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81.
James O'Donnell Bruno Rusterholz Barbara Aebersold Denise Rüegg Wilhelm Simon Ernö Pretsch 《Mikrochimica acta》1994,113(1-2):45-52
In an investigation of octamethylene bis(malonic acid diamides) and their selectivities for magnesium, it was found that presence of secondary amides within the particular ionophore played a considerable role in the enhancement of magnesium selectivity. Similar effects in other ionophores, i.e. tris(malonic acid diamides), were thus systematically looked at with the help of selectivity measurements with the hope of optimizing the number of secondary and tertiary amides so as to improve the magnesium selectivity. The syntheses of several investigated tris(malonic acid diamide) isologues are equally reported.Deceased in November 1992 相似文献
82.
Bischelate platinum(II) complexes of the type [Pt(H-R(2)-N(2)C(2)S(2))(2)] (H-R(2)-N(2)C(2)S(2)(-) = dialkyl-dithioxamidate) are ditopic receptors which, after coordination of the first Pd(eta(3)-allyl)(+) moiety, induce the orientation of the second palladium-allyl fragment. Thus, a series of trimetallic complexes of formula bis-[(eta(3)-allyl)-palladium(II)](mu-bis-dialkyl-dithioxamidate-platinum(II) kappa-S,S-kappa-S',S'-Pt-kappa-N,N-Pd-kappa-N',N'-Pd') has been prepared in which the allyl fragments are oriented toward the same side of the molecular plane. We have also prepared the trimetallic complex using a dithioxamide obtained from the racemic phenylethylamine. Only two isomers were produced in equimolar ratio: the racemate that has four homochiral alkyl substituents and the mesoform containing the meso-dithioxamide that has homochiral substituents on the same side of molecular plane. Under the effect of the temperature, the trimetallic Pd-Pt-Pd complexes undergo rapid allyl isomerization; the mechanism of the isomerization, which is similar to that found by us in an analogue Pt-Pd bimetallic complex, is discussed. The crystal and molecular structure of bis-[(eta(3)-allyl)-palladium(II)](mu-bis-[S]-phenylethyl-dithioxamidate-platinum(II) kappa-S,S-kappa-S',S'-Pt-kappa-N,N-Pd-kappa-N',N'-Pd') has been reported. 相似文献
83.
Abstract— During prolonged continuous irradiation with red light the specific activity of uridine 5'-diphosphoglucose (UDPG) pyrophosphorylase (uridine 5'-triphosphate: glucose 1-phosphate uridylyl-transferase EC 2.7.7.9) decreased in Acetabularia mediterranea Lamouroux (=A. acetabulum (L.) Silva). Subsequent blue light restored the original activity within a comparatively short period of 3 to 4 days. Computer-aided quantitative evaluation of density labelling experiments showed that the synthesis of the enzyme was accelerated about four-fold during the period of activation by blue light. A similar increase in the rate of synthesis was found for hydroxypyruvate reductase (EC 1.1.1.81), a control enzyme that showed no blue light-dependent changes in the specific activity under these conditions. The increase in the rate of enzyme synthesis was caused by an overall stimulation of the cytosolic translation. Degradation of UDPG pyrophosphorylase was unaffected by blue light, while the half life of hydroxypyruvate reductase was shortened about two-fold compared to continuous red light. Thus, degradation of proteins appears to be selectively light dependent in Acetabularia.
Model calculations for enzyme amount and enzyme synthesis were carried out using the measurements of enzyme activity, rates of cytosolic protein synthesis, and degradation constants of the enzymes. Assuming that activities represented amounts of the given enzymes, these calculations indicated a selective activation of UDPG pyrophosphorylase synthesis by blue light since it did not coincide with the overall stimulation of protein synthesis in the cytosol, in contrast to hydroxypyruvate reductase. 相似文献
Model calculations for enzyme amount and enzyme synthesis were carried out using the measurements of enzyme activity, rates of cytosolic protein synthesis, and degradation constants of the enzymes. Assuming that activities represented amounts of the given enzymes, these calculations indicated a selective activation of UDPG pyrophosphorylase synthesis by blue light since it did not coincide with the overall stimulation of protein synthesis in the cytosol, in contrast to hydroxypyruvate reductase. 相似文献
84.
J.Georges Duboudin Michel Petraud Max Ratier Bruno Trouve 《Journal of organometallic chemistry》1985,288(1):C6-C8
Flash pyrolysis of alkyltributyltin acetates, at high temperatures (600–850° C) under a moderate vacuum provides a convenient route to vinyltin derivatives. 相似文献
85.
The nanometer scale is a special place where all sciences meet and develop a particularly strong interdisciplinarity. While biology is a source of inspiration for nanoscientists, chemistry has a central role in turning inspirations and methods from biological systems to nanotechnological use. DNA is the biological molecule by which nanoscience and nanotechnology is mostly fascinated. Nature uses DNA not only as a repository of the genetic information, but also as a controller of the expression of the genes it contains. Thus, there are codes embedded in the DNA sequence that serve to control recognition processes on the atomic scale, such as the base pairing, and others that control processes taking place on the nanoscale. From the chemical point of view, DNA is the supramolecular building block with the highest informational content. Nanoscience has therefore the opportunity of using DNA molecules to increase the level of complexity and efficiency in self-assembling and self-directing processes. 相似文献
86.
Bruno Crociani Umberto Belluco Pierluigi Sandrini 《Journal of organometallic chemistry》1979,177(2):385-401
The reactions of the organometallic 1,4-diazabutadienes, RN=C(R′)C(Me)=NR″ [R = R″ = p-C6H4OMe, R′ = trans-PdCl(PPh3)2 (DAB); R = p-C6H4OMe, R″ = Me, R′ = trans-PdCl(PPh3)2 (DABI; R = R″ = p-C6H4OMe, R′ = Pd(dmtc)-(PPh3), dmtc = dimethyldithiocarbamate (DABII); R = R″ = p-C6H4OMe, R′ = PdCl(diphos), diphos = 1,2-bis(diphenylphosphino)ethane (DABIII)] with [RhCl(COD)]2 (COD = 1,5-cyclooctadiene, Pd/Rh ratio = ) depend on the nature of the ancillary ligands at the Pd atom in group R′. In the reactions with DAB and DABI transfer of one PPh3 ligand from Pd to Rh occurs yielding [RhCl(COD)(PPh3)] and the new binuclear complexes [Rh(COD) {RN=C(R?)-C(Me)=NR″}], in which the diazabutadiene moiety acts as a chelating bidentate ligand. Exchange of ligands between the two different metallic centers also occurs in the reaction with DABII. In this case, the migration of the bidentate dmtc anion yields [Rh(COD)Pdmtc] and [Rh(COD) {RN=C(R?)C(Me)=NR″}]. In contrast, the reaction with DABIII leads to the ionic product [Rh(COD)- (DABIII)][RhCl2(COD)], with no transfer of ligands. The cationic complex [Rh(COD)(DABIII)]+ can be isolated as the perchlorate salt from the same reaction (Pd/Rh ratio = 1/1) in the presence of an excess of NaClO4. In all the binuclear complexes the coordinated 1,5-cyclooctadiene can be readily displaced by carbon monoxide to give the corresponding dicarbonyl derivatives. The reaction of [RhCl(CO)2]2 with DAB and/or DABI yields trinuclear complexes of the type [RhCl(CO)2]2(DAB), in which the diazabutadiene group acts as a bridging bidentate ligand. Some reactions of the organic diazabutadiene RN=C(Me)C(Me)=NR (R = p-C6H4OMe) are also reported for comparison. 相似文献
87.
de Oliveira MC Scarpellini M Neves A Terenzi H Bortoluzzi AJ Szpoganics B Greatti A Mangrich AS de Souza EM Fernandez PM Soares MR 《Inorganic chemistry》2005,44(4):921-929
The crystal structures and redox and UV-vis/EPR spectroscopic properties of two new mononuclear copper(II) complexes, [Cu(HL1)Cl2] (1) and [Cu(L1)Cl] (2), prepared through the reaction between copper(II) chloride and the ligand 2-[(bis(pyridylmethyl)amino)methyl]-4-methyl-6-formylphenol (HL1) under distinct base conditions, are reported along with solution studies. Also, we demonstrate that these CuII complexes are able to cleave unactivated peptide bonds from bovine serum albumin (BSA) and the thermostable enzyme Taq DNA polymerase at micromolar concentration, under mild pH and temperature conditions. The cleavage activity seems to be specific with defined proteolytic fragments appearing after protein treatment. The location of the specific cleavage sites was tentatively assigned to solvent-accessible portions of the protein. These are two of the most active Cu(II) complexes described to date, since their cleavage activity is detected in minutes and evidence is here presented for a hydrolytic mechanism mediating protein cleavage by these complexes. 相似文献
88.
Bruno Gabutti 《Numerische Mathematik》1984,43(3):439-461
Summary The Euler-Knopp transformation and a recently considered transformation, effective for entire function of order 1, are applied to series involving completely monotonic coefficients. Some properties of the resulting series are analyzed; these include uniform convergence with respect to the index, a priori and a posteriori estimates of the remainder. For the latter transformation a compact recursive algorithm is established which enables one to make effective use of the transformation. To illustrate the effectiveness of the transformations three applications, with examples, are included. 相似文献
89.
Bruno Gabutti 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1984,35(3):265-281
Summary Considerf+
ff+ (1–f2)+
f=0 together with the boundary conditionsf(0)=f(0)=0,f ()=1. If=–1,>0, arbitrary there is at least one solution which satisfies 0<f<1 on (0, ). By the additional conditionf>0 on (0, ) or, alternately 0<1, the uniqueness of the solution is demonstrated.If=1,<0, arbitrary the existence of solutions for which –1<f<0 in some initial interval (0,t) and satisfying generallyf>1 is established. In both problems, bounds forf (0) and qualitative behavior of the solutions are shown.
Sommario Si consideri il problema definito dall'equazionef+ f f+ (1–f2)+ f=0 e dalle condizioni al contornof(0)=f (0)=0,f()=1. Assumendo=–1,>0, arbitrario si dimostra che esiste almeno una soluzione che soddisfa 0<f<1 nell'intervallo (0, ). Se in aggiunta si ipotizzaf>0 in (0, ), oppure 0<=1, l'unicità délia soluzione è assicurata.Successivamente si considéra il problema di valori al contorno con=1,<0, arbitrario. In questo caso esiste un'intera classe di soluzioni che soddisfano –1<f<0 in un intorno dell'origine e tali chef>1, in generale.Di detti problemi viene studiato il comportamento délle soluzioni e vengono determinate dalle maggiorazioni e minorazioni del valoref(0).相似文献
90.
Bruno Ernst 《manuscripta mathematica》1978,23(2):103-112
The main object of this paper is to generalize a homomorphism theorem of Köthe [5] for a wide class of not necessarily locally convex topological vector spaces. A sequence =(Bn) of balanced sets Bn in a vector space E(), such that the union of the Bn's equals E and such that Bn+BnBn+1 for all nN, is called an absorbent sequence. E() is called -locally topological, if it possesses an absorbent sequence =(Bn) of bounded sets and if a linear mapping A from E() into any other vector space is continuous if all restrictions
are continuous at 0. It is shown, that a continuous linear mapping A from a vector space E() with an absorbant sequence of compact sets into a boundedly summing -locally topological space F() is a homomorphism if A(E) is closed in F(). 相似文献