首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   20971篇
  免费   3497篇
  国内免费   2795篇
化学   11562篇
晶体学   184篇
力学   945篇
综合类   163篇
数学   1607篇
物理学   6101篇
无线电   6701篇
  2024年   99篇
  2023年   525篇
  2022年   629篇
  2021年   842篇
  2020年   867篇
  2019年   803篇
  2018年   672篇
  2017年   630篇
  2016年   904篇
  2015年   965篇
  2014年   1161篇
  2013年   1532篇
  2012年   1718篇
  2011年   1747篇
  2010年   1262篇
  2009年   1355篇
  2008年   1436篇
  2007年   1347篇
  2006年   1236篇
  2005年   1077篇
  2004年   797篇
  2003年   689篇
  2002年   660篇
  2001年   560篇
  2000年   525篇
  1999年   552篇
  1998年   420篇
  1997年   365篇
  1996年   354篇
  1995年   289篇
  1994年   249篇
  1993年   207篇
  1992年   186篇
  1991年   136篇
  1990年   124篇
  1989年   75篇
  1988年   63篇
  1987年   58篇
  1986年   36篇
  1985年   34篇
  1984年   19篇
  1983年   15篇
  1982年   17篇
  1981年   10篇
  1980年   7篇
  1979年   4篇
  1975年   1篇
  1959年   1篇
  1957年   1篇
  1909年   2篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
41.
Many recent studies have convincingly demonstrated that network traffic exhibits a noticeable self-similar nature, which has a considerable impact on network performance, and most studies of optical burst switching (OBS) networks are under a fundamental assumption that full wavelength conversion is available throughout the network. In practice, however, economic and technical considerations are likely to dictate a more limited and sparse deployment of wavelength converters in the optical network. Therefore, we present a novel scheme for OBS networks, called logical cascaded private subnet (LCPN) with start wavelength assignment policy. We define the concept of canoe relative to cluster in self-similar traffic, and introduce a new device named payload segregator at the edge node as a gateway to the core node in OBS Networks. According to the changes in the edge node framework, we put forward the concept of cluster private subnet and canoe private subnet in the core node correspondingly. A new start wavelength assignment policy is proposed for the absence of (full) wavelength conversion capabilities in the core node of OBS Networks. The performance study indicates that, our new scheme is robust under self-similar traffic and wavelength continuity constraint.  相似文献   
42.
酸糖蛋白手性柱分离6种手性化合物   总被引:3,自引:0,他引:3  
谢智勇  钟大放  李岩 《分析化学》2006,34(2):223-226
通过考察缓冲液种类、浓度及其pH值对对映体在手性柱上的保留和分离行为的影响,以及流动相中加入不同种类、不同浓度的不带电荷的有机溶剂乙腈、甲醇、正丙醇、异丙醇、流动相流速和柱温对对映体分离能力的影响,优化了含碳手性中心的碱性药物苯丙哌林、酸性化合物MT-A5及MT-酸和含硫手性中心的质子泵抑制剂奥美拉唑、泮托拉唑、雷贝拉唑对映体分离条件,最佳手性分离条件为:苯丙哌林,0.05 mol/L磷酸二氢铵缓冲液(pH 3.0)-乙腈(95∶5,V/V)为流动相,流速为0.7 mL/m in,柱温为20℃;MT-A5及MT-酸,流动相为0.01 mol/L醋酸铵缓冲液(pH 5.0)-乙腈(74∶26,V/V),流速为0.9 mL/m in,柱温为20℃;泮托拉唑,流动相为10 mmol/L醋酸铵缓冲液(pH 5.5)-乙腈(93∶7,V/V),流速为0.9 mL/m in;柱温为20℃;奥美拉唑和雷贝拉唑,流动相为0.01 mol/L醋酸铵缓冲液(pH 3.0)-乙腈(95∶5,V/V),流速为0.7 mL/m in,柱温为20℃。实现了应用高效液相色谱法在α1-酸糖蛋白手性柱上对上述化合物的对映体分离,并成功用于手性药物合成中的对映体过量百分率的测定。  相似文献   
43.
谢永斌  张晋  陆武 《通信世界》2006,(44):29-30
TD-SCDMA技术优势 2000年5月,在土耳其伊斯坦布尔召开的国际电联大会上,TD-SCDMA被国际电联接纳为第三代移动通信系统标准之一,这标志着中国在移动通信技术领域已经进入世界先进行列.  相似文献   
44.
We propose a novel polarization-mode dispersion (PMD) compensation scheme for wavelength-division-multiplexing (WDM) systems, in which many WDM channels share one or a few PMD compensators at receiver site. It is shown, both analytically and numerically, that this scheme can achieve virtually the same performance as that using per-channel-based PMD compensation.  相似文献   
45.
Single frequency vibration tests were used to induce fretting corrosion in tin alloy plated contacts. The samples used in this study were connectors consisting of 25 pairs of mated pin and socket contacts. Experimental results for a variety of vibration levels, frequencies, and wiring tie-off lengths are presented. The experiments consisted of running a series of vibration tests at each frequency where the excitation level was stepped through a range of g-levels. During each test run contact resistance was monitored as a performance characteristic. The results exhibit threshold behavior at each frequency for the onset of fretting degradation. Typically a plateau region was observed where similar g-levels produced similar fretting rates. It was also found that outside the plateau region the g-levels varied according to the dynamic behavior of the mechanical system. In addition, a transfer matrix model was used to analyze these results. An empirical fit of the data correlated well with the model when damping was used. This analysis revealed the importance of the bending moment induced at the contact interface as a result of excitation levels and tie-off configurations. Consequently, it is concluded that dynamic response of the mechanical system under various g-levels and tie off configurations can greatly impact the performance of a connector system subjected to vibration stresses.  相似文献   
46.
本文介绍了离子束混合工艺方法。与直接注入相比较,离子束混合所使用的设备造价低1/4—1/2,而生产效率可提高1—2个数量级,因而使生产成本大幅度降低,这无疑对离子束工艺的实际应用将产生巨大的促进作用。 通过对轴承材料(GCr15和Cr4Mo4V)经Cr、N、Ta不同元素的混合处理后,在0.5M H_2SO_4和0.1M NaCl的缓冲溶液中的阳极极化曲线表明经混合处理后的两种材料试样,其抗蚀能力和抗点蚀能力均大大提高,这与直接注入的试样效果是一致的。 通过俄歇谱仪和透射电镜的分析结果表明混合是成功的,且在一定的条件下,形成非晶组织。 本文的结论是,无论是离子的直接注入还是离子束混合,对提高轴承材料的抗腐蚀性能都是有效的方法,特别是离子束混合技术具有更大的应用前景。  相似文献   
47.
Two orange phosphorescent iridium complex monomers, 9‐hexyl‐9‐(iridium (III)bis(2‐(4′‐fluorophenyl)‐4‐phenylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐PIr) and 9‐hexyl‐9‐(iridium(III)bis(2‐(4′‐fluorophenyl)‐4‐methylquinoline‐N,C2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐MIr), were successfully synthesized. The Suzuki polycondensation of 2,7‐bis(trimethylene boronate)‐9,9‐dioctylfluorene with 2,7‐dibromo‐9,9‐dioctylfluorene and Br‐PIr or Br‐MIr afforded two series of copolymers, PIrPFs and MIrPFs, in good yields, in which the concentrations of the phosphorescent moieties were kept small (0.5–3 mol % feed ratio) to realize incomplete energy transfer. The photoluminescence (PL) of the copolymers showed blue‐ and orange‐emission peaks. A white‐light‐emitting diode with a configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/PIr05PF (0.5 mol % feed ratio of Br‐PIr)/Ca/Al exhibited a luminous efficiency of 4.49 cd/A and a power efficiency of 2.35 lm/W at 6.0 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.33). The CIE coordinates were improved to (0.34, 0.33) when copolymer MIr10PF (1.0 mol % feed ratio of Br‐MIr) was employed as the white‐emissive layer. The strong orange emission in the electroluminescence spectra in comparison with PL for these kinds of polymers was attributed to the additional contribution of charge trapping in the phosphorescent dopants. © 2007 Wiley Periodicals, Inc. JPolym Sci Part A: Polym Chem 45: 1746–1757, 2007  相似文献   
48.
聚能射流的断裂时间   总被引:1,自引:0,他引:1  
从描述聚能射流失稳的一维近似方程出发,导出了聚能射流断裂时间的近似公式。这个近似公式定量显示了屈服应力、本构关系、粘度和径向收缩效应等对射流断裂时间的影响,在4个不同的特殊近似下,可以自然演化为近10年来所发表的几个半经验解析公式,并且在合理的参数范围内,公式给出的断裂时间曲线覆盖了射流断裂时间的全部实验点。  相似文献   
49.
化学束外延     
本文介绍了化学束外延(CBE)的发明和发展,论述了CBE的原理和设备。文中还介绍了最近提出的一种生长机理。  相似文献   
50.
A 6H-SiC thyristor has been fabricated and characterized. A forward breakover voltage close to 100 V and a pulse switched current density of 5200 A/cm2 have been demonstrated. The thyristor is shown to operate under pulse gate triggering for turn-on and turn-off, with a rise time of 43 ns and a fall time of less than 100 ns. The forward breakover voltage is found to decrease by only 4% when the operating temperature is increased from room temperature to 300°C. It is found that anode ohmic contact resistance dominates the device forward drop at high current densities  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号