Theory of two-frequency excitation in<Superscript>14</Superscript>N NQR

A simple and effective technique for calculating the transient signals in three-level spin systems irradiated at one and two frequencies is described. All possible signals are presented and discussed. The application of the two-frequency excitation technique for the investigation of the inhomogeneity of the crystalline lattice is suggested.     

Ghost-matter mixing and feigenbaum universality in string theory

Branelike vertex operators, defining backgrounds with ghost-matter mixing in Neveu-Schwarz-Ramond superstring theory, play an important role in a world-sheet formulation of D branes and M theory, being creation operators for extended objects in the second quantized formalism. We show that the dilaton beta function in ghost-matter mixing backgrounds becomes stochastic. The renormalization group (RG) equations in ghost-matter mixing backgrounds lead to non-Markovian Fokker-Planck equations whose solutions describe superstrings in curved spacetimes with branelike metrics. We show that the Feigenbaum universality constant δ=4.669 ..., describing transitions from order to chaos in a huge variety of dynamical systems, appears analytically in these RG equations. We find that the appearance of this constant is related to the scaling of relative spacetime curvatures at fixed points of the RG flow. In this picture, the fixed points correspond to the period doubling of Feigenbaum iterational schemes.

     

High-Q whispering gallery modes in a spherical shell dielectric resonator: Characterization at microwave frequencies

We present a numerical and experimental characterization of high-Q whispering gallery resonant modes excited in a fused quartz spherical shell operated in the 18-26.5 GHz band; easy coupling and selection of modes is a most advantageous feature of the proposed structure with respect to ordinary bulk resonators. The numerical results, based on a finite element algorithm, well match experimental data, which also show the capability of our device to perform gaseous spectroscopy measurements. Received 25 October 2002 Published online 4 February 2003     

Synthesis and Photochemistry of Novel 3,5-Diacetyl-1,4-dihydropyridines. II [1]

In continuation of previous work some novel 3,5-diacetyl-1,4-dihydropyridine derivatives were synthesized and their photochemical behavior was studied under oxygen and argon atmosphere. Oxidation of the dihydropyridine ring and formation of pyridine derivatives was the result of the reaction. The presence of oxygen affects not only on the rate of oxidation, but also the formation of some unidentified by-products was observed on irradiation under this atmosphere.     

Total synthesis of (±) maculalactone A, maculalactone B and maculalactone C and the determination of the absolute configuration of natural (+) maculalactone A by asymmetric synthesis

Maculalactones A, B and C from the marine cyanobacterium Kyrtuthrix maculans are amongst the only compounds based on the tribenzylbutyrolactone skeleton known in nature and (+) maculalactone A from the natural source possesses significant biological activity against various marine herbivores and marine settlers. We now report a concise synthesis of racemic maculalactone A in five steps from inexpensive starting materials. Maculalactones B and C were synthesized by a minor modification to this procedure, and the synthetic design also permitted an asymmetric synthesis of maculalactone A to be achieved in around 85% ee. The (+) and (−) enantiomers of maculalactone A were assigned, respectively, to the S and R configurations on the basis of the chiral selectivity expected for catecholborane reduction of an unsymmetrical ketone in the presence of Corey's oxazoborolidine catalyst. Surprisingly, it appeared that natural (+) maculalactone A was biosynthesized in K. maculans in a partially racemic form, comprising ca. 90-95% of the (S) enantiomer and 5-10% of its (R) enantiomer. Coincidentally therefore, the percentage enantiomeric excess of the product obtained from asymmetric synthesis almost exactly matched that found in nature.     

Regional elemental signatures related to combustion of lignites

In ambient air, arsenic to selenium ratio (As/Se) is generally found to be less than 1, except in areas influenced by specific point sources, such as Cu smelters. However, the annual average of this ratio is found to be much higher than unity in Turkey. This finding is rather unique and may provide a marker for air masses influenced by the coal-related emissions in Turkey. This revised version was published online in August 2006 with corrections to the Cover Date.     

Phase formation and control of morphology in sputtered Cu-In alloy layers

The dependence of structural properties and surface morphology of Cu-In alloy layers on the composition and sputtering deposition sequence were investigated by X-ray diffraction, scanning electron microscopy and energy-dispersive X-ray spectroscopy. The properties of the co-sputtered alloy layers changed abruptly around the composition boundary when the Cu/In ratio reached 1/2. This can be explained by the effective heat of formation (EHF) model, which has been used to predict the sequence of phase formation for metal diffusion couples. The use of a co-sputtered alloy layer with a high In concentration was not suitable for fabricating solar cells, because the film had a very rough morphology due to large In islands formed on the CuIn₂ phase. However, it was possible to minimize this phase by In sputtering followed by co-sputtering with a Cu/In ratio of 1 (Cu-In/In/Glass). This permitted the fabrication of a homogeneous Cu-In alloy layer, which was not possible through the simple co-sputtering.     

On quasi-solution to infeasible linear complementarity problem obtained by Lemke’s method

For a linear complementarity problem with inconsistent system of constraints a notion of quasi-solution of Tschebyshev type is introduced. It’s shown that this solution can be obtained automatically by Lemke’s method if the constraint matrix of the original problem is copositive plus or belongs to the intersection of matrix classes P ₀ and Q ₀.     

Frequencies of Free Oscillations of a Truncated Spherical Sector Covered with a Thin Elastic Spherical Shell

An analytic solution of the problem concerning the frequencies and shapes of free axially symmetric oscillations of a truncated spherical sector filled with an ideal compressible fluid is constructed. A spherical wall of smaller radius and the radial wall of the sector are absolutely rigid. A thin elastic shell whose edge is clamped in the radial wall is located on a spherical boundary of larger radius. The outer surface of the shell borders vacuum. The phenomenon of an anomalous decrease in the fundamental frequency as the spherical walls approach each other is discovered. An approximate formula for determination of the lowest fundamental frequencies, which are approximately proportional to the square root of the difference of the radii of spherical walls for small values of this difference, is constructed and tested numerically. Bibliography: 13 titles.