Luminescent Efficiency in Single-layer Organic Electrophosphorescent Devices

Based on the charge injection and recombination processes and the triplet-triplet annihilation process, a model to calculate the electro.luminescent（EL） efficiency is presented. The influences of the applied electric field on the injection efficiency, recombination efficiency and electroluminescent efficiency are discussed. It is found that： （1） The injection efficiency is increasing while the recombination efficiency is decreasing with the applied electric field increasing. （2） The EL efficiency is enhanced at low electric field slowly but is decreasing at high electric field with the increase of applied voltage. （3） The EL efficiency is decreasing with the increase of the host-guest molecular distance （R）. So, it is concluded that the EL efficiency in single-layer organic electrophosphorescent devices is dominated by injection efficiency at lower electric field and recombination efficiency at higher electric field.     

卡尔曼滤波紫外光度法同时测定酱油、食醋中的山梨酸和苯甲酸

在酸性条件下，采用乙酸乙酯萃取、Na2HPO4溶液反萃取分离酱汪、食醋中的山梨酸、苯甲酸，卡尔曼滤波法计算结果，并与比值导数波谱法进行比较。结果表明，卡尔曼滤波法较地数波谱法有较高准确度和精密度，并能监测干扰物质存在与否。用于实际样品分析有更高的可靠性。     

基于三次谐波PbTiO_3陶瓷t_c的研究

通过对A[Pb(1-3x/2-y)LaxCayTiO3]+B TiO2系统陶瓷的研究,采用La、Ca适量取代Pb和调整适量游离态的TiO2,并通过Bi、Ce、Cr掺杂的办法,得到一种具有较高tC能满足片式元件温度需求的工业用三次谐波PbTiO3陶瓷,同时对改善PbTiO3陶瓷材料tC的机理进行了初步的探讨。     

广义非简谐振子的多尺度微扰理论

应用多尺度微扰理论到广义非简谐振子, 得到了一阶经典和量子微扰解. 特别是 我们的量子解在极限条件下能方便地转变为经典解, 并且坐标和动量算符的对易 关系的简化十分自然. 与Taylor级数解相比较, 无论是在经典还是在量子解 中频率移动都出现在各阶振动表达式中, 所以多尺度微扰解是弱耦合非简谐振动的较好解法.     

Effect of Bias Step on the I-V Curve in Double-Barrier AlGaAs/GaAs/AlGaAs Resonant-Tunnelling Devices

We investigate the non-equilibrium electron transport properties of double-barrier AlGaAs/GaAs/AlGaAs resonant- tunnelling devices in nonlinear bias using the time-dependent simulation technique. It is found that the bias step of the external bias voltage applied on the device has an important effect on the final current-voltage （I - V） curves. The results show that different bias step applied on the device can change the bistability, hysteresis and current plateau structure of the I - V curve. The current plateau occurs only in the case of small bias step. As the bias step increases, this plateau structure disappears.     

CO2激光外差接收的实时强度成像

利用国内的元器件建立了声光调制CO_2激光外差接收系统,并进行了实验室内静止目标的实时强度成像,成像距离3m,成像视场7°× 5°,像素128×98,4个颜色梯度显示像强度.     

水准折光及双波长激光效应

本文从“同温度层不完全平行于地面,且在变化”的“任意分层”假设出发,导出了水准折光修正公式,并利用光的色散效应在10~(-6)的精度要求下,求得r=r_T=h_1/h_2=(n_(01)-1)/(n_(02)-1)=常数最后指出,研制双波长激光水准仪的必要性和可能性,并提出了研制此种仪器的技术参数.     

a-Si:H掺杂机理的研究

本文利用CNDO/2量子化学理论方法,对P和B原子在四面体配位的Si₄₆和Sl₄₆H₆₀H₄^*原子集团中置换Si原子前后的原子集团能量和能态分布变化进行了计算.计算结果表明:1)在Si₄₆H₆₀H₄^*原子集团中用P(或B)置换引Si原子后在能隙中明显地出现施主(或受主)态子带,同样在Si_{46相似文献}   

合成α,β-不饱和炔酰胺的新途径

α,β-不饱和炔酰胺是有用的合成中间体,它们通常是由其相应的羧酸衍生物与胺反应制得。我们在应用Weyerstahl的方法从乙酰乙酸乙酯(1)制备丁炔一2一酸(5)时,发现以胺作为亲核试剂代替     

机械球磨与反应烧结合成Sr2CeO4发光体的研究

Sr₂CeO₄ phosphor was synthesized by mechanical milling and reactive sintering in this work. The solid state reaction of SrCO₃and CeO₂ (2∶1) started at about 850 ℃ and completed at 1 000 ℃ for about 4 h. Two types of formation mechanism of Sr₂CeO₄ were proposed. When the starting powder mixture was fired above 1 000 ℃, the unstable intermediate phase SrCeO₃was developed, which then reacted with SrCO₃to form the final product Sr₂CeO₄, however, SrCO₃and CeO₂ converted directly to Sr₂CeO₄ at a lower temperature. The XRD results showed the crystal structure of Sr₂CeO₄ was orthorhombic. The emission spectra displayed a broad band with maximum at about 465 nm. The mechanical milling of starting power mixture and the sintering temperature had no effect on this emission spectra.