Giant Emission Enhancement of Solid-State Gold Nanoclusters by Surface Engineering

Ligand-induced surface restructuring with heteroatomic doping is used to precisely modify the surface of a prototypical [Au₂₅(SR¹)₁₈]⁻ cluster ( 1 ) while maintaining its icosahedral Au₁₃ core for the synthesis of a new bimetallic [Au₁₉Cd₃(SR²)₁₈]⁻ cluster ( 2 ). Single-crystal X-ray diffraction studies reveal that six bidentate Au₂(SR¹)₃ motifs (L2) attached to the Au₁₃ core of 1 were replaced by three quadridentate Au₂Cd(SR²)₆ motifs (L4) to create a bimetallic cluster 2 . Experimental and theoretical results demonstrate a stronger electronic interaction between the surface motifs (Au₂Cd(SR²)₆) and the Au₁₃ core, attributed to a more compact cluster structure and a larger energy gap of 2 compared to that of 1 . These factors dramatically enhance the photoluminescence quantum efficiency and lifetime of crystal of the cluster 2 . This work provides a new route for the design of a wide range of bimetallic/alloy metal nanoclusters with superior optoelectronic properties and functionality.     

One-pot sequential deoximation and allylation reactions of aldoximes in aqueous solution

A simple procedure has been developed for conducting tin-mediated deoximation and allylation reactions of aldoximes in water to form homoallylic alcohols. Employing the new conditions, various homoallylic alcohols were produced in good to excellent yields.     

褐菖（Sebastiscus marmoratus）早期生长发育与人工繁育技术研究

在室内水泥池育苗条件下研究了褐菖(Sebastiscus marmoratus)仔、稚、幼鱼的生长发育特性和人工育苗关键技术.结果表明：在育苗水温12~17℃,5日龄卵黄囊消失进入仔鱼后期,36日龄各鳍鳍条形成进入稚鱼期,经57~62 d鳞被完整发育为幼鱼;仔鱼期、稚鱼期和幼鱼期的平均存活率分别为17.42%、66.01%和89.21%;水温对30日龄前的仔鱼生长影响不显著,平均体长增长率为(0.12±0.01) mm·d-1,30日龄后温度效应不断增大,平均日增长率(0.75±0.05) mm·d-1,其生长拟合方程为 Lt=0.0001D3+0.001D2+0.0123D+4.3919, R2=0.98;蛋黄可以部分代替轮虫,且存活率及生长速度与轮虫组无显著差异;育苗中发现第14~15天、第28~30天、第41~50天分别为褐菖育苗的3个危险期,死亡率以第1个危险期最高,达67.20%;针对3个危险期提出了加强早期营养供应,缩短卤虫投喂时间,增设底部和各水层隐蔽物等建议.     

Robust High Temperature Sensor Probe Based on a Ni-coated Fiber Bragg Grating

A robust high temperature sensor probe based on a Ni-coated fiber Bragg grating（FBG） was fabricated by Ni electroplating of femtosecond laser written FBG. The probe can resist high temperature up to 800℃ with a high sensitivity of 32.2 pm/℃. It also has a good mechanical strength even after high temperature annealing. The thermal strain of the probe was simulated by the finite element method（FEM）. The Bragg resonant wavelength shift with temperature and its sensitivity change with the thickness of the Ni-coated layer were also calculated.     

Numerical Study on Quantum Efficiency Enhancement of a Light-Emitting Diode Based on Surface Plasmon Coupling With a Quantum Well

We demonstrate the numerical study results of the enhancements of internal quantum efficiency (IQE) and external quantum efficiency (EQE) of a semiconductor quantum well when it is coupled with surface plasmons (SPs) induced on a grating interface between Ag and semiconductor. The IQE and EQE enhancements depend on the emission dipole position and the assigned intrinsic IQE. The SP dissipation in metal and the grazing-angle SP radiation lead to a significant difference between IQE and EQE. The enhancement of EQE is less significant when the intrinsic IQE becomes larger. In applying the SP coupling phenomenon to an InGaN-GaN quantum-well light-emitting diode, the efficiency enhancement is more significant in the green-red range, in which the intrinsic IQE is normally quite low.     

An efficient and accurate method for the relaxation of multiview registration error.

This paper presents a new method for the relaxation of multiview registration error. The multiview registration problem is represented using a graph. Each node and each edge in the graph represents a 3-D data set and a pairwise registration, respectively. Assuming that all the pairwise registration processes have converged to fine results, this paper shows that the multiview registration problem can be converted into a quadratic programming problem of Lie algebra parameters. The constraints are obtained from every cycle of the graph to eliminate the accumulation errors of global registration. A linear solution is proposed to distribute the accumulation error to proper positions in the graph, as specified by the quadratic model. Since the proposed method does not involve the original 3-D data, it has low time and space complexity. Additionally, the proposed method can be embedded into a trust-region algorithm and, thus, can correctly handle the nonlinear effects of large accumulation errors, while preserving the global convergence property to the first-order critical point. Experimental results confirm both the efficiency and the accuracy of the proposed method.     

A K- to Ka-Band Broadband Doubly Balanced Monolithic Ring Mixer

A broadband doubly balanced monolithic ring mixer with a new intermediate frequency (IF) signal extraction method implemented by 0.15 mum pHEMT process is presented. The hybrid couplers of the proposed mixer consist of multiple coupled lines and fourfold coupled line Marchand baluns. The use of multiple coupled lines leads to a die size less than 1 times 1 mm² and improves the bandwidth of the mixer. The novel fourfold coupled line allows the extraction of the IF signal directly without any extra low pass filter circuits. The mixer exhibited 8-13 dB conversion loss, high radio frequency/local oscillation isolation of 35-50 dB over 16-40 GHz and an input 1-dB compression point of 14 dBm.     

C-半群的弱渐近概周期运动

讨论了Bnanch空间上C-半群的弱渐近概周期(WAAP)运动,进而得到其表示定理和扰动定理.     

Binaural active noise control using parametric array loudspeakers

This paper reports the binaural active noise control (ANC) system developed to deal with factory noise. The control points are located in the vicinity of the left and right ears of a worker sitting along the production line. Due to the complicated safety requirements in the factory, secondary sources and error microphones are not allowed to be placed near the worker. Therefore, the proposed ANC system employs the feedforward structure and adopts the parametric array loudspeakers (PALs) as the secondary sources. The PAL is a type of directional loudspeaker that generates a much narrower sound field as compared to the conventional loudspeaker. Once the proposed ANC system has been trained offline, the error microphones can be removed. The performance of the binaural ANC system is successfully demonstrated based on a digital signal processor (DSP) implementation.     

基于发射波束域-三迭代的机载MIMO雷达STAP方法

针对传统机载多输入多输出(MIMO)雷达空时自适应处理(STAP)中由于发射功率分散而造成的输出信杂噪比(SCNR)下降的问题,该文提出一种基于发射波束域-三迭代的机载MIMO雷达STAP方法。首先建立了发射波束域MIMO雷达STAP的信号模型,并且给出了发射波束加权矩阵的优化设计准则,能够使发射功率聚集于感兴趣的目标空域。然后对发射波束域MIMO雷达的杂噪比(CNR)进行分析,表明其与发射总功率的关系,理论推导显示:相比于全向等功率发射的传统MIMO雷达CNR,发射波束域MIMO雷达CNR减小。同时,为进一步降低发射波束域MIMO-STAP的训练样本数需求与运算复杂度,采用三迭代算法进行权值降维求解。理论分析与仿真实验结果表明:通过相应的三迭代降维处理,发射波束域MIMO-STAP与传统全向等功率发射MIMO-STAP相比能够获取更加优越的输出SCNR性能,且运算量进一步降低。因此,本文提出的发射波束域-三迭代方法具有重要的工程应用价值。