Heterogeneous Catalysis of Ozone Using Iron–Manganese Silicate for Degradation of Acrylic Acid

Iron–manganese silicate (IMS) was synthesized by chemical coprecipitation and used as a catalyst for ozonating acrylic acid (AA) in semicontinuous flow mode. The Fe-O-Mn bond, Fe-Si, and Mn-Si binary oxide were formed in IMS on the basis of the results of XRD, FTIR, and XPS analysis. The removal efficiency of AA was highest in the IMS catalytic ozonation processes (98.9% in 15 min) compared with ozonation alone (62.7%), iron silicate (IS) catalytic ozonation (95.6%), and manganese silicate catalytic ozonation (94.8%). Meanwhile, the removal efficiencies of total organic carbon (TOC) were also improved in the IMS catalytic ozonation processes. The IMS showed high stability and ozone utilization. Additionally, H₂O₂ was formed in the process of IMS catalytic ozonation. Electron paramagnetic resonance (EPR) analysis and radical scavenger experiments confirmed that hydroxyl radicals (•OH) were the dominant oxidants. Cl⁻, HCO₃⁻, PO₄³⁻, Ca²⁺, and Mg²⁺ in aqueous solution could adversely affect AA degradation. In the IMS catalytic ozonation of AA, the surface hydroxyl groups and Lewis acid sites played an important role.     

NIR TADF emitters and OLEDs: challenges,progress, and perspectives

Near-infrared (NIR) light-emitting materials show excellent potential applications in the fields of military technology, bioimaging, optical communication, organic light-emitting diodes (OLEDs), etc. Recently, thermally activated delayed fluorescence (TADF) emitters have made historic developments in the field of OLEDs. These metal-free materials are more attractive because of efficient reverse intersystem crossing processes which result in promising high efficiencies in OLEDs. However, the development of NIR TADF emitters has progressed at a relatively slower pace which could be ascribed to the difficult promotion of external quantum efficiencies. Thus, increasing attention has been paid to NIR TADF emitters. In this review, the recent progress of NIR TADF emitters has been summarized along with their molecular design strategies and photophysical properties, as well as electroluminescence performance data of their OLEDs, respectively.

This review presents the recent progress of NIR TADF emitters along with their molecular design strategies and photophysical properties, as well as the electroluminescence performance data of the emitters and their OLEDs.     

离焦激光直写的线宽稳定方法

为了提高激光直写加工衍射光学元件时的线条质量,提出一种离焦激光直写的线宽稳定方法.该方法通过同时调节激光功率和离焦量,使光刻胶的曝光阈值处于线宽对曝光量的变化率较小位置,从而可以弱化线宽对实际曝光量或光刻胶阈值等变化的敏感度,提高利用离焦方法进行衍射光学元件制作时的线宽稳定性.推导了稳定线宽后的光功率控制模型和线宽模型,模型中的变量仅为离焦量,降低了光功率控制的复杂性.利用632.8 nm的He-Ne激光和NA-0.1的物镜在CCD上对采用该方法后的离焦线宽模型进行验证,实验结果与理论模型吻合较好.该方法对于线宽稳定度较高的衍射光学元件制作具有重要价值.     

Broadband Sheet Parametric Oscillator for x~((2)) Optical Frequency Comb Generation via Cavity Phase Matching

We demonstrate a broadband optical parametric oscillation, using a sheet cavity, via cavity phase-matching. A21.2 THz broad comb-like spectrum is achieved, with a uniform line spacing of 133.0 GHz, despite a relatively large dispersion of 275.4 fs~2/mm around 1064 nm. With 22.6% high slope efficiency, and 14.9 kW peak power handling, this sheet optical parametric oscillator can be further developed for x~((2)) comb.     

基于行过扫数据降低大面阵CCD图像噪声算法研究

针对全帧转移大面阵电荷耦合器件(CCD)多帧图像数据随时间漂移的现象和测试电路引入的噪声,导致无法准确评估CCD器件的参数,文章提出一种基于行过扫数据校正算法。行有效像元数据与对应行垂直过扫数据同时输出,通过有效像元数据减去垂直过扫数据均值,对图像数据漂移的现象进行抑制。测试电路中模拟模块与数字模块同时作用于单行有效像元数据与垂直过扫数据,通过有效像元数据减去垂直过扫数据均值,消除测试电路引入的噪声。实验结果表明,经过该算法校正后的器件读出噪声减小了20%,暗场差值图像中超过15 e^-和25 e^-的比例减小了25%。该算法适用于大面阵CCD器件,可校正测试系统引入的测试误差,提高全帧转移大面阵CCD器件测试效率。     

基于DFB激光器的振动传感系统改进PGC解调算法

相位生成载波(Phase Generated Carrier, PGC)解调算法是目前光纤干涉传感领域中重要的解调算法。针对目前PGC解调算法中光强扰动和调制深度影响信号解调准确度的问题,提出了一种改进的PGC解调算法(PGC-Ameliorated),并搭建了基于分布反馈(Distributed Feedback, DFB)激光器的振动传感系统进行实验验证。实验结果表明,当被测振动信号的频率为800 Hz时,该算法信噪比为57 dB,优于微分交叉相乘(Differential and Cross Multiplying, DCM)算法和反正切(Arctan)算法近20 dB。在不同光强下,该算法解调信号幅值波动范围在±0.02 rad;在不同调制深度下,该算法总谐波失真最小为0.61%,信纳比最大为25.9 dB,相比于DCM算法和Arctan算法具有更低的总谐波失真和更高的信纳比。     

飞秒激光制备的全单模光纤法布里-珀罗干涉高温传感器

提出了一种全单模光纤的本征型法布里-珀罗干涉(IFPI)高温传感器。光纤IFPI传感器由飞秒激光在标准单模光纤上刻写的一对内部反射镜和腔内光纤构成,其反射光谱的干涉条纹对比度达到10dB,而插入损耗仅为0.1dB。实验结果表明,该传感器的测量温度可达1000℃,温度灵敏度为14.9pm/℃。而且在重复测量中,反射光谱具有良好的一致性,可以准确地实现高温传感。飞秒激光制备的光纤IFPI高温传感器完全由标准单模光纤构成,结构简单、成本低廉,易于连接现有的光纤器件构成光纤传感网络,在实际工程中有较大的应用价值。     

抛光液组成对LiNbO3 CMP去除速率的影响

影响LiNbO3化学机械抛光速率的因素很多,如抛光液组成、抛光垫质量、抛光工艺参数等.主要研究了抛光液对去除速率的影响,采用磨料 碱 活性剂的配方,首先分析了抛光液各成分对去除速率的影响机理,然后结合各因素的部分相关实验,从机械、化学角度分析其性质特点,对LiNbO3晶片的去除速率进行了研究.结果表明,在保证获得较好抛光表面的前提下,采用的磨料质量分数越高越好,但活性剂体积分数不宜过高,溶液pH值采用无机碱进行调节,即可获得较高的去除速率.     

约瑟夫森阵列振荡器的相位锁定分析

系统地研究了超导亚毫米波阵列振荡器的相位锁定问题。为使超导振荡器达到高工作频率、窄线宽和高稳定的性能，约瑟夫森结与结之间的相位必须相互锁定。相位锁定可以通过结与结之间的耦合电路得以实现。通过对振荡器的各种耦合电路的比较表明，蝴蝶领结天线结构是一个比较适合约瑟夫森振荡器相位锁定的耦合电路。本文提出了一种超导亚毫米波阵列振荡器模型并对其进行了模拟计算与分析，仿真得出了振荡器各项参数值，并给出了相位锁定的条件。