有机分子与聚电解质静电吸附成膜特性研究

选取多种有机分子及聚电解质，采用静电吸附自组装法制备了聚电解质，聚电解质、聚电解质，有机分子、有机分子，有机分子的复合薄膜，讨论了这些体系的静电吸附成膜特性及其成膜机理．     

ELECTRON PARAMAGNETIC RESONANCE STUDIES OF SINGLE CRYSTAL SODIUM HEXAMOLYBDOCHROMATE (Ⅲ)Cr~(3+)/Na_3(AlMo_6O_(24)H_6)·8H_2O

An X-band EPR study on a Na_3(CrMo_6O_(24)H_6)·8H_2O single crystal diluted by its isomor-phic compound Na_3(AlMo_6O_(24)H_6)·8H_2O at room temperature is reported. Using the least squares-fitting method to simulate the EPR data for principal planes, the Hamiltonian parameterswere obtained. The principal values of the g tensors are g_(ZZ) = 1.904, g_(XX)= 1.973, g_(YY)=1.933. The zero field splitting tensor parameters are D = 0.275 cm~(-1), E = 0.05 cm~(-1). The fielddependence of Cr~(3+) energy levels with field at different angles from the principal axes whenthe field is along the principal planes is calculated based on these experimental parameters.The isofrequency plots of calculated field vs. angle are also shown. They agree well with theexperimental results.     

An exponent bound on skew Hadamard abelian difference sets

A difference setD in a groupG is called a skew Hadamard difference set (or an antisymmetric difference set) if and only ifG is the disjoint union ofD, D(^–1), and {1}, whereD(^–1)={d^–1|dD}. In this note, we obtain an exponent bound for non-elementary abelian groupG which admits a skew Hadamard difference set. This improves the bound obtained previously by Johnsen, Camion and Mann.     

激光-载荷联合作用下天然乳胶烧蚀实验研究

为了摸清激光辐照橡胶类气象气球等空中目标的效应规律,为后续开展外场试验提供依据,本文进行了激光-载荷联合作用下天然乳胶材料烧蚀性能实验研究。采用1085 nm光纤固体激光器,对天然乳胶材料进行了激光辐照效应实验,研究了激光和载荷共同作用下材料的烧蚀性能,结果得到：材料主要发生热解、烧蚀穿孔和断裂破坏;在同等功率密度光斑辐照条件下,材料破坏时间随载荷增加先增加后减小;在同等加载条件下,材料破坏时间随辐照功率密度增加而减小。     

面向方向图保形的共口径基站天线去耦技术

为了节省基站天线所占空间资源,降低其运营成本,现代移动通信需要将多个天线阵列紧密地排列在一起,构成多频共口径基站天线。多天线的紧密排列势必造成天线间强烈的耦合,不仅使得天线阻抗失配、隔离度变差,同时也造成辐射方向图的严重变形。因此,近年来多频共口径基站天线的去耦成为工业界和学术界研究的热点,早期的去耦技术主要是面向改善天线的阻抗匹配和隔离度,而对面向方向图保形的去耦技术研究相对较少。文章在简要介绍面向方向图保形的基站天线去耦技术的研究现状的基础上,重点阐述了褚庆昕教授天线射频团队基于感应电流抵消、耦合场抵消和辐射阻断等原理,提出的几种新型的去耦技术。这些技术不仅可以有效地改善基站天线的阻抗匹配和隔离,更重要的是很好地实现了天线方向图保形。仿真和测试结果验证了原理的正确性和设计的可行性。一些技术已被用于5G基站天线产品。     

Minimizing Energy Barrier in Intermediate Connection Layer for Monolithic Tandem WPeLEDs with Wide Color Gamut

Perovskite light-emitting diodes (PeLEDs) show promising prospects in the wide color gamut display owing to their ultra-narrow full width at half maximum (FWHM). However, up to now, all perovskite white LEDs integrated by standard red, green, and blue perovskite emitters, namely, monolithic white PeLEDs (WPeLEDs), have been rarely reported, owing to facing some issues, e.g., solvent incompatibility in solution technique, ion exchange, and energy transfer between different emission centers. Herein, centered on these issues, an optimal intermediate connection layer (ICL) of Po-T2T/LiF/Ag/HAT-CN/MoO₃ is adopted to successfully develop monolithic tandem multicolor PeLEDs and WPeLEDs for the first time. The multicolor PeLEDs can achieve the best external quantum efficiency of 1.8% and the highest luminance of 4844 cd m⁻². Besides, the red/green/blue (R/G/B) monolithic tandem WPeLED shows a standard white International Commission on Illumination coordinate of (0.33, 0.33) and achieves an extremely wide color gamut reaching  National Television Standards Committee of 130%. This study is the first to realize the standard R/G/B co-electroluminescence in a monolithic perovskite device and offers a feasible strategy for developing wide-color gamut perovskite displays.     

Doped/Undoped A1-A2 Typed Copolymers as ETLs for Highly Efficient Organic Solar Cells

The electron transport layer (ETL) is a critical component in achieving high device performance and stability in organic solar cells. Conjugated polyelectrolytes (CPEs) have become an attractive alternative due to film-forming properties and ease of preparation. However, p-type CPEs generally exhibit poor charge mobility and conductivity, incorporation of electron-withdrawing units forming alternated D-A conjugated backbone can make up for these deficiencies. Herein, the ratio of electron withdrawing moieties are further increased and two poly(A1-alt-A2) typed PIIDNDI-Br and PDPPNDI-Br based on the combination of naphthalene diimide (NDI) with isoindigo (IID) or diketopyrrolopyrrole (DPP) via direct arylation polycondensation are synthesized. These CPEs possess excellent alcohol solubility, a suitable lowest unocuppied molecular orbital energy level, and work function tunability. Surprisingly, the incorporation of IID and DPP units generate distinct self-doping behaviors, which are confirmed by UV–vis absorption and ESR spectra. However, no matter doped or undoped, both CPEs present better charge-transporting properties and conductivity when utilized as ETLs. The PIIDNDI-Br and PDPPNDI-Br display good universal compatibility with the blend of PM6:Y6 and PM6:L8-BO, and PCEs of 18.32% and 18.36% are obtained, respectively, which also present excellent storage stability. In short, the combination of two different acceptors demonstrates an efficient strategy to design highly efficient ETLs for high performance photovoltaic devices.     

Boosting Piezo-Catalytic Activity of KNN-Based Materials with Phase Boundary and Defect Engineering

Although the piezo-catalysis is promising for the environmental remediation and biomedicine, the piezo-catalytic properties of various piezoelectric materials are limited by low carrier concentrations and mobility, and rapid electron-hole pair recombination, and reported regulating strategies are quite complex and difficult. Herein, a new and simple strategy, integrating phase boundary engineering and defect engineering, to boost the piezo-catalytic activity of potassium sodium niobate ((K, Na)NbO₃, KNN) based materials is innovatively proposed. Tur strategy is validated by exampling 0.96(K_0.48Na_0.52)Nb_0.955Sb_0.045O₃-0.04(Bi_xNa_4-3x)_0.5ZrO₃-0.3%Fe₂O₃ material having phase boundary engineering and conducted the defect engineering via the high-energy sand-grinding. A high reaction rate constant k of 92.49 × 10⁻³ min⁻¹ in the sand-grinding sample is obtained, which is 2.40 times than that of non-sand-grinding one and superior to those of other representative lead-free perovskite piezoelectric materials. Meanwhile, the sand-grinding sample has remarkable bactericidal properties against Escherichia coli and Staphylococcus aureus. Superior piezo-catalytic activities originate from the enhanced electron-hole pair separation and the increased carrier concentration. This study provides a novel method for improving the piezo-catalytic activities of lead-free piezoelectric materials and holds great promise for harnessing natural energy and disease treatment.     

The research on channel estimation and signal-noise ratio estimation based on minimum error entropy kalman filter for single carrier frequency domain equalization system

In this paper, the channel estimation and signal-to-noise ratio (SNR) estimation technique of single-carrier frequency domain equalization (SC-FDE) system under low SNR in aeronautical multipath channel are studied, a SNR estimation algorithm which is easy to implement in engineering and an improved LS channel estimation algorithm based on Kalman filter using minimum error entropy (MEE-KF) are proposed. This paper first introduces the SC-FDE system and introduces the principle of MEE-KF, and then, the channel estimation flow based on MEE-KF is obtained by combining it with the traditional LS channel estimation algorithm, which makes the estimation results perform better. Simulation results show that after getting more accurate noise variance, the channel estimation results can better follow the changes of the channel after MEE-KF processing, so as to resist the doppler frequency offset effect and make the channel estimation results more accurate, that is the channel response results of the data part can be closer to the real situation, so that the communication performance of SC-FDE system has also been greatly improved.     

Recent Development of Jumping Motions Based on Soft Actuators

Drawing inspiration from the jumping motions of living creatures in nature, jumping robots have emerged as a promising research field over the past few decades due to great application potential in interstellar exploration, military reconnaissance, and life rescue missions. Early reviews mainly focused on jumping robots made of lightweight and rigid materials with mechanical components, concentrating on jumping control and stability. Herein, attention is paid to the jumping mechanisms of soft actuators assembled from various soft smarting materials and powered by different stimulus sources. The challenges and prospects of soft jumping actuators are also discussed. It is hoped that this review will contribute to the further development of soft jumping actuators and broaden their practical applications.