Future contributions toJournal of Crystallographic and Spectroscopic Research

Future contributions toJournal of Crystallographic and Spectroscopic Research     

厚膜导体的金属迁移研究

金属迁移能导致混合微电路发生灾难性失效。本文介绍一种简单易行的测试方法－水滴试验法，来测量厚膜电路的实际金属迁移率。用引方法测量时，发现Ｐｄ－Ａｇ导体的迁移率最大，Ｐｔ－Ａｕ导体的金属迁移率最小。     

Voltammetric determination of methyl parathion, ortho, meta and para nitrophenol with a carbon paste electrode modified with C18

Summary The determination of methyl-parathion (MPT), ortho (ONP), meta (MNP) and para nitrophenol (PNP) has been studied by differential pulse voltammetry with a carbon-paste electrode modified with 50% (w/w) of C₁₈. A study of the influence of the pH in the preconcentration cell and the measurement cell was carried out for an electrode with 50% modifier and an accumulation time of 5 min. The voltammograms were recorded with a sweep rate of 40 mV s^–1 and a pulse amplitude of 50 mV. With the optimum conditions of pH for both of the steps, various other variables were studied. The variables for each compound were optimized and the possibility of application to the determination of a mixture of the four compounds was investigated. The determination limits found for all the compounds are: 2 ng ml^–1 for ONP, 5 ng ml^–1 for MNP, 4.3 ng ml^–1 for PNP and 7.9 ng ml^–1 for MPT. The method was applied to samples of a small lake which gathers rain water and water filtered from land on which cereals are grown.     

Enzymatic synthesis of 3-hydroxybutyramides and their conversion to optically active 1,3-aminoalcohols

3-Hydroxybutyramides are obtained in high optical yield from ethyl (±)-3-hydroxybutyrate and aliphatic amines when the reaction is catalyzed by Candida antartica lipase. The chemical reduction of these 3-hydroxybutyramides yields the corresponding 1,3 -aminoalcohols.     

Application of a digital signal processor to Fourier-transform infrared spectroscopy

Summary The application of a digital signal processor (DSP) to Fourier-transform infrared spectroscopy is described, which allows for near real-time display of the transformed interferograms as spectra.     

三维随机Ising模型的亚稳态性(Ⅱ)

讨论三维格点环面上随机Ising模型当温度趋向零时的亚稳态性,确定从自旋全为-1的组态到自旋全为+1的组态的最大似然路径和临界组态,并计算出从自旋全为-1的组态出发首次到达自旋全为+1的组态的首达时间的渐近对数估计。证明利用一族带指数扰动的Markov链的大偏差估计。     

Dependence of impurity incorporation upon substrate misorientation during GaAs growth by metalorganic vapour phase epitaxy

Doping studies of the incorporation behaviour of three different dopants (Zn, In and Si) versus the misorientation of the (100) surface during MOVPE growth of GaAs have been carried out with diethylzinc, trimethylindium and disilane as precursors. The incorporation of the dopants has been studied as function of the input mole fraction dopant, growth temperature, degree and direction of misorientation. In order to explain the results we discuss the BCF theory and the nature of the steps as function of above mentioned parameters. It appears that the BCF theory alone cannot explain the results, a counteracting mechanism has been introduced based on preferential arsenic desorption from the step edges.     

Low-Energy Digit-Serial/Parallel Finite Field Multipliers

Digit-serial architectures are best suited for systems requiring moderate sample rate and where area and power consumption are critical. This paper presents a new approach for designing digit-serial/parallel finite field multipliers. This approach combines both array-type and parallel multiplication algorithms, where the digit-level array-type algorithm minimizes the latency for one multiplication operation and the parallel architecture inside of each digit cell reduces both the cycle-time as well as the switching activities, hence power consumption. By appropriately constraining the feasible primitive polynomials, the mod p(x) operation involved in finite field multiplication can be performed in a more efficient way. As a result, the computation delay and energy consumption of one finite field multiplication using the proposed digit-serial/parallel architectures are significantly less than of those obtained by folding the parallel semi-systolic multipliers. Furthermore, their energy-delay products are reduced by a even larger percentage. Therefore, the proposed digit-serial/parallel architectures are attractive for both low-energy and high-performance applications.     

MOS结构准静态测试中的异常C—V曲线

本文报导了MOS结构在准静态测试中的异常电容-电压曲线。讨论了它们产生的原因。     

Three-dimensional trajectory study of the I + HI → IH + I, H + I2 reactions

The quasiclassical trajectory calculation of the I + HI collision is performed in order to study the exchange and endothermic reaction channels. The rate constant of the exchange reaction I′ + HI → HI′ + I is found to be equal to 7.7 × 10¹¹ cm³/mol s at room temperature of 300 K. The study of the endothermic reaction I + HI → H + I₂ shows that it takes place only in configurations with large bend angles. Due to the non-collinear character of this reaction its threshold (2 eV) exceeds significantly the threshold of the minimal energy (collinear) reaction path (1.55 eV).