2-bromobutane on Cu(643)R&S and Cu(531)R&S, the surface chemistry is not enantioselective. At monolayer coverage, however, the product yields indicate that the R-2-bromobutane decomposition reaction rates are sensitive to the handedness of the two chiral surfaces. The impact of surface structure on enantioselectivity was examined by studying the chemistry of R-2-bromobutane on both Cu(643)R&S and Cu(531)R&S. The selectivity of R-2-bromobutane desorption versus debromination is enantiospecific and differs significantly from Cu(643) to Cu(531). The selectivity of the R-2-butyl reaction by beta-hydride elimination versus hydrogenation is only weakly enantiospecific and is similar on both the Cu(643) and Cu(531) surfaces. These results represent the first quantitative observations of enantioselectivity in reactions with well-known mechanisms probed using a simple adsorbate on naturally chiral metal surfaces. 相似文献
989.
项目简介:项目所属科学技术领域、主要内容、特点及应用推广情况:所报项目属通信网络技术中城域网多业务传送领域,分别得到2个国家“863”项目、2个国家重大标准专项和国家发展改革委员会重点产业化项目的支持,2004年获信息产业重大技术发明奖。2003年以前的LAPS和GFP协议版本都不支持流控功能和以太网映射到SDH/SONET支路(E1/T1/E3/DS3/E4等面向比特)的传送。修订后的X.85既可做到面向字节还可兼顾面向比特,做到前后版本兼容,以及与PPP/HDLC的兼容性。2001年和2002年2月代表中国向国际电联提出“面向比特的LAPS方法”和“使… 相似文献
990.
Carlucci L Ciani G Proserpio DM 《Angewandte Chemie (International ed. in English)》1999,38(23):3488-3492
A twofold interpenetrated neutral three-dimensional network with rectangular channels (left) and a noninterpenetrated three-dimensional cationic framework (right) are the stuctural motifs observed in the simple salt Ag(tta) and in the double salt 2 Ag(tta) small middle dotAgNO(3), respectively. These compounds exhibit the first examples of the μ(4)-eta(1):eta(1):eta(1):eta(1) bonding mode for tetrazolate (tta). 相似文献