WZNW模型的手征Hamilton约化

对WZNW模型作传统的Hamilton约化时,总是将Kac-Moody流的某些分量约束为非零常数。本文将这种归为常数的约束推广到了任意手征函数的惰形,证明在经典及量子水平上,这种手征约束都将导致共形的可积模型。深入的讨论表明,手征约束的引入相应于将Hamilton 约化转移到WZNW模型与自由场的直积相空间进行。     

非线性扩散方程Cauchy问题解的唯一性和稳定性

研究方程au/at=△A(u)+Σ^N_i=1 abⁱ(u) / ax^#em/em#+c(u)Cauchy问题解的唯一性。证明了如果u∈BV_x且A(u)严格递增,则解是唯一的。     

Solvent-dependence of KI Mediated Electrosynthesis of Imidazo[1,2-a]pyridines

Iodized salts are widely used as mediators to promote C—H functionalization. Solvents and additives have been described as significant roles in these reactions. However, the further electrochemical investigations have rarely been reported. Herein, a KI mediated electrochemical annulation between acetophenones and 2-amniopyridines was developed. We revealed the effect of acids and solvents by cyclic voltammetry(CV), differential pulse voltammetry(DPV), and square wave voltammetry(SWV). The oxidation of 2-aminopyridine is inhibited at the potential window with the addition of strong acids, and the lowest oxidation potential difference of KI was obtained by utilizing EtOH as solvent. The experimental studies also show that the mixture solvent of EtOH/DMSO(9/1, volume ratio) facilitates the electrochemical cyclization due to the solubility improvement of KI. CF₃SO₃H has been screened as the optimal acid. A range of Imidazo[1,2-a]- pyridines have been synthesized in yields of 42% to 96%. Electrochemical investigations present that the KI mediated electro- chemical reaction is probably solvent-dependence.     

Water and fluorinated alcohol mediated/promoted tandem insertion/aerobic oxidation/bisindolylation under metal-free conditions: Easy access to bis(indolyl)methanes

A green tandem reaction, including insertion/aerobic oxidation/bisindolylation, starting from indoles and diazo compounds has been developed. The combination of water and fluorinated alcohol plays dual roles as solvent and promoter in this chemical transformation. Molecular oxygen in the air acts as an oxidant. 3,3′-Bis(indolyl)methanes with quaternary carbon were produced under metal-free conditions. No any catalyst and additive were required. N₂ and water were released as sole by-products. Absence of water and fluorinated alcohol resulted in Wolff rearrangement product.     

角度调谐光参量振荡器的理论

推导、计算了晶体角度调谐光参量振荡器的信号光波长与调谐速率之间的关系曲线,并对信号光单谐振和空闲光单谐振两种情况进行了分析和比较,所得结果对获得高效、宽调谐光参量振荡器实验研究具有一定的指导意义。     

Mo2C@C纳米棒的制备及氧还原性能研究

碳化钼(Mo2 C)已在许多催化反应中被证明具有类Pt金属的特性,在取代贵金属基电催化剂方面具有很好的应用前景.但是,由于催化剂稳定性差,催化性能不能达到工业标准.在此,MoO3-EDA前躯体作模板,丹宁酸(TA)作为碳源,原位合成路线以获得作为氧还原反应催化剂的Mo2 C@C纳米棒.有趣的是,SEM和TEM结果显示在Mo2 C上覆盖着无定形碳和形成了Mo2 C@C纳米棒.另外,与MO2 C相比,Mo2 C@C纳米棒表现出较高的的氧还原催化活性和的稳定性.     

CoP纳米片制备及其电催化产氢性能的研究

高稳定性的催化剂对于规模化电催化产氢起着关键的作用.因此,采用简单的方法合成CoP纳米片,其表现出优越电催化活性和稳定性. CoP纳米片采用水热法和在氩气中磷化法制备的,纳米片的厚度为100～300 nm.CoP纳米片在0.5 M H2SO4的电解质中,表现出良好的电化学产氢性能,起始过电为～75 mV,塔菲尔斜率为～39. 67 mV/decade,当电流密度为10 mA· cm-2,过电压为～125 mV,经过1000次的循环后,保持良好的稳定性能.     

多标准数字广播网络终端切换技术研究

首先介绍了移动终端在不同数字广播网络间(以DVB-H和DTMB为例)移动时得到无缝切换服务的需求与场景.随后介绍了欧洲的数字广播标准DVB-H,DVB-T和中国的数字广播标准DTMB,切换的判决条件以及节日的同步过程,终端进行切换的状态转换机制,以及实现切换功能的移动终端的模块结构设计.最后给出了实验结果.     

基于TMS320F28335的SVPWM信号发生器

电压空间矢量脉宽调制能提高直流侧电压利用率,其应用范围已跨越变频调速系统,进入各个领域。文中在分析SVPWM原理的基础上,结合三相H桥逆变电路的特点,介绍了TMS320F28335的SVPWM信号发生器设计,并实现了逆变桥一相断路情况下的SVPWM波。通过硬软件结合,在DSP实验平台上进行了调试和实验观察,给出实验结果波形。实验证明,基于DSP的SVPWM信号发生器具有实现简单方便、易于数字化的特点,能更好地满足功率器件对驱动信号的不同要求,便于实现容错控制。     

光参量振荡器泵浦源的理论研究与优化设计

研究了作为光参量振荡器的泵浦源1064nm声光Q Nd:YAG激光器.从Nd:YAG激光特性出发,介绍了LD端面抽运Nd:YAG调Q固体激光器的特性,对谐振腔结构进行了等效、分析和数值计算,给出了稳腔条件和腔中振荡光斑随腔长的变化曲线.对调Q脉冲形成过程的速率方程进行了数值计算,得到脉冲形状,分析了泵浦光脉冲形状和脉宽对参量振荡信号光的影响.所得结果对产生高质量、宽调谐、高转换效率的光参量振荡器具有一定的指导意义.