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981.
Bruno Kisch 《Colloid and polymer science》1929,49(2):156-158
Ohne Zusammenfassung 相似文献
982.
Ohne Zusammenfassung
über diese Untersuchung wurde bei gleich-, zeitiger Vorführung des Kinofilmes am 18. 3. 1933 von K. He? vor der kolloidchemischen
Sektion der holl?ndischen chemischen Gesellschaft, am 15. 5. 1933 im Colloquium des Kaiser-Wilhelm-Institut für physikalische
Chemie und Elektrochemie, sowie am 10. 7. 1933 in der Juli-Sitzung der Deutschen chemischen Gesellschaft berichtet.
Für die überlassung optischer Instrumente zur Durchführung der Untersuchungen im Dunkelfeld sind wir der Deutschen Gemeinschaft
zur Erhaltung und F?rderung der Forschung zu aufrichtigem Dank verpflichtet. Der I. G. Farbenindustrie A. G. und im besonderen
Herrn Direktor Dr. Gajewski danken wir für die überlassung von Filmmaterial für die Kinoaufnahme. 相似文献
983.
R. Benedikt F. Ulzer Focke Finkener Th. Morawski Alfred H. Allen O. Schweissinger R. Marzahn Dieterich Hazura F. W. A. Woll Bruno Röse Ch. Dubois L. Padé R. Bensemann Audoynaud Levallois T. Leone A. Longi F. Benecke Joseph Herz P. Soltsien C. Schädler C. L. Reimer W. Will H. Hager 《Analytical and bioanalytical chemistry》1888,27(1):524-539
984.
985.
The modes of fragmentation of perchlorylbenzene (C6H5ClO3) and its perdeutero derivative under electron impact are reported and discussed. The occurrence of the [C6H5O]? and [C6H5O]+ ions is accounted for in terms of a novel phenyl migration from chlorine to oxygen. 相似文献
986.
Carmona D Sáez J Granados H Pérez E Blair S Angulo A Figadere B 《Natural product research》2003,17(4):275-280
Dichloromethane extracts of both the roots and the leaves of Raimondia cf. monoica showed in vitro antiplasmodial and leishmanicidal activities against Plasmodium falciparum and Leishmania panamensis, respectively. Three 6-substituted 5,6-dihydro-2H-pyran-2-ones were isolated. (1) and (2) were identified as (6S)-(5'-oxohepten-1'E,3'E-dienyl)-5,6-dihydro-2H-pyran-2-one (1) and (6R)-(5'-oxohepten-1'Z,3'E-dienyl)-5,6-dihydro-2H-pyran-2-one (2), respectively. (-)-Arentilactone (3) was also isolated. The structure of the new compound (1) was determined by spectroscopic methods; additional spectroscopic data for (2) are reported for the first time. 相似文献
987.
De Gregorio A Battistutta R Arena N Panzalorto M Francescato P Valentini G Bruno G Zanotti G 《Organic & biomolecular chemistry》2003,1(18):3178-3185
Ornithine transcarbamoylase from ovine liver has been purified to homogeneity. Like all anabolic OTCs, the ovine enzyme is a trimer, constituted by identical subunits of 34 kDa. Sequence analysis of the 54 N-terminal residues of ovine OTC shows a high degree of homology with the human enzyme. The optimum pH and the Michaelis constants for the catalytic reaction were determined. The ovine enzyme is the most thermostable one among mammals OTCs, its critical temperature being 6 degrees C higher than those measured for the other enzymes. The enzyme has been crystallised and the structure determined at 3.5 A resolution. Crystals belong to the cubic P4(3)32 space group, with a = b = c = 184.7 A and a solvent content of about 80%. There is no evidence of any ligand in the active site cavity, indicating that the crystals contain an unliganded or T state of the enzyme. The unliganded OTCase enzyme adopts a trimeric structure which, in the crystal, presents a three-fold axis coincident with the crystallographic one. The conformation of each monomer in the trimer is quite similar to that of the liganded human protein, with the exception of a few loops, directly interacting with the substrate(s), which are able to induce a rearrangement of the quaternary organisation of the trimer, that accounts for the cooperative behaviour of the enzyme following the binding of the substrates. 相似文献
988.
The Z- and E-γ-alkylthio-allylboronates and were found to add aldehydes forming diastereoselectively the adducts and respectively in high yield. 相似文献
989.
A conformational study of new diversely substituted 14-membered diketal dilactam macrocycles was conducted by NMR spectroscopy in liquid and solid states, molecular mechanics calculations and, for one compound, a previous X-ray analysis. The results obtained by the different techniques show that the conformations depend closely on whether the molecules are chiral or achiral and on the stereochemistry of the ketal OMe groups. In achiral compounds, the most stable conformation of each compound has, in both the liquid and solid states, the two NH-CO links positioned perpendicular to the macrocycle plane, lending to the trans-7,7′-OMe macrocycles 6b and 7b a rectangular [3434]-type structure. In contrast, in chiral compounds, the most stable conformations are not the same in the liquid and solid phases. In the liquid state the conformations are set by the presence of one or two N4-H?O1′, N4′-H?O1 intramolecular hydrogen bonds that position the amide group parallel to the macrocycle plane, whereas in the solid state the amide moieties again adopt a perpendicular position which can be stabilized, when the 3-R substituent is not too bulky, by intermolecular N-H?OC bonds between parallel sheets, and exceptionally, in the cis-7,7′-OMe-3,3′-Ph compound 1c, by a π-π stacking effect between the phenyl groups. 相似文献
990.
Erich Widmer Milan Soukup Reinhard Zell Emil Broger Bruno Lohri Roman Marbet Teodor Luk
《Helvetica chimica acta》1982,65(3):944-957
Technical Procedures for the Synthesis of Carotenoids and Related Compounds from 6-Oxo-isophorone, VI. Synthesis of Rhodoxanthin and (3RS, 3′RS)-Zeaxanthin; Routes to the C15-Ring Component via 3-Oxo-ionone Derivatives The C15-ring component 4 , key intermediate of a new scheme for the synthesis of rhodoxanthin ( 1 ) and (3RS, 3RS)-zeaxanthin ( 3 ), has been synthesized starting from 6-oxo-isophorone ( 7 ) via 3-oxo-cyclocitral and 3-oxo-ionone derivatives. 相似文献