铌酸钾钠基1-3型压电复合物的制备及其性能研究

采用传统固相法制备了在1 130℃下烧结而成的(K_0.45Na_0.55)_0.98Li_0.02(Nb_0.77Ta_0.18Sb_0.05)O₃(KNLNTS)无铅压电陶瓷。陶瓷致密度和电学性能较好,致密度达到98%,室温压电常数为308.7 pC/N,厚度振动机电耦合系数可达0.5,1 kHz时介电损耗为0.043。以上述KNLNTS基粉体为原料,利用切割填充法制备1-3型压电复合材料并研究了厚度对复合材料的性能影响。结果表明,复合材料的压电常数、厚度振动机电耦合系数均随厚度的增加而增加,介电损耗随厚度的增加而减少,而相对介电常数基本保持不变。     

State-crossing from a Locally Excited to an Electron Transfer State(SLEET) Model Rationalizing the Aggregation-induced Emission Mechanism of (Bi)piperidylanthracenes

Luminogens with aggregation-induced emission(AIE)characteristics(or AIEgens)have been widely used in various applications due to their excellent luminescent properties in molecular aggregates and the solid state.A deep understanding of the AIE mechanism is critical for the rational development of AIEgens.In this work,the“state-crossing from a locally excited to an electron transfer state”(SLEET)model is employed to rationalize the AIE phenomenon of two(bi)piperidylanthracenes.According to the SLEET model,an electron transfer(ET)state is formed along with the rotation of the piperidyl group in the excited state of(bi)piperidylan-thracene monomers,leading to fluorescence quenching.In contrast,a bright state exists in the crystal and molecular aggregates of these compounds,as the intermolecular interactions restrict the formation of the dark ET state.This mechanistic understanding could inspire the deployment of the SLEET model in the rational designs of various functional AIEgens.     

Studies on the Reaction Mechanism of Br2 ＋ I2 = 2IBr

1 INTRODUCTION Interhalogen compounds have played an impor- tant role in environment and chemical engineering production. During the course of ozone exhaustion induced by sunlight in polar region, Br2, BrCl and HOBr are all precursors of Br atom[1]. Lately, scien- tists have detected that the content of BrCl in polar region sunlight was 35 ppt, larger than that of Br2 (25 ppt). Previous studies suggested that the con- centration of BrCl and O3 exhibits obvious negative correlation: w…     

洁净室气态分子污染物的监测技术

随着微电子工业工序复杂性的增加和产品尺寸的不断缩小,气态分子污染物(AMC)对产品的影响成为洁净室环境控制中重点关注的问题。文章介绍了洁净室中AMC的定义,重点阐述了AMC的监测技术。     

自由活塞斯特林发动机活塞位移测量

自由活塞斯特林发动机活塞往复振动位移对研究发动机特性具有重要意义,然而该类发动机活塞位于高压封闭腔体内且结构较为紧凑,其活塞往复振动位移难于直接进行测量。加速度传感器具有尺寸小、安装方便和工作稳定等特点,提出了采用加速度传感器测量活塞位移的方法。根据加速度传感器测量位移的原理,建立了一套加速度传感器测量自由活塞斯特林发动机活塞位移的标定试验系统,以位移传感器为基准测试并分析了不同活塞振幅和不同振动频率下加速度传感器测量位移的误差大小。实验结果表明,在活塞振幅小于8 mm,振动频率大于20 Hz条件下,加速度传感器测量位移的误差小于5%。因此加速度传感器可以用于测量自由活塞斯特林发动机的活塞往复运动位移。最后成功把加速度传感器测量的自由活塞斯特林发动机活塞振动位移用于发动机循环指示功的实验研究。     

Polypyrrole Hollow Nanotubes Loaded with Au and Fe3O4 Nanoparticles for Simultaneous Determination of Ascorbic Acid,Dopamine, and Uric Acid

An ultrasensitive electrochemical biosensor was fabricated for electroanalytical determination of ascorbic acid(AA), dopamine(DA) and uric acid(UA) individually and simultaneously based on polypyrrole hollow nanotubes loaded with Au and Fe₃O₄ nanoparticles(NPs) uniformly(PPy@Au-Fe₃O₄). The PPy@Au-Fe₃O₄ nanotubes were synthesized in one-pot using MoO₃ nanorods as templates and the polymerization of Py, the formation of Au and Fe₃O₄ NPs and the removel of MoO₃ templates took place stimultaneously. Electrochemical studies reveal that PPy@Au-Fe₃O₄modified glassy carbon electrode(GCE) possesses excellent electro-catalytic activities toward the oxidation of AA, DA and UA. Their oxidation peak currents increase linearly in the concentration ranges of 1-2000 μmol/L for AA, 0.01-25 and 25-300 μmol/L for DA and 0.1-300 μmol/L for UA. Their detection limit values(S/N=3) were calculated as 0.45, 0.0049, and 0.051 μmol/L for AA, DA and UA in the individual detection. By changing the concentrations simultaneously, the calibration curves showed linearity to 1000, 200, and 200 μmol/L with detection limit of 0.39, 0.0060, and 0.060 μmol/L for AA, DA, and UA, respectively. Finally, the obtained biosensor was successfully applied to the detection of AA, DA, and UA with satisfactory results on actual samples.     

茜素红S-牛血清白蛋白配合物的凝胶层析分离制备及紫外可见吸收光谱研究

用葡聚糖凝胶层析分离制备牛血清蛋白(BSA)-茜素红S(ARS)配合物。在420和530 nm处用紫外可见吸收光谱法同时测定含有BSA-ARS配合物和茜素红S的联立方程为:A420=4.89×103cARS 3.06×104cBSA-ARS,A530=4.60×102cARS 2.29×104cBSA-ARS;正交试验选择了合适的分离条件:柱直径1.0 cm,柱长30.0 cm,凝胶用量1.3 g,最佳进样浓度为ARS:5×10-3mol/L、BSA:1.49×10-4mol/L,进样体积1.5 mL,洗脱流速0.33 mL/min,分离度为1.25;测定了纯BSA-ARS配合物紫外吸收光谱,最大吸收峰在530 nm。     

双原子分子在啁啾激光作用下的经典解离

采用辛算法及经典理论方法,计算了HF分子在啁啾激光作用下的经典解离,讨论了解离几率随激光强度的变化,以及在相同激光强度下,选取不同的振动态作为初始态时解离几率的变化.     

剧院建筑声学设计中"歌手共振峰"问题研究

通过对"歌手共振峰"的分析以及对杭州2006世界休闲博览会主会场3200座水世界大剧院的实例应用,对剧院建筑声学设计中"歌手共振峰"问题进行了研究。结果表明:在现代剧院及多功能厅堂建筑声学设计过程中,建筑声学设计师在考虑了混响时间等参数指标的前提下,如果还能兼顾考虑"歌手共振峰"等音乐的某些特征,那么,剧院最后达到的声学效果远超出了有关厅堂的声学设计指标的意义。     

Java虚拟机内存管理与优化策略

多年以来,人们使用工具来完成任务,直到最近我们的工具才开始变得越来越聪明,并且互相连接起来。微处理器已经出现在很多日常使用的物品中,并且越来越多地和网络有了联系。J2ME目标是在具有16位或32位处理器和总量不少于约128KB的存储器的微型设备上运行JAvA程序。但由于硬件和软件方面的限制,为了给应用程序尽可能的空间和资源,让应用程序在虚拟机上流畅、稳定地运行,因而需要对这类嵌入式JAVA虚拟机进行优化处理,以提高其性能。对于JVW中代的划分、根集的确定和堆空间的分配、回收的新算法无疑能够优化虚拟机,提高其效率。