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51.
In order to obtain the depth profile of a thin film, we investigated the emission characteristics of a voltage modulation glow discharge to optimize the modulation parameters (modulation voltage, offset voltage, and modulation frequency). In this study, a phase-sensitive detection method with a lock-in amplifier to the modulation technique led to a higher sensitivity and a larger signal-to-noise ratio in the emission analysis compared to the normal dc amplification method. Upon increasing the maximum voltage, the emission intensity of the Cu atomic line (CuI 239.34 nm) increased linearly at a modulation voltage of 400 V and an offset voltage of 300 V. On the other hand, the emission intensity was gradually reduced when a modulation frequency increased. It is advantageous for surface analysis that the voltage modulation technique gives a lower sputtering rate rather than the conventional dc discharge. 相似文献
52.
T. S. Lee S. B. Lee J. M. Kim J. S. Kim S. H. Suh J. H. Song I. H. Park S. U. Kim M. J. Park 《Journal of Electronic Materials》1995,24(9):1057-1059
In order to improve the Zn homogeneity along the axial direction of CdZnTe boule, we have employed a modified Bridgman technique
using a (Cd, Zn) alloy source in communication with the melt, whose temperature has been gradually changed from 800 to 840°C
during growth. Electron probe microanalysis (EPMA) measurements of Zn composition in the boule shows an excellent homogeneity
of Zn along the axis of the CdZnTe boule compared with results in a boule grown by using a fixed source temperature. We have
performed a numerical simulation to obtain the approximate temperatures of additional heating and cooling needed to improve
the radial Zn homogeneity. CdZnTe boule has been grown by seeded vertical Bridgman furnace with two zones of heater and cooler.
Ultraviolet/visible spectroscopic measurements of Zn composition over the length of the boule indicate that the radial distribution
of Zn composition is very homogeneous in the body region of the boule, where the radial variation of Zn composition is ±0.0005. 相似文献
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William W. Paudler Richard A. Vandahm Young N. Park 《Journal of heterocyclic chemistry》1972,9(1):81-85
The diazaanalog of “cycl[3,2,2]azine”, “1,4-diazacycl[3,2,2]azine” (1,4,7b-triazacyclopent-[cd]indene) and its 2-methyl derivative were prepared. These compounds are subject to facile acid-catalyzed hydrolysis affording substituted imidazo[1,2-a]pyridines. 相似文献
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Choon Sup RaGyoosoon Park 《Tetrahedron letters》2003,44(5):1099-1102
The mechanism of the allylic oxidation of 2-methyl-2-butene with selenium dioxide has been investigated by ab initio quantum mechanics. Transition states for two major steps (an ene reaction and a [2,3]-sigmatropic rearrangement) of this reaction have been optimized by the B3LYP/6-311+G(d,p) method. A comparison of the energies of the transition states shows that the anti-endo and syn-endo approaches are the efficient routes in the ene reaction and the methyl (C4) group is sited in a pseudo-equatorial environment in cyclic transition states during the [2,3]-rearrangement. Calculations also show the kind of the terminal alkyl (C4) substituents may control (E)-selectivity in the formation of the allylic alcohols. 相似文献