Highly regioselective rearrangement of 2-substituted vinylepoxides catalyzed by gallium(III) triflate

Gallium(III) triflate catalyzed the rearrangement of 2-substituted vinylepoxides into beta,gamma-unsaturated carbonyl compounds with high regio- and chemoselectivity (>97/3) in low catalyst loading (1-5 mol %). The alkyl-substituted trimethylsilylvinyl epoxides gave beta,gamma-unsaturated ketone, but aryl-substituted vinylepoxides gave the aldehydes instead.     

2型糖尿病患者血清钙镁与甲状腺激素含量变化及临床意义

为了监测 2型糖尿病人血清钙、镁和甲状腺激素含量 ,分析其临床意义及相关性 ,应用放射免疫分析法测定了 1 1 5例 2型糖尿病及 1 5 0例健康人血清甲状腺激素含量。同时用美国杜邦RXL自动生化仪测定了其血清钙、镁含量。结果表明 ,在 2型糖尿病伴有明显并发症者血镁、FT3水平明显降低 (P <0 0 5 ) ,钙镁两种元素与甲状腺激素水平无明显相关性。 2型糖尿病患者适当补镁对预防其并发症是有益的 ,测定FT3 等可作为判断 2型糖尿病严重程度和估计预后的参考指标。     

苯胺气相N－烷基化反应研究Ⅱ．苯胺和乙醇常压催化合成N－乙基苯胺的工业应用

苯胺气相Ｎ－烷基化反应研究Ⅱ．苯胺和乙醇常压催化合成Ｎ－乙基苯胺的工业应用陈骏如，李瑞祥，韩银仙，李贤均（四川大学化学系成都６１００６４）Ｎ－乙基苯胺是制造染料、塑料、炸药和医药等许多化工产品的重要中间体，其合成方法过去多采用无机酸催化剂，如Ｈ＿２Ｓ...     

Calculation of avoided crossings for highly excited Stark states of Rb

Using the method of diagonalization, in which zero-field wavefunctions from a potential model are chosen as a basis, we calculate positions and widths of anticrossings for highly excited Stark states of Rb with principal quantum number n up to 49. We obtain the theoretical positions and widths in good agreement with available experimental values, and we present scaling laws of the field positions and widths of anticrossings that can be used to provide information for future experiments.     

Dye-sensitized solar cells based on composite solid polymer electrolytes

The ionic conductivity of polymer electrolytes and their interfacial contact with dye-attached TiO2 particles were enhanced markedly by the addition of amorphous oligomer into polymer electrolytes, resulting in very high overall energy conversion efficiency.