Syntheses and Crystal Structures of Two One-dimensional Cobalt(Ⅱ) Compounds with the Flexible Dipyridyl Ligan

Two one-dimensional cobalt(Ⅱ) compounds {[Co(Hbpma)(H2O)4 ] 2 ·3SO 4 ·4.5H2O} n1 and {[Co(Hbpma)(NCS) 3 (H2O)]·2.85H2O}n2 (bpma = N,N -bis(3-pyridylmethyl)amine) have been synthesized and structurally characterized by single-crystal X-ray diffraction. Complex 1 crystallizes in triclinic, space group P1 with a = 15.8780(5), b = 16.2187(5), c = 16.4858(5) , α = 91.0420(10), β = 94.5190(10), γ = 101.4360(10)°, V = 4145.7(2) 3 , C 24 H 53 Co 2 N 6 O 24.50 S 3 , M r = 1031.76, Z = 4, D c = 1.653 g/cm 3 , μ(MoKα) = 1.046 mm -1 , F(000) = 2148, S = 1.017, the final R = 0.0269 and wR = 0.0644 for 13032 observed reflections (I > 2σ(I)). For complex 2, it belongs to triclinic, space group P1 with a = 9.3761(11), b = 10.5814(13), c = 11.2972(14) , α = 85.472(2), β = 88.058(2), γ = 76.203(2)°, V = 1085.0(2) 3 , C 15 H 21.70 CoN 6 O 3.85 S 3 , M r = 502.79, Z = 2, D c = 1.539 g/cm 3 , μ(MoKα) = 1.112 mm -1 , F(000) = 519, S = 1.070, the final R = 0.0358 and wR = 0.0899 for 3466 observed reflections (I > 2σ(I)). Two complexes 1 and 2 are both found to be one-dimensional coordination polymers bridged by the protonated bpma ligands, which are assembled into three-dimensional supramolecular structures through the hydrogen bonding interactions and π-π packing interactions.     

Delphi通过ADO技术访问数据库方法研究

Delphi是一种功能强大的编程语言,可以编写任何类型的程序。在众多的软件中,在数据库方面,Delphi表现出色,可以开发多种数据库结构的客户服务器模式数据库应用程序。文中研究了数据库程序开发中的最基本的一步,即如何用ADO连接数据库的方法。通过实例演示,展示了这种方法的细节,具有可操作性和可重复性,可供其他程序员借鉴,提高开发效率。     

盘旋螺旋槽管强化传热研究

用实验的方法以水为介质研究了同轴换热器的流动与传热,Re范围为30000到100000。研究表明管内摩擦阻力系数是相同情况下圆管的4到5倍,总体传热系数随管内Re的增大而增大,当Re较大时提高壳侧速度对换热性能的提升更有利。采用数值模拟的方法分别研究了同轴换热器整体的换热与流动,且和实验结果进行了比较,研究表明,受离心力的影响流体在管内产生了掺混流动,掺混流动的程度随螺距的减小而加剧,增加槽深减少了参与掺混的流体量,流体之间的掺混对换热具有积极的影响。     

A surface plasmon resonance imaging system for the stimulated living cell analysis

In this paper, a surface plasmon resonance imaging(SPRI) system for cell analysis is developed for obtaining the surface plasmon resonance(SPR) signal from the interactions between cells and different stimuli. The system is constructed with a red laser light source, a P-polarizer, a glass prism, a 5× objective lens, a charge coupled device(CCD) camera, a gold sensor chip, a polydimethylsiloxane(PDMS) reaction well and a mechanical scanning device. The system is applied to mapping living cells in response to stimuli by characterization of the refractive index(RI) changes. Cell responses to K+ in KCl solutions with concentrations of 5 mmol/L, 20 mmol/L, 50 mmol/L and 100 mmol/L are collected, which indicates that the SPRI method can distinguish the concentration of the stimuli. Furthermore, cell responses to epidermal growth factor(EGF) and vascular endothelial growth factor(VEGF) are studied independently. The binding of EGF receptor(EGFR) and EGF is collected as the first signal, and the internal change in cells is recorded as the second signal. The cell response to VEGF is different from that to EGF, which indicates that the SPRI as a label-free, real-time, fast and quantitative method has a potential to distinguish the cell responses to different stimuli.     

叶绿素及其Cu、Zn衍生物的伪装性能研究

研究了类叶绿素活性颜料在伪装应用中的光谱性能及光稳定性问题。从绿色植被的色素着手,分析了叶绿素的性质及影响其降解的原因,用Cu2+、Zn2+金属离子替代天然叶绿素中的Mg2+,制备了叶绿素衍生物,并通过光谱特性和光稳定性对叶绿素衍生物的特性进行了比较分析。研究结果表明,从光谱性能和稳定性两方面综合考虑,Cu叶绿素更适合作为叶绿素修饰目标来提高颜料的稳定性,从而为新型光学伪装涂料的制备提供材料基础。     

Tumor segmentation in lung CT images based on support vector machine and improved level set

In lung CT images, the edge of a tumor is frequently fuzzy because of the complex relationship between tumors and tissues, especially in cases that the tumor adheres to the chest and lung in the pathology area. This makes the tumor segmentation more difficult. In order to segment tumors in lung CT images accurately, a method based on support vector machine (SVM) and improved level set model is proposed. Firstly, the image is divided into several block units; then the texture, gray and shape features of each block are extracted to construct eigenvector and then the SVM classifier is trained to detect suspicious lung lesion areas; finally, the suspicious edge is extracted as the initial contour after optimizing lesion areas, and the complete tumor segmentation can be obtained by level set model modified with morphological gradient. Experimental results show that this method can efficiently and fast segment the tumors from complex lung CT images with higher accuracy.     

纳米银浆在微系统集成技术方面的应用

在纳米材料发展趋势的基础上,重点介绍了纳米银浆的特点及在微系统集成领域的发展现状。同时,使用京瓷的纳米银浆进行了装配验证,试验结果表明纳米银浆可应用于三维集成领域,并解决复杂组件组装时的温度兼容性问题。     

基于TDOA/TSOA的ADS-B虚假信号检测技术研究

广播式自动相关监视(ADS-B)开放式监视构架的特点使其面临易受人为虚假欺骗的安全性挑战。本文设置多个ADS-B基站,利用ADS-B信号的到达时间差(TDOA)与到达时间和(TSOA)对飞机实际位置进行多点定位,与ADS-B信号解码所得位置信息进行比对,从而剔除虚假飞机目标。首先实现ADS-B基站间的时间同步,建立基于TDOA/TSOA的定位模型与算法,给出了利用Friedlander算法获取初值的改进的Taylor级数算法以获取飞机位置。运用蒙特卡洛方法进行了四基站和五基站的仿真实验,结果表明,与现有Taylor级数算法相比,改进算法能提供更精确的飞机位置,并且五基站的定位性能要优于四基站的定位性能。     

多Agent在装备远程故障诊断系统中的应用

基于建立基层装备故障诊断模型并为装备故障诊断的发展打下理论前瞻的目的。本文通过对多Agent技术的理论分析,模型建立和实验论证,结合多Agent之间的交互和协助的实际情况,论证了多Agent技术在基层装备故障诊断中的应用价值,为基层故障诊断技术的建设打下了理论前瞻。     

基于目标指示的两坐标警戒雷达目标高度补偿状态估计

为了克服现有目标高度补偿算法存在的模型假设不合理、实际应用效果难以保证等问题,本文以目标恒海拔等速运动为前提,利用协同单元提供的目标指示信息,对两坐标雷达的空间目标跟踪问题重新进行了研究.首先根据不同坐标系间的转换关系,构建了目标高度的准确表达式.然后通过恒等变换和合理的近似,得到了目标高度的估计公式,并利用绝对值不等式和柯西-施瓦茨不等式,推导得到了高度估计公式的误差.最后联合目标高度估计公式和两坐标雷达的缺维量测方程,采用扩展卡尔曼滤波方法,实现了目标空间状态的估计.仿真结果表明:本文算法可有效地对目标高度进行补偿,获得稳定、可靠的目标空间状态估计,从而为两坐标雷达目标空间状态估计问题提供了相对有效完善的解决方法.