首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   50688篇
  免费   6389篇
  国内免费   4764篇
化学   26439篇
晶体学   370篇
力学   2258篇
综合类   241篇
数学   4394篇
物理学   13912篇
无线电   14227篇
  2024年   179篇
  2023年   1175篇
  2022年   1389篇
  2021年   1898篇
  2020年   1821篇
  2019年   1638篇
  2018年   1414篇
  2017年   1352篇
  2016年   1925篇
  2015年   2057篇
  2014年   2518篇
  2013年   3249篇
  2012年   4040篇
  2011年   3956篇
  2010年   2838篇
  2009年   2815篇
  2008年   3050篇
  2007年   2700篇
  2006年   2623篇
  2005年   2301篇
  2004年   1783篇
  2003年   1424篇
  2002年   1277篇
  2001年   1089篇
  2000年   1064篇
  1999年   1193篇
  1998年   1052篇
  1997年   947篇
  1996年   1005篇
  1995年   875篇
  1994年   799篇
  1993年   690篇
  1992年   633篇
  1991年   505篇
  1990年   435篇
  1989年   310篇
  1988年   275篇
  1987年   244篇
  1986年   173篇
  1985年   200篇
  1984年   168篇
  1983年   143篇
  1982年   108篇
  1981年   76篇
  1980年   68篇
  1979年   48篇
  1978年   37篇
  1976年   37篇
  1975年   43篇
  1974年   30篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
A fast convergent integral equation solution to the scattering problem of a transverse electric/transverse magnetic (TE/TM) plane wave by a one-dimensional periodic array of thin metal strips on a dielectric substrate is described. The formulation of the integral equation is similar to that derived by Montgomery for a two-dimensional periodic array of thin conductors on a dielectric substrate. However, the basis functions which satisfy the appropriate edge conditions are incorporated here for the unknown current expansion on the strips. Following the standard Galerkin's procedure, one may readily determine the induced currents on the strips and thus the reflected and transmitted fields. Sample numerical results are given and good agreement with previously published data is obtained. It is found that the convergence rate of this method is improved by an order of magnitude. Also it is shown that the dielectric substrate has a strong effect on the scattering from the large spacing strip grating.  相似文献   
42.
A fluoroionophore sensor, N-[4-(1-pyrene)butyroyl]-L-tryptophan (PLT), has been reported. It can distinguish lead ion from other 12 metal ions via forming a pyrene dimer and it exhibits a very high sensitivity (0.15 microM) in aqueous solution (Chem. Commun., 2006, 2702). When the indole moiety in PLT was changed to benzene, in forming a new fluoroionophore of N-[4-(1-pyrene)butyroyl]-L-phenylalanine (PLP), it could not form a pyrene dimer in response to Pb(2+) in water. The present study describes the spectroscopic clarification of the intrinsic differences of the binding model between PLP and PLT in binding with Pb(2+). The model shows identical chelating bidentate coordination between COO(-) and Pb(2+) both in PLP-Pb and PLT-Pb; however, there is no indication of the interaction between the phenyl ring and the metal ion or the hydrogen bonding between amide groups in PLP-Pb. These differences in the binding model between PLP-Pb and PLT-Pb illustrate that the indole ring in PLT appears to play a crucial role in the high selectivity and sensitivity of PLT to lead(II) ion.  相似文献   
43.
The influence of the electron-LO-phonon coupling on energy spectrum of the low-lying states ofan exciton inparabolic quantum dots is investigated as a function of dot size. Calculations are made by using the method of few-bodyphysics within the effective-mass approximation. A considerable decrease of the energy in the stronger confinement rangeis found for the low-lying states of an exciton in quantum dots, which results from the confinement of electron-phononcoupling.  相似文献   
44.
Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are randomly dispersed and exfoliated into the PHB matrix. In this study, the effect of PMLDH on the isothermal crystallization behavior of PHB was investigated using a differential scanning calorimeter (DSC) and polarized optical microscopy. Isothermal crystallization results of PHB/PMLDH nanocomposites show that the addition of 2 wt % PMLDH into PHB induced more heterogeneous nucleation in the crystallization significantly increasing the crystallization rate and reducing their activation energy. By adding more PMLDH into the PHB probably causes more steric hindrance of the diffusion of PHB, reducing the transportation ability of polymer chains during crystallization, thus increasing the activation energy. The correlation among crystallization kinetics, melting behavior and crystalline structure of PHB/PMLDH nanocomposites can also be discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3337–3347, 2006  相似文献   
45.
An improvement has been made to couple isoelectric focusing (IEF) sample injection and capillary zone electrophoresis in an untreated fused silica capillary. Electroosmotic flow is efficiently prevented by simply using a rubber block at the outlet end of the capillary during IEF sample injection. The experimental conditions that affect the concentration effect are discussed. A concentration enhancement factor of over 100-fold can be easily obtained for two model proteins: lysozyme and ribonuclease A.  相似文献   
46.
A nonlinear method named detrended fluctuation analysis (DFA) was utilized to investigate the scaling behavior of the human electroencephalogram (EEG) in three emotional music conditions (fear, happiness, sadness) and a rest condition (eyes-closed). The results showed that the EEG exhibited scaling behavior in two regions with two scaling exponents β1 and β2 which represented the complexity of higher and lower frequency activity besides α band respectively. As the emotional intensity decreased the value of β1 increased and the value of β2 decreased. The change of β1 was weakly correlated with the 'approach-withdrawal' model of emotion and both of fear and sad music made certain differences compared with the eyes-closed rest condition. The study shows that music is a powerful elicitor of emotion and that using nonlinear method can potentially contribute to the investigation of emotion.  相似文献   
47.
We prove that every noetherian affine PI Hopf algebra has finite injective dimension, which answers a question of Brown (1998).

  相似文献   

48.
BaXO4 (X = Mo, W) nanobelts and a variety of hierarchical superstructures assembled from the nanobelts have been synthesized in a catanionic reverse‐micelle system. The effects of various factors, such as the mixing ratio (r) between the anionic and cationic surfactants, the temperature, and the presence of polymeric additives, on the formation of the nanobelts and their hierarchical assembly have been examined in detail. In particular, r has been shown to be powerful in modulating the formation and assembly of the BaMoO4 and BaWO4 nanobelts. Architectural control of the penniform nanobelt superstructures has been readily achieved by changing the experimental parameters. A plausible two‐stage growth mechanism has been proposed for the formation of penniform BaXO4 nanobelt superstructures in catanionic reverse micelles.  相似文献   
49.
We characterize functions in Morrey space by p-Carleson measures. We then reveal a simple relation between Q space and Morrey space, that is Q space can be viewed as a fractional integration of the Morrey space. Therefore, many results for Morrey space can be translated onto Q space. For example, we show that Q space is a dual space by identifying its predual.  相似文献   
50.
In this paper, we present some counterexamples which show that there is no theory on the spectrum of homogeneous compact operators which parallels the Riesz-Schauder theory on the spectrum of linear compact operators. These counterexamples also illustrate that it is impossible to study in a unified setting the Fucik spectrum of the Laplacian: -△w = au+ - bu- inΩand u = 0 on (?)Ω, as well as the spectrum of the p-Laplacian: -div(|(?)u| p-2(?)u) = λ|u|p-2u and u = 0 on (?)Ω.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号