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101.
Libo Li Qihong Lou Jun Zhou Jingxing Dong Yunrong Wei Songtao Du Bing He 《Optics Communications》2008,281(4):655-657
To get high output power with good beam quality, a tapered section is introduced to large-mode-area (LMA) Yb-doped fiber laser. Output characteristics of the fiber laser without tapered section and with tapered section are compared experimentally. When the launched pump power is 119.1 W, 77.9 W with M2 3.08 and 56.4 W with M2 1.14 can be obtained, respectively. The corresponding slope efficiencies are 71.8% and 54.1%, respectively. Although output power of the tapered fiber laser has 30.6% penalty, brightness of it is as much as 5.28 times of the fiber laser without tapered section. Moreover, spectra of them are measured. It is found that tapered section makes lasing wavelength of the fiber laser shorter. 相似文献
102.
103.
Wan Yupeng Lyu Heng Du Hengyi Wang Dunjia Yin Guodong 《Research on Chemical Intermediates》2019,45(4):1669-1687
Research on Chemical Intermediates - Two pentafluorinated β-diketone ligands, 4,4,5,5,5-pentafluoro-1-(4-methoxyphenyl)pentane-1,3-dione (PFMP) and 4,4,5,5,5-pentafluoro-1-(4-dimethyl... 相似文献
104.
Jia-Pei Du Dr. Alexander Wilting Prof. Dr. Inke Siewert 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(21):5555-5564
Here, the reduction chemistry of mono- and binuclear α-diimine-Re(CO)3 complexes with proton responsive ligands and their application in the electrochemically-driven CO2 reduction catalysis are presented. The work was aimed to investigate the impact of 1) two metal ions in close proximity and 2) an internal proton source on catalysis. Therefore, three different Re complexes, a binuclear one with a central phenol unit, 3 , and two mononuclear, one having a central phenol unit, 1 , and one with a methoxy unit, 2 , were utilised. All complexes are active in the CO2-to-CO conversion and CO is always the major product. The catalytic rate constant kcat for all three complexes is much higher and the overpotential is lower in DMF/water mixtures than in pure DMF (DMF=N,N-dimethylformamide). Cyclic voltammetry (CV) studies in the absence of substrate revealed that this is due to an accelerated chloride ion loss after initial reduction in DMF/water mixtures in comparison to pure DMF. Chloride ion loss is necessary for subsequent CO2 binding and this step is around ten times faster in the presence of water [ 2 : kCl(DMF)≈1.7 s−1; kCl(DMF/H2O)≈20 s−1]. The binuclear complex 3 with a proton responsive phenol unit is more active than the mononuclear complexes. In the presence of water, the observed rate constant kobs for 3 is four times higher than of 2 , in the absence of water even ten times. Thus, the two metal centres are beneficial for catalysis. Lastly, the investigation showed that the phenol unit has no impact on the rate of the catalysis, it even slows down the CO2-to-CO conversion. This is due to an unproductive, competitive side reaction: After initial reduction, 1 and 3 loose either Cl− or undergo a reductive OH deprotonation forming a phenolate unit. The phenolate could bind to the metal centre blocking the sixth coordination site for CO2 activation. In DMF, O−H bond breaking and Cl− ion loss have similar rate constants [ 1 : kCl(DMF)≈2 s−1, kOH≈1.5 s−1], in water/DMF Cl− loss is much faster. Thus, the effect on the catalytic rate is more pronounced in DMF. However, the acidic protons lower the overpotential of the catalysis by about 150 mV. 相似文献
105.
Ben-Xian Xiao Xin-Yue Gao Dr. Wei Du Prof. Dr. Ying-Chun Chen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(7):1607-1613
Numerous protocols have been developed for the functionalization of aromatic substances. Among them, the strategy by which aromatic substrates are activated in situ to generate dearomatized intermediates is highly efficient but challenging, especially in the field of asymmetric catalysis. In this Concept article, the application of some well-established chiral Lewis base catalysis, including primary/secondary amines and N-heterocyclic carbenes, that can covalently form catalyst-tethered dearomatized ortho/para-quinodimethane species with diverse heteroaryl and aryl carbonyl substrates is summarized in a number of asymmetric cycloaddition and addition reactions with diverse reagents generally having electrophilic properties. As a result, a variety of enantioenriched aromatic products with higher molecular complexity are constructed effectively through a rearomatization process. 相似文献
106.
YongGuang Tu GuoNing Xu XiaoYu Yang YiFei Zhang ZhaoJie Li Rui Su DeYing Luo WenQiang Yang Ying Miao Rong Cai LuHua Jiang XiaoWei Du YanChu Yang QianShi Liu Yang Gao Shuai Zhao Wei Huang QiHuang Gong Rui Zhu 《中国科学:物理学 力学 天文学(英文版)》2019,(7)
<正>The metal halide perovskite materials demonstrate outstanding performance in photovoltaics because of their excellent optoelectronic properties [1-7]. The perovskite solar cells (PSCs) exhibiting outstanding efficiency [8,9], high power-per-weight [10], and excellent radiation resistance[11-13] are considered to be promising for developing the new-generation energy technology for space application.However, the extreme space environment would impose 相似文献
107.
A series of NiMnTi mixed metal oxides (Ni/Mn-TiO2, Mn/NiTi-LDO and TiO2/NiMn-LDO, NiMnTi-LDO) were synthesized via different assembling methods and evaluated in the selective catalytic reduction of NOx with NH3(NH3-SCR). As the results presented, catalysts via diverse assembling methods of LDHs templates afforded different catalytic denitrification (DeNOx) performance, which might be related to the exposure degree of active constituents and the interaction intensity between metal components. Noticeably, compared with Ni/Mn-TiO2, Mn/NiTi-LDO and TiO2/NiMn-LDO catalysts, the NiMnTi-LDO catalyst deriving from one step in-situ method NiMnTi-LDH precursor template exhibited the most desirable performance at temperature window of 150–360 °C in NH3-SCR (above 90% NOx conversion with 95% N2 selectivity). The specific structure and property of samples were correlated by means of a series of characterizations, where the results indicated that NiMnTi-LDO possessed the highest surface area, the strongest redox ability, the most abundant acid amount and the best dispersion. 相似文献
108.
Yang Yang Ying Jiang Prof. Dr. Wei Du Prof. Dr. Ying-Chun Chen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(8):1754-1758
Isobenzofulvene species are versatile synthons in organic chemistry, which have been employed in diverse challenging higher-order cycloaddition reactions. Here, the first chemoselective and asymmetric cross [10+2] cycloaddition reaction between activated 2-alkylidene-1-indanones and a variety of electron-deficient alkenes has been developed, relying on the in situ generation of dearomative 1-hydroxyl isobenzofulvene anion intermediates under the catalysis of a newly designed bulky cinchona-derived phase-transfer compound. An array of fused frameworks with multifunctionalities were generally furnished in excellent diastereo- and enantioselectivity, even at 1 mol % catalyst loadings. 相似文献
109.
Nonlinear Dynamics - In this work, we propose the cumulative residual entropy (CRE) plane and CRE curve based on the weighted-multiscale cumulative residual Rényi/Tsallis permutation entropy... 相似文献
110.
Dr. Ran Du Dr. Jan-Ole Joswig Dr. René Hübner Lin Zhou Dr. Wei Wei Prof. Yue Hu Prof. Dr. Alexander Eychmüller 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(21):8370-8377
Noble-metal aerogels (NMAs) have drawn increasing attention because of their self-supported conductive networks, high surface areas, and numerous optically/catalytically active sites, enabling their impressive performance in diverse fields. However, the fabrication methods suffer from tedious procedures, long preparation times, unavoidable impurities, and uncontrolled multiscale structures, discouraging their developments. By utilizing the self-healing properties of noble-metal aggregates, the freezing-promoted salting-out behavior, and the ice-templating effect, a freeze–thaw method is crafted that is capable of preparing various hierarchically structured noble-metal gels within one day without extra additives. In light of their cleanliness, the multi-scale structures, and combined catalytic/optical properties, the electrocatalytic and photoelectrocatalytic performance of NMAs are demonstrated, which surpasses that of commercial noble-metal catalysts. 相似文献