Copolymers Containing Phosphorescent Iridium(III) Complexes Obtained by Free and Controlled Radical Polymerization Techniques

A methacrylate‐functionalized phosphorescent Ir(III)‐complex has been synthesized, characterized, and applied as a monomer in radical copolymerizations. Together with methyl methacrylate, the complex has been copolymerized under free radical polymerization conditions. Aiming for host‐guest‐systems, applicable e.g. in organic light emitting devices (OLEDs), the complex was further copolymerized with a methacrylate‐functionalized carbazole derivative using the atom transfer radical polymerization technique. Applying gel permeation chromatography, in combination with a photodiode array detector, could clearly prove the formation of the copolymers. The optical properties of the photoactive monomers as well as the copolymers were investigated by absorption and emission spectroscopy (in solution). For the carbazole‐copolymer, the emission originates almost exclusively from the complex. This provides evidence of an efficient intrachain energy transfer, which makes the system an interesting candidate for potential OLED applications.

     

A Discussion About Some of the Principles/Practices of Wireless Communication Under a Maxwellian Framework

There has been a plethora of papers dealing with wireless communication that use techniques, which when viewed from the perspective of a Maxwellian framework raise more questions than they answer. By Maxwellian framework we imply not only the relevance of electromagnetics in studying communication systems but also the proper interpretation of an ensemble processing in mathematical physics which was first introduced by Maxwell to study the behavior of an aggregate of molecules rather than the property of individuals. Initially, most of the modern signal processing techniques was developed for scalar acoustic problems. However, with the advent of wireless, these same techniques are being applied to the vector electromagnetics problem, which is fundamentally different in concept with respect to the scalar acoustic problem. The objective is to discuss some of these concerns associated with some of the current modeling methodologies particularly related to propagation modeling and antenna diversity. A goal is to initiate a dialog about the scientific merits of these new applications. One of the points to be made is that an incorrect use of probability theory can often lead to erroneous conclusions that directly contradict the principles of physics. A few examples are presented to initiate this dialog, mainly the applicability of scalar techniques to the vector wireless problem, including a proper interpretation of the Shannon channel capacity theorem. A methodology is also presented to illustrate how a simple multiple-input-multiple-output system can be based on the principles of reciprocity. Integration of the electromagnetic principles in some of the current methodologies of signal processing and communications theory may lead to a better system     

Solid-state Electrochemical Sensor Based on a Cross-linked Copper(II)-doped Copolymer and Carbon Nanotube Material for Selective and Sensitive Detection of Monohydrogen Phosphate

A novel solid-state electrochemical sensor based on a newly synthesized cross-linked copper(II) doped-copolymer and carbon nanotube material was developed for the direct determination of monohydrogen phosphate ions (HPO₄²⁻). The synthesized copolymers were characterized by FTIR, XPS, TG/DTG-DTA and SEM techniques. The sensor had a Nernstian slope:-30.7±0.4 mV/decade, linear concentrations range: 1.0×10⁻⁶ - 1.0×10⁻¹ M, detection limit: 6.5×10⁻⁷ M, response time: 4 s and life time: 17 weeks. The sensor displayed constant potentials in the pH range 7.0-9.5. The sensor was successfully used as an indicator electrode in potentiometric titration and the direct determination of HPO₄ ²⁻ in water samples.     

Synthesis,crystal structure,spectroscopy, thermal properties and carbonic anhydrase activities of new metal(II) complexes with mefenamic acid and picoline derivatives

The mononuclear six metal(II) complexes ([Co(mef)₂(3-pic)₂(CH₃OH)₂] (1), [Ni(mef)₂(3-pic)₂(CH₃OH)₂] (2), [Cu(mef)₂(3-pic)₂] (3), [Co(mef)₂(4-pic)₂] (4), [Ni(mef)₂(4-pic)₂] (5), and [Cu(mef)₂(4-pic)₂] (6) with mefenamic acid and picoline ligands were synthesized, characterized, and their carbonic anhydrase inhibitory activities were evaluated. The six complexes were characterized by elemental analysis, FT-IR spectroscopy, and thermal analyses. The crystal structures of 1, 3, and 6 were determined by X-ray crystallography. The complexes have octahedral geometry. In 1, the mefenamato ligand behaved as monodentate whereas in 3 and 6, the mefenamato ligand acted as a bidentate ligand. Complexes 3 and 6 consist of the mefenamate and 4-picoline ligands. In 1, unlike the other complexes, methanol acted as a ligand and was involved in the coordination. Carbonic anhydrase I and II isoenzymes were purified from human erythrocytes. The in vitro effects of mefenamic acid, 3-picoline, 4-picoline, and the six metal(II) complexes on these isoenzymes were evaluated.     

A new dioxime ligand and its trinuclear copper(II) complex: Synthesis, characterization and optical properties

The synthesis and characterization of a new dioxime ligand, (H₂L), (III) and its trinuclear copper(II) complex, [Cu₃L₂(H₂O)₂](ClO₄)₂, (V) is described. IR spectra show that the ligand acts in a tetradentate manner and coordinates N₄ donor groups of H₂L to copper(II) ion. The structure of the metal chelate is clarified with the help of elemental analysis, magnetic moment, conductometric and spectroscopic measurements. The optical absorption studies reveal that the transition is direct with band gap energy values are calculated. The optical constants such as refractive index and dielectric constant of the compound were determined. The refractive index dispersion curves of the films obey the single-oscillator model and oscillator parameters. Optical dispersion parameters E₀ and E_d developed by Wemple-DiDomenico were calculated.     

Temperature dependence of the optical band gap and electrical conductivity of sol-gel derived undoped and Li-doped ZnO films

Undoped and lithium (Li)-doped ZnO films were prepared by sol-gel method using spin coating technique. The effects of Li content on the crystallinity and morphological properties of ZnO films were assessed by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM). XRD patterns of the films showed the hexagonal wurtzite type polycrystalline structure and that the incorporation of lithium leads to substantial changes in the structural characteristics of ZnO films. The SEM and AFM measurements showed that the surface morphology of the films was affected from the lithium incorporation. The wrinkle network was observed on the surface from both SEM and AFM results for undoped ZnO. The wrinkle structure disappeared with increasing Li content. The absorption spectra of the ZnO and 5% Li-doped ZnO (LZO5) films were carried out between 140 and 400 K temperatures. The optical band gap of ZnO and LZO5 films (calculated at various temperatures) showed a linear dependence on the temperature. The absolute zero value optical band gap and the rate of change of the band gap with temperature of the ZnO and LZO5 films were found to be 3.339 and 3.322 eV, and 2.95 × 10⁻⁴ and 1.60 × 10⁻⁴ eV/K, respectively. The transport mechanisms in the ZnO and LZO5 films have been investigated by analyzing of the temperature (80-300 K) dependence of the conductivity. The activation energies of the ZnO film increased with Li content.     

A density functional theory study of ethylene adsorption on Ni10(1 1 1), Ni13(1 0 0) and Ni10(1 1 0) surface cluster models and Ni13 nanocluster

Ethylene adsorption was studied by use of DFT/B3LYP with basis set 6-31G(d,p) in Gaussian’03 software. It was found that ethylene has adsorbed molecularly on all clusters with π adsorption mode. Relative energy values were calculated to be −50.86 kcal/mol, −20.48 kcal/mol, −32.44 kcal/mol and −39.27 kcal/mol for Ni₁₃ nanocluster, Ni₁₀(1 1 1), Ni₁₃(1 0 0) and Ni₁₀(1 1 0) surface cluster models, respectively. Ethylene adsorption energy is inversely proportional to Ni coordination number when Ni₁₀(1 1 1), Ni₁₃(1 0 0) and Ni₁₀(1 1 0) cluster models and Ni₁₃ nanocluster are compared with each other.     

Particle filtering for passive fathometer tracking

Seabed interface depths and fathometer amplitudes are tracked for an unknown and changing number of sub-bottom reflectors. This is achieved by incorporating conventional and adaptive fathometer processors into sequential Monte Carlo methods for a moving vertical line array. Sediment layering information and time-varying fathometer response amplitudes are tracked by using a multiple model particle filter with an uncertain number of reflectors. Results are compared to a classical particle filter where the number of reflectors is considered to be known. Reflector tracking is demonstrated for both conventional and adaptive processing applied to the drifting array data from the Boundary 2003 experiment. The layering information is successfully tracked by the multiple model particle filter even for noisy fathometer outputs.     

Towards the formation of comprehensive SLAs between heterogeneous wireless DiffServ domains

Traffic patterns generated by multimedia services are different from traditional Poisson traffic. It has been shown in numerous studies that multimedia network traffic exhibits self-similarity and burstiness over a large range of time-scales. The area of wireless IP traffic modeling for the purpose of providing assured QoS to the end-user is still immature and the majority of existing work is based on characterization of wireless IP traffic without any coupling of the behaviour of queueing systems under such traffic conditions. Work in this area has either been limited to simplified models of FIFO queueing systems which do not accurately reflect likely queueing system implementations or the results have been limited to simplified numerical analysis studies. In this paper, we advance the knowledge of queueing systems by example of traffic engineering of different UMTS service classes. Specifically, we examine QoS mapping using three common queueing disciplines; Priority Queuing (PQ), Low Latency Queuing (LLQ) and Custom Queueing (CQ), which are likely to be used in future all-IP based packet transport networks. The present study is based on a long-range dependent traffic model, which is second order self-similar. We consider three different classes of self-similar traffic fed into a G/M/1 queueing system and construct analytical models on the basis of non-preemptive priority, low-latency queueing and custom queueing respectively. In each case, expressions are derived for the expected waiting times and packet loss rates of different traffic classes. We have developed a comprehensive discrete-event simulator for a G/M/1 queueing system in order to understand and evaluate the QoS behaviour of self-similar traffic and carried out performance evaluations of multiple classes of input traffic in terms of expected queue length, packet delay and packet loss rate. Furthermore, we have developed a traffic generator based on the self-similar traffic model and fed the generated traffic through a CISCO router-based test bed. The results obtained from the three different queueing schemes (PQ, CQ and LLQ) are then compared with the simulation results in order to validate our analytical models.     

On inverse problem for singular Sturm-Liouville operator from two spectra

We study an inverse problem with two given spectra for a second-order differential operator with singularity of the type (here, l is a positive integer or zero) at zero point. It is well known that two spectra {λ _n } and {λ _n } uniquely determine the potential function q(r) in the singular Sturm-Liouville equation defined on the interval (0, π]. One of the aims of the paper is to prove the generalized degeneracy of the kernel K(r, s). In particular, we obtain a new proof of the Hochstadt theorem concerning the structure of the difference . Published in Ukrains’kyi Matematychnyi Zhurnal, Vol. 58, No. 1, pp. 132–138, January, 2006.