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C. Herrero Latorre J. Barciela GarcíaAuthor VitaeS. García MartínAuthor Vitae R.M. Peña CrecenteAuthor Vitae 《Analytica chimica acta》2013
Selenium is an essential element for the normal cellular function of living organisms. However, selenium is toxic at concentrations of only three to five times higher than the essential concentration. The inorganic forms (mainly selenite and selenate) present in environmental water generally exhibit higher toxicity (up to 40 times) than organic forms. Therefore, the determination of low levels of different inorganic selenium species in water is an analytical challenge. Solid-phase extraction has been used as a separation and/or preconcentration technique prior to the determination of selenium species due to the need for accurate measurements for Se species in water at extremely low levels. The present paper provides a critical review of the published methods for inorganic selenium speciation in water samples using solid phase extraction as a preconcentration procedure. On the basis of more than 75 references, the different speciation strategies used for this task have been highlighted and classified. The solid-phase extraction sorbents and the performance and analytical characteristics of the developed methods for Se speciation are also discussed. 相似文献
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Chromatography is one of the cornerstones of modern analytical chemistry; developing an instinctive feeling for how chromatography works will be invaluable to future generation of chromatographers. Specialized software programs exist that handle and manipulate chromatographic data; there are also some that simulate chromatograms. However, the algorithm details of such software are not transparent to a beginner. In contrast, how spreadsheet tools like Microsoft Excel™ work is well understood and the software is nearly universally available. We show that the simple repetition of an equilibration process at each plate (a spreadsheet row) followed by discrete movement of the mobile phase down by a row, easily automated by a subroutine (a “Macro” in Excel), readily simulates chromatography. The process is readily understood by a novice. Not only does this permit simulation of isocratic and simple single step gradient elution, linear or multistep gradients are also easily simulated. The versatility of a transparent and easily understandable computational platform further enables the simulation of complex but commonly encountered chromatographic scenarios such as the effects of nonlinear isotherms, active sites, column overloading, on-column analyte degradation, etc. These are not as easily simulated by available software. Views of the separation as it develops on the column and as it is seen by an end-column detector are both available in real time. Excel 2010™ also permits a 16-level (4-bit) color gradation of numerical values in a column/row; this permits visualization of a band migrating down the column, much as Tswett may have originally observed, but in a numerical domain. All parameters of relevance (partition constants, elution conditions, etc.) are readily changed so their effects can be examined. Illustrative Excel spreadsheets are given in the Supporting Information; these are easily modified by the user or the user can write his/her own routine. 相似文献
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Bisphenol A (BPA) is ubiquitous in humans and the environment. Its potential adverse effects through genomic and non-genomic pathways have fostered BPA replacement by bisphenol analogs that, unfortunately, exert similar adverse effects. Many of these analogs, as well as their derivatives, have already found in humans and the environment and major concerns have arisen over their low dose- and mixture-related effects. This review aims to discuss the characteristics of the main analytical methods reported so far for the determination of mixtures of bisphenol analogs and/or derivatives in human and environmental exposure sources and biological fluids. Approaches followed for removal of background contamination, sample preparation and separation and detection of mixtures of bisphenols and derivatives are critically discussed. Sample treatment is matrix-dependent and common steps include analyte isolation, removal of interferences, evaporation of the extracts and solvent reconstitution. Separation and quantification has been almost exclusively carried out by liquid chromatography tandem mass spectrometry (LC-MS/MS) or gas chromatography mass spectrometry (GC–MS), in the last case prior derivatization, but LC-fluorescence detection has also found some applications. Main characteristics, advantages and drawbacks of these methods will be comparatively discussed. Although at an early stage, some approaches for the assessment of the risk to mixtures of bisphenols, mainly based on the combination of chemical target analysis and toxicity evaluation, have been already applied and they will be here presented. Current knowledge gaps hindering a reliable assessment of human and environmental risk to mixtures of bisphenols and derivatives will be outlined. 相似文献
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Marko BarjaktarovicAuthor Vitae Slobodan PetricevicAuthor VitaeJovan RadunovicAuthor Vitae 《AEUE-International Journal of Electronics and Communications》2012,66(4):313-321
This paper presents a study of an important improvement in an already installed monochrome vision system for detection of defects during coated board manufacture. This improvement allows the inspection system to detect targeted defect in subsampling conditions (i.e. Nyquist theorem is not satisfied). This improvement is accomplished entirely in the image processing software without the need for additional changes in the vision hardware. Processing software is optimized for SIMD instruction set requiring no improvement in the processing hardware. Results obtained by the use of this improved algorithm provide real time detection of the targeted defect that in turns enables elimination of the waist coated board. 相似文献
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Kazuya Okano Author Vitae 《Tetrahedron》2011,67(14):2483-2512
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Yu Song MengAuthor Vitae Yee Hui LeeAuthor Vitae 《AEUE-International Journal of Electronics and Communications》2012,66(1):7-11
This paper investigates the shadowing effect induced by an aircraft during maneuvering for air-to-ground communication at C band. Narrowband measurements with a linear flight route and a circular flight route have been conducted and the results are compared in this paper. It is found that, the communication link can easily be shadowed by the aircraft body. Due to this shadowing, the transmitted signal undergoes significant attenuation of up to 28 dB at 5.7 GHz. Results also show that spatial diversity at the ground station is unable to eliminate this shadowing effect caused by the aircraft during maneuvering. 相似文献
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