Determination of Trace Iron(II) in the Presence of Iron(III)

The determination of trace iron(II) is usually interfered by the presence of iron(III) when ortho-phenanthroline colorimetric method is used. In this report a chromogenic reagent which contains ortho-phenanthroline-EDTA mixture has been developed to decrease the interference of ferric ion after adjusting the acidity of sample at 0.1 N by adding the sulfuric acid. The procedure is also simplified by introducing sulfamate buffer solution (pH= 1.5) without adjusting the acidity of sample with sulfuric acid. If iron(III) is not present in the sample, this method is also applicable. The comparative results are exhibited for the present method and the conventional o-phenanthroline method.     

The structure and thermodynamics of binary microclusters: A Monte Carlo simulation

The Monte Carlo computer simulation technique of classical statistical mechanics is employed to determine the structure and thermodynamics of binary microclusters of Lennard-Jones atoms as a function of cluster size, composition and temperature. Further, amorphous microclusters are prepared by a Monte Carlo quench, and their structural properties are examined. The properties of interest include the internal energy, instantaneous “snapshot” pictures of the microcluster's atomic configuration, and the single-particle and pair distribution functions. The Lennard-Jones potential parameters are chosen to model Ar₁₃, Ar₇Kr₆, Ar₃₆Kr₁₉ and Ar₁₉Kr₃₆, as well as to crudely model the bimetallic clusters of Cu₁₉Ni₃₆, Cu₁₉Ru₃₆ and Cu₁₉Os₃₆. A large variety of interesting features associated with these systems are described.     

Dipole antenna coaxially mounted on a conducting cylinder

The problem of a cylindrical dipole antenna symmetrically mounted on a conducting coaxial cylinder is analyzed both theoretically and experimentally. The theoretical approach is based on the Fourier transform solution for thin wire antennas, equivalence and image principles, point matching, and numerical optimization. The basic idea is that the modified dipole structure can be replaced by an equivalent system (as far as exterior fields are concerned) consisting of a simple perfectly conducting rod excited by an array of magnetic ring sources. The coefficients of these sources are then adjusted to match boundary conditions on the cylindrical modification surface. For the locations of the match points and sources, three gauges involving weighted integrals of the tangential electric fields are used to optimize the solution. Good agreements between measurement and theory have been obtained for the input admittances, resonance properties, and radiation patterns. Results are also presented for a dipole on a sphere to contrast effects due to change in modification shape.     

A numerical solution for the near and far fields of an annular ring of magnetic current

A simple method for calculating the near and far zone fields from an annular ring of circumferentially directed magnetic current which may be used to represent coaxial apertures is presented. Near-field contours are given for two ring sizes. The utility of the method has been illustrated by its application in several practical antenna problems where the magnetic ring current serves as the primary source. Among these are the analysis of dipole antennas mounted on a conducting sphere or cylinder, the impedance of a coaxially fed Yagi-Uda antenna, a coaxially driven wire loop, and the radiation from a coaxial aperture at the base of a cone.     

Optical channel waveguide switch and coupler using total internal reflection

Light beam switching and coupling in a four-port channel waveguide-horn structure has been accomplished using electrooptic modulation of the critical angle of a refractive index interface in aY-cut LiNbO3substrate. The resulting double-pole double-throw switch/coupler is potentially capable of simultaneously providing a combination of desirable characteristics.     

Dichloromethane as an unusual methylene equivalent. A new entry of highly nucleophilic and selective titanium-methylene complexes for ester methylenation

[reaction: see text] The successful application of CH2Cl2-Mg-TiCl4-system mediated methylenation of various esters such as tert-butyl ester and 2,5-cyclohexadiene-1-carboxylate highlights the extraordinary reactivity, selectivity, and the nonbasic nature of this new methylene-carbenoid, which serves as a practical reagent applicable to large-scale synthesis.     

Spectrophotometric determination of deacetylation degree of chitinous materials dissolved in phosphoric acid

A simple spectrophotometric method is proposed for determining deacetylation degrees (DD) of chitinous materials using phosphoric acid as the UV-transparent solvent system. Calibrating by the extinction coefficients (A(210)) of D-glucosamine and N-acetyl-D-glucosamine, DD values (24-88%) were computed numerically. The results correlated well (R(2) = 0.9805, n = 50) with those obtained by solid-state (13)C NMR. Comparison of the results obtained by the proposed UV method and solid-state (13)C NMR.     

Diode-pumped passively Q-switched picosecond Nd:GDxY1-xVO4 self-stimulated raman laser

An efficiency of 8.2% is demonstrated for a diode-pumped passively Q-switched self-stimulated Raman laser with an a-cut mixed vanadate crystal, Nd:Gd0.8Y0.2VO4. At 2.2 W of incident pump power, the self-stimulated Raman laser produces pulses as short as 660 ps at a Stokes wavelength of 1175 nm with 2.7 microJ of energy per pulse at a 66-kHz repetition rate.